Name:
Hydranal Composite 5
Synonym:
CAS:
0-00-0
Section 1 - Chemical Product
MSDS Name:Hydranal Composite 5
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 0-00-0 | Sulfur dioxide | N/A | 231-195-2 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Combustible liquid. Can form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Combustible liquid. Can form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 0-00-0: CAS# 7446-09-5: United States OSHA: 5 ppm TWA; 13 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 5 ppm VLE; 10 mg/m3 VLE Germany: 1 ppm TWA (paper production, chemical and pharmaceutical industries); 2.5 mg/m3 Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 0-00-0: CAS# 7446-09-5: United States OSHA: 5 ppm TWA; 13 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 5 ppm VLE; 10 mg/m3 VLE Germany: 1 ppm TWA (paper production, chemical and pharmaceutical industries); 2.5 mg/m3 Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: dark brown
Odor: Characteristic
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 193 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 76 deg C ( 168.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
For the incompatabilities associated with iodine and sulfur dioxide please refer to the NFPA Fire Protection Guide for the specific details.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, oxides of carbon, iodine.
Hazardous Polymerization:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
For the incompatabilities associated with iodine and sulfur dioxide please refer to the NFPA Fire Protection Guide for the specific details.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, oxides of carbon, iodine.
Hazardous Polymerization:
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 0-00-0 unlisted.
CAS# 7446-09-5: WS4550000 CAS# 7553-56-2: NN1575000 LD50/LC50:
Not available.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild; Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520 ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
Carcinogenicity:
Amine - Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 0-00-0 unlisted.
CAS# 7446-09-5: WS4550000 CAS# 7553-56-2: NN1575000 LD50/LC50:
Not available.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild; Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520 ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
Carcinogenicity:
Amine - Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 0-00-0: No information available.
CAS# 7446-09-5: 1
CAS# 7553-56-2: 1
Canada
CAS# 7446-09-5 is listed on Canadas DSL List.
CAS# 7553-56-2 is listed on Canadas DSL List.
CAS# 0-00-0 is not listed on Canadas Ingredient Disclosure List.
CAS# 7446-09-5 is listed on Canadas Ingredient Disclosure List.
CAS# 7553-56-2 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 0-00-0 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 7446-09-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
