Name:
Hydranal Coulomat A
Synonym:
CAS:
67-56-1
Section 1 - Chemical Product
MSDS Name:Hydranal Coulomat A
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 67-56-1 | Methanol | N/A | 200-659-6 |
| Hazard Symbols: T F Risk Phrases: 11 23/25 38 40 48/20/22 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Toxic by inhalation and if swallowed. Irritating to skin. Limited evidence of a carcinogenic effect. Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.Toxic.Cancer suspect agent.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Vapors may cause eye irritation. May cause painful sensitization to light.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful amounts. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
Ingestion:
May be fatal or cause blindness if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Harmful if inhaled. Effects may be delayed. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause liver and kidney damage. May cause narcotic effects in high concentration. May cause drowsiness, unconsciousness, and central nervous system depression. Inhalation of high concentrations can lead to respiratory failure, cardiac arrhythmia, and death. Symptoms include progressive weakness, prolonged vomiting, delirium, coma, and possible death.
Chronic:
Not available.
Highly flammable. Toxic by inhalation and if swallowed. Irritating to skin. Limited evidence of a carcinogenic effect. Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.Toxic.Cancer suspect agent.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Vapors may cause eye irritation. May cause painful sensitization to light.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful amounts. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
Ingestion:
May be fatal or cause blindness if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Harmful if inhaled. Effects may be delayed. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause liver and kidney damage. May cause narcotic effects in high concentration. May cause drowsiness, unconsciousness, and central nervous system depression. Inhalation of high concentrations can lead to respiratory failure, cardiac arrhythmia, and death. Symptoms include progressive weakness, prolonged vomiting, delirium, coma, and possible death.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extremely flammable. Material will readily ignite at room temperature. Can form explosive mixtures at temperatures above the flashpoint.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extremely flammable. Material will readily ignite at room temperature. Can form explosive mixtures at temperatures above the flashpoint.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 67-56-1: United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL United States OSHA: 200 ppm TWA; 260 mg/m3 TWA Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE France - VME: 200 ppm VME; 260 mg/m3 VME France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE Germany: 200 ppm TWA; 270 mg/m3 TWA Germany: Skin absorber Japan: 200 ppm OEL; 260 mg/m3 OEL Malaysia: 200 ppm TWA; 262 mg/m3 TWA Netherlands: 200 ppm MAC; 260 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC CAS# 67-66-3: United Kingdom, WEL - TWA: 2 ppm TWA; 9.9 mg/m3 TWA United Kingdom, WEL - STEL: 6 ppm STEL; 29.7 mg/m3 STEL United States OSHA: ; 50 ppm Ceiling; 240 mg/m3 Ceiling Belgium - TWA: 10 ppm VLE; 50 mg/m3 VLE France - VME: 5 ppm VME; 25 mg/m3 VME France - VLE: 50 ppm VLE; 250 mg/m3 VLE Germany: 4 ppm TWA (large technical manufacture and use); 20 mg/m TWA (large technical m Germany: Skin absorber Japan: 10 ppm OEL; 49 mg/m3 OEL Malaysia: 10 ppm TWA; 49 mg/m3 TWA Netherlands: 5 ppm STEL; 25 mg/m3 STEL Netherlands: 1 ppm MAC; 5 mg/m3 MAC Spain: 2 ppm VLA-ED; 10 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 67-56-1: United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL United States OSHA: 200 ppm TWA; 260 mg/m3 TWA Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE France - VME: 200 ppm VME; 260 mg/m3 VME France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE Germany: 200 ppm TWA; 270 mg/m3 TWA Germany: Skin absorber Japan: 200 ppm OEL; 260 mg/m3 OEL Malaysia: 200 ppm TWA; 262 mg/m3 TWA Netherlands: 200 ppm MAC; 260 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC CAS# 67-66-3: United Kingdom, WEL - TWA: 2 ppm TWA; 9.9 mg/m3 TWA United Kingdom, WEL - STEL: 6 ppm STEL; 29.7 mg/m3 STEL United States OSHA: ; 50 ppm Ceiling; 240 mg/m3 Ceiling Belgium - TWA: 10 ppm VLE; 50 mg/m3 VLE France - VME: 5 ppm VME; 25 mg/m3 VME France - VLE: 50 ppm VLE; 250 mg/m3 VLE Germany: 4 ppm TWA (large technical manufacture and use); 20 mg/m TWA (large technical m Germany: Skin absorber Japan: 10 ppm OEL; 49 mg/m3 OEL Malaysia: 10 ppm TWA; 49 mg/m3 TWA Netherlands: 5 ppm STEL; 25 mg/m3 STEL Netherlands: 1 ppm MAC; 5 mg/m3 MAC Spain: 2 ppm VLA-ED; 10 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: brown-yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 59 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 11 deg C ( 51.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
The incompatabilities associated with methanol include: oxidants, sodium hypochlorite, chromium(vi) oxide, nitric acid, hydrogen peroxide, active metals, acetyl bromide, aluminum salts, beryllium dihydride, carbon tetrachloride,+metals, chloroform+metals, chloroform+heat, chloroform+sodium hydroxide, cyanuric chloride, diethyl zinc, and potassium tertbutoxide. Explosive reaction occurs when sodium is added to a methanol/chloroform mixture. For a complete list of the incompatibilities associated with chloroform please refer to the NFPA Fire Protection Guide for the specific details.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of sulfur, phosgene gas.
Hazardous Polymerization: Has not been reported.
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
The incompatabilities associated with methanol include: oxidants, sodium hypochlorite, chromium(vi) oxide, nitric acid, hydrogen peroxide, active metals, acetyl bromide, aluminum salts, beryllium dihydride, carbon tetrachloride,+metals, chloroform+metals, chloroform+heat, chloroform+sodium hydroxide, cyanuric chloride, diethyl zinc, and potassium tertbutoxide. Explosive reaction occurs when sodium is added to a methanol/chloroform mixture. For a complete list of the incompatibilities associated with chloroform please refer to the NFPA Fire Protection Guide for the specific details.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of sulfur, phosgene gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 67-56-1: PC1400000 CAS# 67-66-3: FS9100000 LD50/LC50:
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 67-66-3: Draize test, rabbit, eye: 148 mg; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 17200 mg/m3/2H; Inhalation, mouse: LC50 = 6000 mg/m3/6H; Inhalation, rat: LC50 = 47702 mg/m3/4H; Inhalation, rat: LC50 = 6000 mg/m3/6H; Oral, mouse: LD50 = 36 mg/kg; Oral, rat: LD50 = 695 mg/kg; Oral, rat: LD50 = 1250 mg/kg; Skin, rabbit: LD50 = >20 gm/kg.
Carcinogenicity:
Methanol - Not listed by ACGIH, IARC, or NTP.
Chloroform - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 10/1/87 NTP: Suspect carcinogen IARC: Group 2B carcinogen Other:
See actual entry in RTECS for complete information.
CAS# 67-56-1: PC1400000 CAS# 67-66-3: FS9100000 LD50/LC50:
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 67-66-3: Draize test, rabbit, eye: 148 mg; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 17200 mg/m3/2H; Inhalation, mouse: LC50 = 6000 mg/m3/6H; Inhalation, rat: LC50 = 47702 mg/m3/4H; Inhalation, rat: LC50 = 6000 mg/m3/6H; Oral, mouse: LD50 = 36 mg/kg; Oral, rat: LD50 = 695 mg/kg; Oral, rat: LD50 = 1250 mg/kg; Skin, rabbit: LD50 = >20 gm/kg.
Carcinogenicity:
Methanol - Not listed by ACGIH, IARC, or NTP.
Chloroform - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 10/1/87 NTP: Suspect carcinogen IARC: Group 2B carcinogen Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 67-66-3: 10 lb final RQ; 4.54 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 23/25 Toxic by inhalation and if swallowed.
R 38 Irritating to skin.
R 40 Limited evidence of a carcinogenic effect.
R 48/20/22 Harmful : danger of serious damage to
health by prolonged exposure through inhalation and if
swallowed.
Safety Phrases:
S 7 Keep container tightly closed.
S 14 Keep away from ... (incompatible materials to
be indicated by the manufacturer).
S 15 Keep away from heat.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
S 36 Wear suitable protective clothing.
WGK (Water Danger/Protection)
CAS# 67-56-1: 1
CAS# 67-66-3: 3
Canada
CAS# 67-56-1 is listed on Canadas DSL List.
CAS# 67-66-3 is listed on Canadas DSL List.
CAS# 67-56-1 is listed on Canadas Ingredient Disclosure List.
CAS# 67-66-3 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 67-66-3 is listed on the TSCA inventory.
