Name:
Isopropyl glycidyl ether 98%
Synonym:
1(Methylethoxy)-methyloxirane; ((1-Methylethoxy)methyl)oxirane; (Isopropoxymethyl)oxirane; 1,2-Epoxy-3-isopropoxypropane; 2,3-Epoxypropyl isopropyl ether; 3-Isopropyloxypropylene oxide; Ether, 2,3-epoxypropyl isopropyl; Glycidyl isopropyl ethe
CAS:
4016-14-2
Section 1 - Chemical Product
MSDS Name:Isopropyl glycidyl ether 98%
Synonym:1(Methylethoxy)-methyloxirane; ((1-Methylethoxy)methyl)oxirane; (Isopropoxymethyl)oxirane; 1,2-Epoxy-3-isopropoxypropane; 2,3-Epoxypropyl isopropyl ether; 3-Isopropyloxypropylene oxide; Ether, 2,3-epoxypropyl isopropyl; Glycidyl isopropyl ethe
Synonym:1(Methylethoxy)-methyloxirane; ((1-Methylethoxy)methyl)oxirane; (Isopropoxymethyl)oxirane; 1,2-Epoxy-3-isopropoxypropane; 2,3-Epoxypropyl isopropyl ether; 3-Isopropyloxypropylene oxide; Ether, 2,3-epoxypropyl isopropyl; Glycidyl isopropyl ethe
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 4016-14-2 | Isopropyl glycidyl ether | 98 | 223-672-9 |
| Hazard Symbols: XI Risk Phrases: 10 19 42/43 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. May form explosive peroxides. May cause sensitization by inhalation and skin contact.Moisture sensitive.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Vapors may cause eye irritation. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation. May cause dermatitis. May cause cyanosis of the extremities. May cause sensitization by skin contact.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest.
Chronic:
Effects may be delayed.
Flammable. May form explosive peroxides. May cause sensitization by inhalation and skin contact.Moisture sensitive.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Vapors may cause eye irritation. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation. May cause dermatitis. May cause cyanosis of the extremities. May cause sensitization by skin contact.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest.
Chronic:
Effects may be delayed.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors.
Section 7 - HANDLING and STORAGE
Handling:
Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not ingest or inhale. Store protected from light. Handle under an inert atmosphere.
Store protected from air. Do not allow contact with water. Use only in a chemical fume hood. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area. Do not expose to air. Store protected from moisture.
Store protected from light. Store under an inert atmosphere.
Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not ingest or inhale. Store protected from light. Handle under an inert atmosphere.
Store protected from air. Do not allow contact with water. Use only in a chemical fume hood. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area. Do not expose to air. Store protected from moisture.
Store protected from light. Store under an inert atmosphere.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 4016-14-2: United States OSHA: 50 ppm TWA; 240 mg/m3 TWA Belgium - TWA: 50 ppm VLE; 241 mg/m3 VLE Belgium - STEL: 75 ppm VLE; 361 mg/m3 VLE France - VME: 50 ppm VME; 240 mg/m3 VME Malaysia: 50 ppm TWA; 238 mg/m3 TWA Netherlands: 0.1 ppm MAC; 0.5 mg/m3 MAC Spain: 50 ppm VLA-ED; 241 mg/m3 VLA-ED Spain: 75 ppm VLA-EC; 362 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 4016-14-2: United States OSHA: 50 ppm TWA; 240 mg/m3 TWA Belgium - TWA: 50 ppm VLE; 241 mg/m3 VLE Belgium - STEL: 75 ppm VLE; 361 mg/m3 VLE France - VME: 50 ppm VME; 240 mg/m3 VME Malaysia: 50 ppm TWA; 238 mg/m3 TWA Netherlands: 0.1 ppm MAC; 0.5 mg/m3 MAC Spain: 50 ppm VLA-ED; 241 mg/m3 VLA-ED Spain: 75 ppm VLA-EC; 362 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 9.4 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 137 deg C @ 760.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 35 deg C ( 95.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 188 g/l (19 c)
Specific Gravity/Density: .9200g/cm3
Molecular Formula: C6H10O2
Molecular Weight: 116.16
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. May form explosive peroxides. Air sensitive.
Moisture sensitive. Light sensitive.
Conditions to Avoid:
Incompatible materials, light, ignition sources, moisture, exposure to air, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Moisture, air, strong oxidizing agents, strong bases, acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable at room temperature in closed containers under normal storage and handling conditions. May form explosive peroxides. Air sensitive.
Moisture sensitive. Light sensitive.
Conditions to Avoid:
Incompatible materials, light, ignition sources, moisture, exposure to air, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Moisture, air, strong oxidizing agents, strong bases, acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 4016-14-2: TZ3500000 LD50/LC50:
CAS# 4016-14-2: Draize test, rabbit, eye: 92 mg Moderate; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 459 mg/3D Moderate; Draize test, rabbit, skin: 100 mg/24H Moderate; Inhalation, mouse: LC50 = 1500 ppm/4H; Inhalation, rat: LC50 = 1100 ppm/8H; Oral, mouse: LD50 = 1300 mg/kg; Oral, rat: LD50 = 4200 mg/kg; Skin, rabbit: LD50 = 9650 mg/kg.
Carcinogenicity:
Isopropyl glycidyl ether - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 4016-14-2: TZ3500000 LD50/LC50:
CAS# 4016-14-2: Draize test, rabbit, eye: 92 mg Moderate; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 459 mg/3D Moderate; Draize test, rabbit, skin: 100 mg/24H Moderate; Inhalation, mouse: LC50 = 1500 ppm/4H; Inhalation, rat: LC50 = 1100 ppm/8H; Oral, mouse: LD50 = 1300 mg/kg; Oral, rat: LD50 = 4200 mg/kg; Skin, rabbit: LD50 = 9650 mg/kg.
Carcinogenicity:
Isopropyl glycidyl ether - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 19 May form explosive peroxides.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 4016-14-2: 2
Canada
CAS# 4016-14-2 is listed on Canadas NDSL List.
CAS# 4016-14-2 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4016-14-2 is listed on the TSCA inventory.
