Name:
Isobornyl methacrylate 85-90% (stabilized with ~200 ppm MEHQ)
Synonym:
(1,7,7-Trimethyltricyclo[2.2.1]hepten-2-yl)-2-methyl-2-propenoate
CAS:
150-76-5
Section 1 - Chemical Product
MSDS Name:Isobornyl methacrylate 85-90% (stabilized with ~200 ppm MEHQ)
Synonym:(1,7,7-Trimethyltricyclo[2.2.1]hepten-2-yl)-2-methyl-2-propenoate
Synonym:(1,7,7-Trimethyltricyclo[2.2.1]hepten-2-yl)-2-methyl-2-propenoate
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 150-76-5 | 4-Methoxyphenol | .02 | 205-769-8 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.
Not available.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigeration has been recommended.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigeration has been recommended.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 150-76-5: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED CAS# 7534-94-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 150-76-5: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED CAS# 7534-94-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 245 deg C @ 760mmHg
Freezing/Melting Point: -60 deg C
Autoignition Temperature: Not available.
Flash Point: 101 deg C ( 213.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: negligible
Specific Gravity/Density: .9800g/cm3
Molecular Formula: C14H22O2
Molecular Weight: 222.33
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable only if stored and handled under recommended conditions. The stability of the product depends upon the availability of both dissolved oxygen and MEHQ inhibitor(CAS=150-76-5). The presence of oxygen is necessary for the MEHQ to function effectively. The product should never be stored under an inert gas atmosphere, but should always be stored under an atmosphere containing 5-21% oxygen by volume.
Conditions to Avoid:
Incompatible materials, excess heat, electrical sparks, exposure to flame, loss of inhibitor.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, peroxides.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.
Stable only if stored and handled under recommended conditions. The stability of the product depends upon the availability of both dissolved oxygen and MEHQ inhibitor(CAS=150-76-5). The presence of oxygen is necessary for the MEHQ to function effectively. The product should never be stored under an inert gas atmosphere, but should always be stored under an atmosphere containing 5-21% oxygen by volume.
Conditions to Avoid:
Incompatible materials, excess heat, electrical sparks, exposure to flame, loss of inhibitor.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, peroxides.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 150-76-5: SL7700000 CAS# 7534-94-3 unlisted.
LD50/LC50:
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
CAS# 7534-94-3.
Carcinogenicity:
4-Methoxyphenol - Not listed by ACGIH, IARC, or NTP.
Isobornyl methacrylate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 150-76-5: SL7700000 CAS# 7534-94-3 unlisted.
LD50/LC50:
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
CAS# 7534-94-3.
Carcinogenicity:
4-Methoxyphenol - Not listed by ACGIH, IARC, or NTP.
Isobornyl methacrylate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 150-76-5: 1
CAS# 7534-94-3: 1
Canada
CAS# 150-76-5 is listed on Canadas DSL List.
CAS# 7534-94-3 is listed on Canadas DSL List.
CAS# 150-76-5 is listed on Canadas Ingredient Disclosure List.
CAS# 7534-94-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 150-76-5 is listed on the TSCA inventory.
CAS# 7534-94-3 is listed on the TSCA inventory.
