Name:
Hydranal Water Standard 5.0
Synonym:
CAS:
133-20-7
Section 1 - Chemical Product
MSDS Name:Hydranal Water Standard 5.0
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 133-20-7 | Butan-1-ol | N/A | unlisted |
| Hazard Symbols: XN F Risk Phrases: 10 20/21 38 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and in contact with skin.
Irritating to skin.
Potential Health Effects
Eye:
May cause severe eye irritation. May result in corneal injury.
Vapors may cause eye irritation.
Skin:
Prolonged and/or repeated contact may cause irritation and/or dermatitis. Exposure may cause irritation characterized by redness, dryness, and inflammation.
Ingestion:
Harmful if swallowed. May cause central nervous system depression, kidney damage, and liver damage. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Harmful if inhaled. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Inhalation of vapor may cause respiratory tract irritation. Prolonged exposure may result in dizziness and general weakness. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause liver and kidney damage.
May cause effects similar to those described for ingestion. May cause narcotic effects in high concentration.
Chronic:
Chronic exposure to organic solvents has been associated with various neurotoxic effects including permanent brain and nervous system damage.
Flammable. Harmful by inhalation and in contact with skin.
Irritating to skin.
Potential Health Effects
Eye:
May cause severe eye irritation. May result in corneal injury.
Vapors may cause eye irritation.
Skin:
Prolonged and/or repeated contact may cause irritation and/or dermatitis. Exposure may cause irritation characterized by redness, dryness, and inflammation.
Ingestion:
Harmful if swallowed. May cause central nervous system depression, kidney damage, and liver damage. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Harmful if inhaled. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Inhalation of vapor may cause respiratory tract irritation. Prolonged exposure may result in dizziness and general weakness. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause liver and kidney damage.
May cause effects similar to those described for ingestion. May cause narcotic effects in high concentration.
Chronic:
Chronic exposure to organic solvents has been associated with various neurotoxic effects including permanent brain and nervous system damage.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat symptomatically and supportively.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat symptomatically and supportively.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 133-20-7: CAS# 61990-73-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 133-20-7: CAS# 61990-73-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 116 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 21 deg C ( 69.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible with alcohol, diethyl ether
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Incompatabilities with xylene include: strong acids, strong oxidizers, ,3-dichloro-5,5-dimethyl-2,4-imidazolidindione(dichlorohydrantoin).
May attack some forms of plastics, rubber and coatings.
Incompatabilities with butan-1-ol include aluminum, chromium trioxide, organic peroxides, and strong oxidizers..
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Incompatabilities with xylene include: strong acids, strong oxidizers, ,3-dichloro-5,5-dimethyl-2,4-imidazolidindione(dichlorohydrantoin).
May attack some forms of plastics, rubber and coatings.
Incompatabilities with butan-1-ol include aluminum, chromium trioxide, organic peroxides, and strong oxidizers..
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 133-20-7 unlisted.
CAS# 61990-73-6 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Xylene - Not listed by ACGIH, IARC, or NTP.
Butan-1-ol - Not listed by ACGIH, IARC, or NTP.
CAS# 133-20-7 unlisted.
CAS# 61990-73-6 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Xylene - Not listed by ACGIH, IARC, or NTP.
Butan-1-ol - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 38 Irritating to skin.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 133-20-7: No information available.
CAS# 61990-73-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 133-20-7 is not listed on Canadas Ingredient Disclosure List.
CAS# 61990-73-6 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 133-20-7 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 61990-73-6 is not listed on the TSCA inventory.
It is for research and development use only.
