Name:
Iodine Solution According to WIJS 0.1 Mol ICl/l
Synonym:
CAS:
64-19-7
Section 1 - Chemical Product
MSDS Name:Iodine Solution According to WIJS 0.1 Mol ICl/l
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-19-7 | Acetic acid | 98.37 | 200-580-7 |
| Hazard Symbols: C Risk Phrases: 10 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Causes burns.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. Ingestion of large amounts may cause nausea and vomiting, which can produce dehydration, internal organ congestion and possibly coma.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure can lead to iodism characterized by salivation, nasal discharge, sneezing, conjunctivitis, fever, laryngitis, bronchitis, stomatitis, and skin rashes.
Flammable. Causes burns.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. Ingestion of large amounts may cause nausea and vomiting, which can produce dehydration, internal organ congestion and possibly coma.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure can lead to iodism characterized by salivation, nasal discharge, sneezing, conjunctivitis, fever, laryngitis, bronchitis, stomatitis, and skin rashes.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Discard contaminated clothing in a manner which limits further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Discard contaminated clothing in a manner which limits further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam. Use agent most appropriate to extinguish fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam. Use agent most appropriate to extinguish fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 64-19-7: United States OSHA: 10 ppm TWA; 25 mg/m3 TWA Belgium - TWA: 10 ppm VLE; 25 mg/m3 VLE Belgium - STEL: 15 ppm VLE; 38 mg/m3 VLE France - VLE: 10 ppm VLE; 25 mg/m3 VLE Germany: 10 ppm TWA; 25 mg/m3 TWA Japan: 10 ppm OEL; 25 mg/m3 OEL Malaysia: 10 ppm TWA; 25 mg/m3 TWA Netherlands: 10 ppm MAC; 25 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 10 ppm VLA-ED; 25 mg/m3 VLA-ED Spain: 15 ppm VLA-EC; 37 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC CAS# 7782-50-5: United Kingdom, WEL - TWA: 0.5 ppm TWA; 1.5 mg/m3 TWA United Kingdom, WEL - STEL: 1 ppm STEL; 2.9 mg/m3 STEL United States OSHA: ; 1 ppm Ceiling; 3 mg/m3 Ceiling Belgium - TWA: 0.5 ppm VLE; 1.5 mg/m3 VLE Belgium - STEL: 1 ppm VLE; 2.9 mg/m3 VLE France - VLE: 1 ppm VLE; 3 mg/m3 VLE Germany: 0.5 ppm TWA; 1.5 mg/m3 TWA Japan: 0.5 ppm Ceiling; 1.5 mg/m3 Ceiling Malaysia: 0.5 ppm TWA; 1.5 mg/m3 TWA Russia: 1 mg/m3 TWA Spain: 0.5 ppm VLA-ED; 1.5 mg/m3 VLA-ED Spain: 1 ppm VLA-EC; 3 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 64-19-7: United States OSHA: 10 ppm TWA; 25 mg/m3 TWA Belgium - TWA: 10 ppm VLE; 25 mg/m3 VLE Belgium - STEL: 15 ppm VLE; 38 mg/m3 VLE France - VLE: 10 ppm VLE; 25 mg/m3 VLE Germany: 10 ppm TWA; 25 mg/m3 TWA Japan: 10 ppm OEL; 25 mg/m3 OEL Malaysia: 10 ppm TWA; 25 mg/m3 TWA Netherlands: 10 ppm MAC; 25 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 10 ppm VLA-ED; 25 mg/m3 VLA-ED Spain: 15 ppm VLA-EC; 37 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC CAS# 7782-50-5: United Kingdom, WEL - TWA: 0.5 ppm TWA; 1.5 mg/m3 TWA United Kingdom, WEL - STEL: 1 ppm STEL; 2.9 mg/m3 STEL United States OSHA: ; 1 ppm Ceiling; 3 mg/m3 Ceiling Belgium - TWA: 0.5 ppm VLE; 1.5 mg/m3 VLE Belgium - STEL: 1 ppm VLE; 2.9 mg/m3 VLE France - VLE: 1 ppm VLE; 3 mg/m3 VLE Germany: 0.5 ppm TWA; 1.5 mg/m3 TWA Japan: 0.5 ppm Ceiling; 1.5 mg/m3 Ceiling Malaysia: 0.5 ppm TWA; 1.5 mg/m3 TWA Russia: 1 mg/m3 TWA Spain: 0.5 ppm VLA-ED; 1.5 mg/m3 VLA-ED Spain: 1 ppm VLA-EC; 3 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: clear brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 40 deg C ( 104.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong bases.
Hazardous Decomposition Products:
Not available.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong bases.
Hazardous Decomposition Products:
Not available.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-19-7: AF1225000 CAS# 7553-56-2: NN1575000 CAS# 7782-50-5: FO2100000 LD50/LC50:
CAS# 64-19-7: Draize test, rabbit, skin: 50 mg/24H Mild; Inhalation, mouse: LC50 = 5620 ppm/1H; Oral, rat: LD50 = 3310 mg/kg; Skin, rabbit: LD50 = 1060 uL/kg.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
CAS# 7782-50-5: Inhalation, mouse: LC50 = 137 ppm/1H; Inhalation, mouse: LC50 = 368 mg/m3/30M; Inhalation, rat: LC50 = 293 ppm/1H.
Carcinogenicity:
Acetic acid - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
Chlorine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 64-19-7: AF1225000 CAS# 7553-56-2: NN1575000 CAS# 7782-50-5: FO2100000 LD50/LC50:
CAS# 64-19-7: Draize test, rabbit, skin: 50 mg/24H Mild; Inhalation, mouse: LC50 = 5620 ppm/1H; Oral, rat: LD50 = 3310 mg/kg; Skin, rabbit: LD50 = 1060 uL/kg.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
CAS# 7782-50-5: Inhalation, mouse: LC50 = 137 ppm/1H; Inhalation, mouse: LC50 = 368 mg/m3/30M; Inhalation, rat: LC50 = 293 ppm/1H.
Carcinogenicity:
Acetic acid - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
Chlorine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
USA RQ: CAS# 64-19-7: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 7782-50-5: 10 lb final RQ; 4.54 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 25 Avoid contact with eyes.
WGK (Water Danger/Protection)
CAS# 64-19-7: 1
CAS# 7553-56-2: 1
CAS# 7782-50-5: 2
Canada
CAS# 64-19-7 is listed on Canadas DSL List.
CAS# 7553-56-2 is listed on Canadas DSL List.
CAS# 7782-50-5 is listed on Canadas DSL List.
CAS# 64-19-7 is listed on Canadas Ingredient Disclosure List.
CAS# 7553-56-2 is listed on Canadas Ingredient Disclosure List.
CAS# 7782-50-5 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-19-7 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
CAS# 7782-50-5 is listed on the TSCA inventory.
