Name:
ICP Standard
Synonym:
None known
CAS:
7429-90-5
Section 1 - Chemical Product
MSDS Name:ICP Standard
Synonym:None known
Synonym:None known
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7429-90-5 | Aluminum | 0.1 | 231-072-3 |
| Hazard Symbols: XN C Risk Phrases: 21/22 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Causes burns.Corrosive.Cancer suspect agent.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects. The barium ion is a muscle poison causing stimulation and then paralysis. Initial symptoms are gastrointestinal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with tingling in the extremities.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
May cause cancer in humans. Effects may be delayed. Chronic inhalation of cadmium compounds has been associated with lung and prostate cancer. Cobalt compounds may cause cancer based upon animal studies. Cadmium and compounds may cause lung, liver and kidney damage and lung and prostate cancer in humans.
Harmful in contact with skin and if swallowed. Causes burns.Corrosive.Cancer suspect agent.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects. The barium ion is a muscle poison causing stimulation and then paralysis. Initial symptoms are gastrointestinal, including nausea, vomiting, colic, and diarrhea, followed by myocardial and general muscular stimulation with tingling in the extremities.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
May cause cancer in humans. Effects may be delayed. Chronic inhalation of cadmium compounds has been associated with lung and prostate cancer. Cobalt compounds may cause cancer based upon animal studies. Cadmium and compounds may cause lung, liver and kidney damage and lung and prostate cancer in humans.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. Contact with metals may evolve flammable hydrogen gas.
Containers may explode when heated. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. Contact with metals may evolve flammable hydrogen gas.
Containers may explode when heated. Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Use only in a well-ventilated area. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Use only in a well-ventilated area. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7429-90-5: United Kingdom, WEL - TWA: 10 mg/m3 TWA (inhalable dust); 4 mg/m3 (respirable dust) United Kingdom, WEL - STEL: 30 mg/m3 STEL (inhalable dust); 12 mg STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE (metal); 5 mg/m3 VLE (fume) France - VME: 10 mg/m3 VME (metal); 5 mg/m3 VME (dust) Japan: 0.5 mg/m3 OEL (respirable dust); 2 mg/m3 OEL (total dust) Malaysia: 10 mg/m3 TWA (metal dust) Netherlands: 10 mg/m3 MAC Russia: 2 mg/m3 TWA Spain: 10 mg/m3 VLA-ED (dust) CAS# 7440-22-4: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.01 mg/m3 TWA Belgium - TWA: 0.1 mg/m3 VLE France - VME: 0.1 mg/m3 VME Germany: 0.1 mg/m3 TWA (inhalable fraction) Japan: 0.01 mg/m3 OEL Malaysia: 0.1 mg/m3 TWA Netherlands: 0.1 mg/m3 MAC (as Ag) Russia: 1 mg/m3 TWA Spain: 0.1 mg/m3 VLA-ED CAS# 7440-39-3: United States OSHA: 0.5 mg/m3 TWA Belgium - TWA: 0.5 mg/m3 VLE Malaysia: 0.5 mg/m3 TWA Netherlands: 0.5 mg/m3 MAC Spain: 0.5 mg/m3 VLA-ED CAS# 7440-42-8: CAS# 7440-43-9: United Kingdom, WEL - TWA: 0.025 mg/m3 TWA United Kingdom, WEL - STEL: 0.075 mg/m3 STEL United States OSHA: 0.2 mg/m3 TWA (dust); 0.1 mg/m3 TWA (fume); 0 mg/m3 Ceiling (dust); 0.3 mg/m3 Ceiling (fume); 2.5 ??g/m3 Action Level; 5 ??g/m3 TWA (Do not eat, drink or chew tobacco or gum or apply cosmetics in regulated areas. Carcinogen - dust can cause l and kidn Belgium - TWA: 0.002 mg/m3 VLE (respirable particulates); 0.01 mg VLE (inhalable particulate France - VME: 0.05 mg/m3 VME Germany: 0.03 mg/m3 TWA (dusts/aerosols, inhalable fraction, batt production - thermal Japan: 0.05 mg/m3 OEL Malaysia: 0.01 mg/m3 TWA; 0.002 mg/m3 TWA (respirable fraction) Netherlands: (listed as chromium compounds): 0.01 mg/m3 STEL Netherlands: 0.005 mg/m3 MAC Russia: 0.05 mg/m3 TWA Russia: 0.01 mg/m3 STEL Spain: 0.01 mg/m3 VLA-ED (inhalable fraction); 0.002 mg/m3 VLA-ED (respirable fraction) CAS# 7440-47-3: United Kingdom, WEL - TWA: 0.5 mg/m3 TWA United Kingdom, WEL - STEL: 1.5 mg/m3 STEL United States OSHA: 1 mg/m3 TWA Belgium - TWA: 0.5 mg/m3 VLE France - VME: 0.5 mg/m3 VME Japan: 0.5 mg/m3 OEL Malaysia: 0.5 mg/m3 TWA Netherlands: (listed as chromium compounds): 0.01 mg/m3 STEL Netherlands: 0.5 mg/m3 MAC Spain: 0.5 mg/m3 VLA-ED CAS# 7440-48-4: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.1 mg/m3 TWA (dust and fume) Belgium - TWA: 0.02 mg/m3 VLE (dust and fume) Germany: 0.5 mg/m3 TWA (inhalable fraction, production of cobalt powder and catalysts, tu Japan: 0.05 mg/m3 OEL Malaysia: 0.02 mg/m3 TWA Netherlands: 0.02 mg/m3 MAC (dust and smoke, as Co) Russia: 0.5 mg/m3 TWA (dust and/or fumes) Spain: 0.02 mg/m3 VLA-ED CAS# 7440-70-2: CAS# 7697-37-2: United Kingdom, WEL - TWA: 2 ppm TWA; 5.2 mg/m3 TWA United Kingdom, WEL - STEL: 4 ppm STEL; 10 mg/m3 STEL United States OSHA: 2 ppm TWA; 5 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 4 ppm VLE; 10 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 4 ppm VLE; 10 mg/m3 VLE Germany: 2 ppm TWA; 5.2 mg/m3 TWA Japan: 2 ppm OEL; 5.2 mg/m3 OEL Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 0.5 ppm STEL; 1.3 mg/m3 STEL Russia: 2 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.2 mg/m3 VLA-ED Spain: 4 ppm VLA-EC; 10 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7429-90-5: United Kingdom, WEL - TWA: 10 mg/m3 TWA (inhalable dust); 4 mg/m3 (respirable dust) United Kingdom, WEL - STEL: 30 mg/m3 STEL (inhalable dust); 12 mg STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE (metal); 5 mg/m3 VLE (fume) France - VME: 10 mg/m3 VME (metal); 5 mg/m3 VME (dust) Japan: 0.5 mg/m3 OEL (respirable dust); 2 mg/m3 OEL (total dust) Malaysia: 10 mg/m3 TWA (metal dust) Netherlands: 10 mg/m3 MAC Russia: 2 mg/m3 TWA Spain: 10 mg/m3 VLA-ED (dust) CAS# 7440-22-4: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.01 mg/m3 TWA Belgium - TWA: 0.1 mg/m3 VLE France - VME: 0.1 mg/m3 VME Germany: 0.1 mg/m3 TWA (inhalable fraction) Japan: 0.01 mg/m3 OEL Malaysia: 0.1 mg/m3 TWA Netherlands: 0.1 mg/m3 MAC (as Ag) Russia: 1 mg/m3 TWA Spain: 0.1 mg/m3 VLA-ED CAS# 7440-39-3: United States OSHA: 0.5 mg/m3 TWA Belgium - TWA: 0.5 mg/m3 VLE Malaysia: 0.5 mg/m3 TWA Netherlands: 0.5 mg/m3 MAC Spain: 0.5 mg/m3 VLA-ED CAS# 7440-42-8: CAS# 7440-43-9: United Kingdom, WEL - TWA: 0.025 mg/m3 TWA United Kingdom, WEL - STEL: 0.075 mg/m3 STEL United States OSHA: 0.2 mg/m3 TWA (dust); 0.1 mg/m3 TWA (fume); 0 mg/m3 Ceiling (dust); 0.3 mg/m3 Ceiling (fume); 2.5 ??g/m3 Action Level; 5 ??g/m3 TWA (Do not eat, drink or chew tobacco or gum or apply cosmetics in regulated areas. Carcinogen - dust can cause l and kidn Belgium - TWA: 0.002 mg/m3 VLE (respirable particulates); 0.01 mg VLE (inhalable particulate France - VME: 0.05 mg/m3 VME Germany: 0.03 mg/m3 TWA (dusts/aerosols, inhalable fraction, batt production - thermal Japan: 0.05 mg/m3 OEL Malaysia: 0.01 mg/m3 TWA; 0.002 mg/m3 TWA (respirable fraction) Netherlands: (listed as chromium compounds): 0.01 mg/m3 STEL Netherlands: 0.005 mg/m3 MAC Russia: 0.05 mg/m3 TWA Russia: 0.01 mg/m3 STEL Spain: 0.01 mg/m3 VLA-ED (inhalable fraction); 0.002 mg/m3 VLA-ED (respirable fraction) CAS# 7440-47-3: United Kingdom, WEL - TWA: 0.5 mg/m3 TWA United Kingdom, WEL - STEL: 1.5 mg/m3 STEL United States OSHA: 1 mg/m3 TWA Belgium - TWA: 0.5 mg/m3 VLE France - VME: 0.5 mg/m3 VME Japan: 0.5 mg/m3 OEL Malaysia: 0.5 mg/m3 TWA Netherlands: (listed as chromium compounds): 0.01 mg/m3 STEL Netherlands: 0.5 mg/m3 MAC Spain: 0.5 mg/m3 VLA-ED CAS# 7440-48-4: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.1 mg/m3 TWA (dust and fume) Belgium - TWA: 0.02 mg/m3 VLE (dust and fume) Germany: 0.5 mg/m3 TWA (inhalable fraction, production of cobalt powder and catalysts, tu Japan: 0.05 mg/m3 OEL Malaysia: 0.02 mg/m3 TWA Netherlands: 0.02 mg/m3 MAC (dust and smoke, as Co) Russia: 0.5 mg/m3 TWA (dust and/or fumes) Spain: 0.02 mg/m3 VLA-ED CAS# 7440-70-2: CAS# 7697-37-2: United Kingdom, WEL - TWA: 2 ppm TWA; 5.2 mg/m3 TWA United Kingdom, WEL - STEL: 4 ppm STEL; 10 mg/m3 STEL United States OSHA: 2 ppm TWA; 5 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 4 ppm VLE; 10 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 4 ppm VLE; 10 mg/m3 VLE Germany: 2 ppm TWA; 5.2 mg/m3 TWA Japan: 2 ppm OEL; 5.2 mg/m3 OEL Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 0.5 ppm STEL; 1.3 mg/m3 STEL Russia: 2 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.2 mg/m3 VLA-ED Spain: 4 ppm VLA-EC; 10 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: mild odor - acetic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: > 100 deg C
Freezing/Melting Point: > 0 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: >1.0
Molecular Formula: Solution
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong acids, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, barium oxide, aluminum oxide, calcium oxide, silver fumes, cadmium fumes, chromium dioxide, boron oxides, cobalt/cobalt oxides.
Hazardous Polymerization: Has not been reported
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong acids, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, barium oxide, aluminum oxide, calcium oxide, silver fumes, cadmium fumes, chromium dioxide, boron oxides, cobalt/cobalt oxides.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7429-90-5: BD0330000 BD1020000 CAS# 7440-22-4: VW3500000 CAS# 7440-39-3: CQ8370000 CAS# 7440-42-8: ED7350000 CAS# 7440-43-9: EU9800000 CAS# 7440-47-3: GB4200000 CAS# 7440-48-4: GF8750000 GF8850000 GG0375000 CAS# 7440-70-2: EV8500000 CAS# 7697-37-2: QU5775000 QU5900000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
Not available.
Not available.
Not available.
CAS# 7440-42-8: Oral, mouse: LD50 = 560 mg/kg; Oral, rabbit: LD50 = 310 mg/kg; Oral, rat: LD50 = 650 mg/kg.
CAS# 7440-43-9: Inhalation, rat: LC50 = 25 mg/m3/30M; Oral, mouse: LD50 = 890 mg/kg; Oral, rat: LD50 = 2330 mg/kg.
CAS# 7440-47-3.
CAS# 7440-48-4: Oral, rat: LD50 = 6171 mg/kg.
CAS# 7440-70-2.
CAS# 7697-37-2: Inhalation, rat: LC50 = 260 mg/m3/30M; Inhalation, rat: LC50 = 130 mg/m3/4H; Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Aluminum - Not listed by ACGIH, IARC, or NTP.
Silver - Not listed by ACGIH, IARC, or NTP.
Barium - Not listed by ACGIH, IARC, or NTP.
Boron - Not listed by ACGIH, IARC, or NTP.
Cadmium - ACGIH: A2 - Suspected Human Carcinogen (listed as Cadmium compoun California: carcinogen, initial date 10/1/87 NTP: Known carcinogen IARC: Group 1 carcinogen Chromium - Not listed by ACGIH, IARC, or NTP.
Cobalt - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 7/1/92 (powder) IARC: Group 2B carcinogen Calcium - Not listed by ACGIH, IARC, or NTP.
Nitric acid - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7429-90-5: BD0330000 BD1020000 CAS# 7440-22-4: VW3500000 CAS# 7440-39-3: CQ8370000 CAS# 7440-42-8: ED7350000 CAS# 7440-43-9: EU9800000 CAS# 7440-47-3: GB4200000 CAS# 7440-48-4: GF8750000 GF8850000 GG0375000 CAS# 7440-70-2: EV8500000 CAS# 7697-37-2: QU5775000 QU5900000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
Not available.
Not available.
Not available.
CAS# 7440-42-8: Oral, mouse: LD50 = 560 mg/kg; Oral, rabbit: LD50 = 310 mg/kg; Oral, rat: LD50 = 650 mg/kg.
CAS# 7440-43-9: Inhalation, rat: LC50 = 25 mg/m3/30M; Oral, mouse: LD50 = 890 mg/kg; Oral, rat: LD50 = 2330 mg/kg.
CAS# 7440-47-3.
CAS# 7440-48-4: Oral, rat: LD50 = 6171 mg/kg.
CAS# 7440-70-2.
CAS# 7697-37-2: Inhalation, rat: LC50 = 260 mg/m3/30M; Inhalation, rat: LC50 = 130 mg/m3/4H; Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Aluminum - Not listed by ACGIH, IARC, or NTP.
Silver - Not listed by ACGIH, IARC, or NTP.
Barium - Not listed by ACGIH, IARC, or NTP.
Boron - Not listed by ACGIH, IARC, or NTP.
Cadmium - ACGIH: A2 - Suspected Human Carcinogen (listed as Cadmium compoun California: carcinogen, initial date 10/1/87 NTP: Known carcinogen IARC: Group 1 carcinogen Chromium - Not listed by ACGIH, IARC, or NTP.
Cobalt - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 7/1/92 (powder) IARC: Group 2B carcinogen Calcium - Not listed by ACGIH, IARC, or NTP.
Nitric acid - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3289
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3289
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3289
Packing group: II
USA RQ: CAS# 7440-22-4: 1000 lb final RQ (no reporting of releases of this hazar
USA RQ: CAS# 7440-43-9: 10 lb final RQ (no reporting of releases of this hazardo
USA RQ: CAS# 7440-47-3: 5000 lb final RQ (no reporting of releases of this hazar
USA RQ: CAS# 7697-37-2: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN C
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 25 Avoid contact with eyes.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7429-90-5: 0
CAS# 7440-22-4: 0
CAS# 7440-39-3: No information available.
CAS# 7440-42-8: No information available.
CAS# 7440-43-9: No information available.
CAS# 7440-47-3: No information available.
CAS# 7440-48-4: 1
CAS# 7440-70-2: 1
CAS# 7697-37-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7429-90-5 is listed on Canadas DSL List.
CAS# 7440-22-4 is listed on Canadas DSL List.
CAS# 7440-39-3 is listed on Canadas DSL List.
CAS# 7440-42-8 is listed on Canadas DSL List.
CAS# 7440-43-9 is listed on Canadas DSL List.
CAS# 7440-47-3 is listed on Canadas DSL List.
CAS# 7440-48-4 is listed on Canadas DSL List.
CAS# 7440-70-2 is listed on Canadas DSL List.
CAS# 7697-37-2 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 7429-90-5 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-22-4 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-39-3 is not listed on Canadas Ingredient Disclosure List.
CAS# 7440-42-8 is not listed on Canadas Ingredient Disclosure List.
CAS# 7440-43-9 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-47-3 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-48-4 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-70-2 is not listed on Canadas Ingredient Disclosure List.
CAS# 7697-37-2 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7429-90-5 is listed on the TSCA inventory.
CAS# 7440-22-4 is listed on the TSCA inventory.
CAS# 7440-39-3 is listed on the TSCA inventory.
CAS# 7440-42-8 is listed on the TSCA inventory.
CAS# 7440-43-9 is listed on the TSCA inventory.
CAS# 7440-47-3 is listed on the TSCA inventory.
CAS# 7440-48-4 is listed on the TSCA inventory.
CAS# 7440-70-2 is listed on the TSCA inventory.
CAS# 7697-37-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
