Name:
Iron electrolytically reduced reagent (powder)
Synonym:
CAS:
7439-89-6
Section 1 - Chemical Product
MSDS Name:Iron electrolytically reduced reagent (powder)
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7439-89-6 | IRON | >97 | 231-096-4 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Exposure to particulates or solution may cause conjunctivitis, ulceration, and corneal abnormalities. Deposition of particles may cause corneal discoloration.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause lung damage.
Chronic:
Chronic exposure may lead to liver and lung damage. Repeated exposure may cause pancreatic damage, diabetes, and cardiac abnormalities.
Not available.
Potential Health Effects
Eye:
Exposure to particulates or solution may cause conjunctivitis, ulceration, and corneal abnormalities. Deposition of particles may cause corneal discoloration.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause lung damage.
Chronic:
Chronic exposure may lead to liver and lung damage. Repeated exposure may cause pancreatic damage, diabetes, and cardiac abnormalities.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Antidote: The use of Deferoxamine as a chelating agent should be determined only by qualified medical personnel.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Antidote: The use of Deferoxamine as a chelating agent should be determined only by qualified medical personnel.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. Combustion generates toxic fumes.
Extinguishing Media:
Use only graphite powder, soda ash, powdered sodium chloride, or an appropriate metal-fire-extinguishing dry powder.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. Combustion generates toxic fumes.
Extinguishing Media:
Use only graphite powder, soda ash, powdered sodium chloride, or an appropriate metal-fire-extinguishing dry powder.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.
Remove all sources of ignition.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.
Remove all sources of ignition.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 7439-89-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 7439-89-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Powder
Color: black
Odor: None reported.
pH: Not available.
Vapor Pressure: 1 mm Hg @ 1787C
Viscosity: Not available.
Boiling Point: 3000 deg C
Freezing/Melting Point: 1535 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 7.86 g/cm3
Molecular Formula: Fe
Molecular Weight: 55.84
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. Decomposes when heated. Oxidizes when exposed to air.
Conditions to Avoid:
Incompatible materials, moisture, exposure to air, excess heat.
Incompatibilities with Other Materials:
Acetaldehyde, ammonium peroxodisulfate, chloroformamidinium, chloric acid, ammonium nitrate, halogens, dinitrogen tetroxide, nitryl fluoride, polystyrene, sodium acetylide, potassium dichromate, peroxyformic acid, nitryl fluoride, sulfuric acid, sodium carbide.
Hazardous Decomposition Products:
Oxides of iron.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures. Decomposes when heated. Oxidizes when exposed to air.
Conditions to Avoid:
Incompatible materials, moisture, exposure to air, excess heat.
Incompatibilities with Other Materials:
Acetaldehyde, ammonium peroxodisulfate, chloroformamidinium, chloric acid, ammonium nitrate, halogens, dinitrogen tetroxide, nitryl fluoride, polystyrene, sodium acetylide, potassium dichromate, peroxyformic acid, nitryl fluoride, sulfuric acid, sodium carbide.
Hazardous Decomposition Products:
Oxides of iron.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7439-89-6: NO4565500 NO8225000 LD50/LC50:
CAS# 7439-89-6: Oral, rat: LD50 = 30 gm/kg.
Carcinogenicity:
IRON - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7439-89-6: NO4565500 NO8225000 LD50/LC50:
CAS# 7439-89-6: Oral, rat: LD50 = 30 gm/kg.
Carcinogenicity:
IRON - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7439-89-6: 0
Canada
CAS# 7439-89-6 is listed on Canadas DSL List.
CAS# 7439-89-6 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7439-89-6 is listed on the TSCA inventory.
