Name:
Lead (II) Perchlorate Trihydrate 95%
Synonym:
None
CAS:
13453-62-8
Section 1 - Chemical Product
MSDS Name:Lead (II) Perchlorate Trihydrate 95%
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 13453-62-8 | Lead (II) Perchlorate Trihydrate | 95 | unlisted |
| Hazard Symbols: T O Risk Phrases: 20/22 33 8 61 62 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Danger of cumulative effects. Contact with combustible material may cause fire. May cause harm to the unborn child. Possible risk of impaired fertility.Light sensitive.Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of lead compounds can cause toxic effects in the blood-forming organs, kidneys and central nervous system. Ingestion of lead compounds can produce symptoms of lead poisoning.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Chronic exposure to lead may result in plumbism which is characterized by lead line in gum, headache, muscle weakness, mental changes.
Harmful by inhalation and if swallowed. Danger of cumulative effects. Contact with combustible material may cause fire. May cause harm to the unborn child. Possible risk of impaired fertility.Light sensitive.Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of lead compounds can cause toxic effects in the blood-forming organs, kidneys and central nervous system. Ingestion of lead compounds can produce symptoms of lead poisoning.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Chronic exposure to lead may result in plumbism which is characterized by lead line in gum, headache, muscle weakness, mental changes.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Contact professional fire-fighters immediately.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Contact professional fire-fighters immediately.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Isolate area and deny entry. Provide ventilation. In case of spill, sweep up solid or absorb liquid with inert material, then place into a biohazard container. Wear protective equipment. Place under an inert atmosphere. Do not get water inside containers.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Isolate area and deny entry. Provide ventilation. In case of spill, sweep up solid or absorb liquid with inert material, then place into a biohazard container. Wear protective equipment. Place under an inert atmosphere. Do not get water inside containers.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation.
Store protected from light. Do not allow contact with water. If peroxide formation is suspected, do not open or move container.
Avoid contact with air and sunlight. Keep from contact with moist air and steam. Unused chemicals should not be returned to the container. Do not distill since this removes peroxide-inhibitors.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Regularly check inhibitor levels to maintain peroxide levels below 1%. Store protected from moisture. Store protected from light. Do not break the seal on the container until it is needed. Label the container with the date it was first opened. Long-term storage is not recommended.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation.
Store protected from light. Do not allow contact with water. If peroxide formation is suspected, do not open or move container.
Avoid contact with air and sunlight. Keep from contact with moist air and steam. Unused chemicals should not be returned to the container. Do not distill since this removes peroxide-inhibitors.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Regularly check inhibitor levels to maintain peroxide levels below 1%. Store protected from moisture. Store protected from light. Do not break the seal on the container until it is needed. Label the container with the date it was first opened. Long-term storage is not recommended.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystals
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 100C dec
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: > 100 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 2.6000
Molecular Formula: PbCl2O8H6O3
Molecular Weight: 460.1414
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable. On long term storage, substances with similar functional groups form explosive peroxides. Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating. Tends to form explosive peroxides; especially when anhydrous. Peroxide formation may occur in containers that have been opened and remain in storage.
Conditions to Avoid:
Incompatible materials, light, ignition sources, dust generation, moisture, exposure to air, combustible materials, reducing agents, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, lead/lead oxides, chloride fumes.
Hazardous Polymerization: Has not been reported
Stable. On long term storage, substances with similar functional groups form explosive peroxides. Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating. Tends to form explosive peroxides; especially when anhydrous. Peroxide formation may occur in containers that have been opened and remain in storage.
Conditions to Avoid:
Incompatible materials, light, ignition sources, dust generation, moisture, exposure to air, combustible materials, reducing agents, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, lead/lead oxides, chloride fumes.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13453-62-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Lead (II) Perchlorate Trihydrate - California: carcinogen, initial date 10/1/92 (listed as Lead compounds See actual entry in RTECS for complete information.
CAS# 13453-62-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Lead (II) Perchlorate Trihydrate - California: carcinogen, initial date 10/1/92 (listed as Lead compounds See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: LEAD PERCHLORATE
Hazard Class: 5.1
UN Number: 1470
Packing Group: II
IMO
Shipping Name: LEAD PERCHLORATE
Hazard Class: 5.1
UN Number: 1470
Packing Group: II
RID/ADR
Shipping Name: LEAD PERCHLORATE
Hazard Class: 5.1
UN Number: 1470
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T O
Risk Phrases:
R 61 May cause harm to the unborn child.
R 20/22 Harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 62 Possible risk of impaired fertility.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13453-62-8: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
CAS# 13453-62-8: MEL-United Kingdom, TWA (listed as ** undefined
**): 0.15 mg/m3 TWA (except lead alkyls - see CLAW regulations)
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13453-62-8 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 13453-62-8: Not available.
US FEDERAL
TSCA
CAS# 13453-62-8 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
