Name:
Lead(II) perchlorate trihydrate
Synonym:
Perchloric acid, lead(2+) salt, trihydrate
CAS:
13453-62-8
Section 1 - Chemical Product
MSDS Name:Lead(II) perchlorate trihydrate
Synonym:Perchloric acid, lead(2+) salt, trihydrate
Synonym:Perchloric acid, lead(2+) salt, trihydrate
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 13453-62-8 | Lead(II) perchlorate trihydrate | >95 | unlisted |
| Hazard Symbols: T O N Risk Phrases: 20/22 33 8 61 62 50/53 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Danger of cumulative effects. Contact with combustible material may cause fire. May cause harm to the unborn child. Possible risk of impaired fertility. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
Ingestion of lead compounds can cause toxic effects in the blood-forming organs, kidneys and central nervous system. Ingestion of lead compounds can produce symptoms of lead poisoning. Symptoms of lead poisoning or plumbism include weakness, weight loss, lassitude, insomnia, and hypotension. It also includes constipation, anorexia, abdominal discomfort and colic.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Chronic exposure to lead may result in plumbism which is characterized by lead line in gum, headache, muscle weakness, mental changes. Chronic expsoure to lead may cause adverse effects on human reproduction, embryonic and fetal development and postnatal (e.g., mental) development.
Harmful by inhalation and if swallowed. Danger of cumulative effects. Contact with combustible material may cause fire. May cause harm to the unborn child. Possible risk of impaired fertility. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
Ingestion of lead compounds can cause toxic effects in the blood-forming organs, kidneys and central nervous system. Ingestion of lead compounds can produce symptoms of lead poisoning. Symptoms of lead poisoning or plumbism include weakness, weight loss, lassitude, insomnia, and hypotension. It also includes constipation, anorexia, abdominal discomfort and colic.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Chronic exposure to lead may result in plumbism which is characterized by lead line in gum, headache, muscle weakness, mental changes. Chronic expsoure to lead may cause adverse effects on human reproduction, embryonic and fetal development and postnatal (e.g., mental) development.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Use water with caution and in flooding amounts.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Use water with caution and in flooding amounts.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Provide ventilation. Keep combustibles (wood, paper, oil, etc.,) away from spilled material.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Provide ventilation. Keep combustibles (wood, paper, oil, etc.,) away from spilled material.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Keep from contact with clothing and other combustible materials. Avoid breathing dust.
Storage:
Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Keep from contact with clothing and other combustible materials. Avoid breathing dust.
Storage:
Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 13453-62-8: United Kingdom, WEL - TWA: (listed as lead compounds): 0.15 mg/m3 (as Pb) United Kingdom, WEL - STEL: (listed as lead compounds): 0.45 mg/m TWA (as Pb) United States OSHA: 50 ??g/m3 TWA (as Pb); 30 ??g/m3 Action Level ( Pb. Poison - see 29 CFR 1910.10 25) (listed under Lead, inorgani compounds).
Belgium - TWA: (listed as lead, inorganic compounds): 0.15 mg/m3 (dust and fume) France - VME: (listed as lead compounds): 0.1 mg/m3 VME (as Pb) Germany: (listed as lead compounds): 0.1 mg/m3 VME (as Pb) Japan: (listed as lead compounds): 0.1 mg/m3 OEL (except alkyl le compounds, as Pb) Malaysia: (listed as lead, inorganic compounds): 0.05 mg/m3 TWA ( Pb) Netherlands: (listed as lead, inorganic compounds): 0.15 mg/m3 MA (dust and smoke, as Pb) Russia: (listed as lead, inorganic compounds): 0.5 mg/m3 TWA (as Spain: (listed as lead, inorganic compounds): 0.15 mg/m3 VLA-ED ( Pb) CAS# 13637-76-8: United Kingdom, WEL - TWA: (listed as lead compounds): 0.15 mg/m3 (as Pb) United Kingdom, WEL - STEL: (listed as lead compounds): 0.45 mg/m TWA (as Pb) United States OSHA: 50 ??g/m3 TWA (as Pb); 30 ??g/m3 Action Level ( Pb. Poison - see 29 CFR 1910.10 25) (listed under Lead, inorgani compounds).
Belgium - TWA: (listed as lead, inorganic compounds): 0.15 mg/m3 (dust and fume) France - VME: (listed as lead compounds): 0.1 mg/m3 VME (as Pb) Germany: (listed as lead compounds): 0.1 mg/m3 VME (as Pb) Japan: (listed as lead compounds): 0.1 mg/m3 OEL (except alkyl le compounds, as Pb) Malaysia: (listed as lead, inorganic compounds): 0.05 mg/m3 TWA ( Pb) Netherlands: (listed as lead, inorganic compounds): 0.15 mg/m3 MA (dust and smoke, as Pb) Russia: (listed as lead, inorganic compounds): 0.5 mg/m3 TWA (as Spain: (listed as lead, inorganic compounds): 0.15 mg/m3 VLA-ED ( Pb) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Refer to 29 CFR1910.1025 for regulations on respiratory protection required during exposure to lead and lead compounds.
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 13453-62-8: United Kingdom, WEL - TWA: (listed as lead compounds): 0.15 mg/m3 (as Pb) United Kingdom, WEL - STEL: (listed as lead compounds): 0.45 mg/m TWA (as Pb) United States OSHA: 50 ??g/m3 TWA (as Pb); 30 ??g/m3 Action Level ( Pb. Poison - see 29 CFR 1910.10 25) (listed under Lead, inorgani compounds).
Belgium - TWA: (listed as lead, inorganic compounds): 0.15 mg/m3 (dust and fume) France - VME: (listed as lead compounds): 0.1 mg/m3 VME (as Pb) Germany: (listed as lead compounds): 0.1 mg/m3 VME (as Pb) Japan: (listed as lead compounds): 0.1 mg/m3 OEL (except alkyl le compounds, as Pb) Malaysia: (listed as lead, inorganic compounds): 0.05 mg/m3 TWA ( Pb) Netherlands: (listed as lead, inorganic compounds): 0.15 mg/m3 MA (dust and smoke, as Pb) Russia: (listed as lead, inorganic compounds): 0.5 mg/m3 TWA (as Spain: (listed as lead, inorganic compounds): 0.15 mg/m3 VLA-ED ( Pb) CAS# 13637-76-8: United Kingdom, WEL - TWA: (listed as lead compounds): 0.15 mg/m3 (as Pb) United Kingdom, WEL - STEL: (listed as lead compounds): 0.45 mg/m TWA (as Pb) United States OSHA: 50 ??g/m3 TWA (as Pb); 30 ??g/m3 Action Level ( Pb. Poison - see 29 CFR 1910.10 25) (listed under Lead, inorgani compounds).
Belgium - TWA: (listed as lead, inorganic compounds): 0.15 mg/m3 (dust and fume) France - VME: (listed as lead compounds): 0.1 mg/m3 VME (as Pb) Germany: (listed as lead compounds): 0.1 mg/m3 VME (as Pb) Japan: (listed as lead compounds): 0.1 mg/m3 OEL (except alkyl le compounds, as Pb) Malaysia: (listed as lead, inorganic compounds): 0.05 mg/m3 TWA ( Pb) Netherlands: (listed as lead, inorganic compounds): 0.15 mg/m3 MA (dust and smoke, as Pb) Russia: (listed as lead, inorganic compounds): 0.5 mg/m3 TWA (as Spain: (listed as lead, inorganic compounds): 0.15 mg/m3 VLA-ED ( Pb) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Refer to 29 CFR1910.1025 for regulations on respiratory protection required during exposure to lead and lead compounds.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystals
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 100 deg C (dec)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: 100 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 2.6000
Molecular Formula: PbCl2O8H6O3
Molecular Weight: 460.14
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Has not been fully evaluated.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong reducing agents, organic matter, combustible materials.
Hazardous Decomposition Products:
Lead/lead oxides, chloride fumes.
Hazardous Polymerization: Has not been reported
Has not been fully evaluated.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong reducing agents, organic matter, combustible materials.
Hazardous Decomposition Products:
Lead/lead oxides, chloride fumes.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13453-62-8 unlisted.
CAS# 13637-76-8: SC8100000 LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Lead(II) perchlorate trihydrate - California: carcinogen, initial date 10/1/92 (listed as Lead compounds NTP: Suspect carcinogen (listed as Lead compounds).
IARC: Group 2A carcinogen (listed as Lead, inorganic compounds).
Lead perchlorate - California: carcinogen, initial date 10/1/92 (listed as Lead compounds NTP: Suspect carcinogen (listed as Lead compounds).
IARC: Group 2A carcinogen (listed as Lead, inorganic compounds).
Other:
See actual entry in RTECS for complete information.
CAS# 13453-62-8 unlisted.
CAS# 13637-76-8: SC8100000 LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Lead(II) perchlorate trihydrate - California: carcinogen, initial date 10/1/92 (listed as Lead compounds NTP: Suspect carcinogen (listed as Lead compounds).
IARC: Group 2A carcinogen (listed as Lead, inorganic compounds).
Lead perchlorate - California: carcinogen, initial date 10/1/92 (listed as Lead compounds NTP: Suspect carcinogen (listed as Lead compounds).
IARC: Group 2A carcinogen (listed as Lead, inorganic compounds).
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: LEAD PERCHLORATE
Hazard Class: 5.1 (6.1)
UN Number: 1470
Packing Group: II
IMO
Shipping Name: LEAD PERCHLORATE
Hazard Class: 5.1 (6.1)
UN Number: 1470
Packing Group: II
RID/ADR
Shipping Name: LEAD PERCHLORATE
Hazard Class: 5.1
UN Number: 1470
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T O N
Risk Phrases:
R 61 May cause harm to the unborn child.
R 20/22 Harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 62 Possible risk of impaired fertility.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 17 Keep away from combustible material.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 13453-62-8: No information available.
CAS# 13637-76-8: 2
Canada
CAS# 13637-76-8 is listed on Canadas NDSL List.
CAS# 13453-62-8 is not listed on Canadas Ingredient Disclosure List.
CAS# 13637-76-8 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13453-62-8 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 13637-76-8 is listed on the TSCA inventory.
