Name:
Lithium bromide 0.05M solution in trifluoroethanol filtered over
Synonym:
None
CAS:
75-89-8
Section 1 - Chemical Product
MSDS Name:Lithium bromide 0.05M solution in trifluoroethanol filtered over
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 75-89-8 | 2,2,2-Trifluoroethanol | 99.6 | 200-913-6 |
| Hazard Symbols: XN Risk Phrases: 10 20/21/22 38 41 62 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to skin. Risk of serious damage to eyes.
Possible risk of impaired fertility.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
May cause anemia and other blood cell abnormalities.
Flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to skin. Risk of serious damage to eyes.
Possible risk of impaired fertility.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
May cause anemia and other blood cell abnormalities.
Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Get medical aid. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Get medical aid. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not ingest or inhale. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation.
Storage:
Keep away from heat, sparks, and flame. Keep container closed when not in use. Flammables-area.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not ingest or inhale. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation.
Storage:
Keep away from heat, sparks, and flame. Keep container closed when not in use. Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 75-89-8: Russia: 10 mg/m3 TWA CAS# 7550-35-8: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 75-89-8: Russia: 10 mg/m3 TWA CAS# 7550-35-8: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear, colorless
Odor: alcohol-like
pH: 5-7 (10% aq soln)
Vapor Pressure: 70 mm Hg @ 25 deg C
Viscosity: 1.75 cP 25 deg
Boiling Point: 73.6 deg C
Freezing/Melting Point: -45 deg C
Autoignition Temperature: 480 deg C ( 896.00 deg F)
Flash Point: 29 deg C ( 84.20 deg F)
Explosion Limits, lower: 5.5%
Explosion Limits, upper: 42%
Decomposition Temperature: 315 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 1.39 g/cm3
Molecular Formula: LiBr
Molecular Weight: 86.85
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, electrical sparks, exposure to flame, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, lithium oxide, bromide fumes.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, electrical sparks, exposure to flame, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, lithium oxide, bromide fumes.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 75-89-8: KM5250000 CAS# 7550-35-8: OJ5755000 LD50/LC50:
CAS# 75-89-8: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 750 ug/24H Severe; Inhalation, mouse: LC50 = 2900 mg/m3/2H; Inhalation, mouse: LC50 = 2900 mg/m3/2H; Inhalation, rat: LC50 = 470 ppm/6H; Oral, mouse: LD50 = 366 mg/kg; Oral, rat: LD50 = 240 mg/kg; Skin, rabbit: LD50 = 390 uL/kg; Skin, rat: LD50 = 1680 mg/kg.
CAS# 7550-35-8: Oral, mouse: LD50 = 1840 mg/kg; Oral, mouse: LD50 = 2353 mg/kg; Oral, rat: LD50 = 1800 mg/kg.
Carcinogenicity:
2,2,2-Trifluoroethanol - Not listed by ACGIH, IARC, or NTP.
Lithium bromide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 75-89-8: KM5250000 CAS# 7550-35-8: OJ5755000 LD50/LC50:
CAS# 75-89-8: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 750 ug/24H Severe; Inhalation, mouse: LC50 = 2900 mg/m3/2H; Inhalation, mouse: LC50 = 2900 mg/m3/2H; Inhalation, rat: LC50 = 470 ppm/6H; Oral, mouse: LD50 = 366 mg/kg; Oral, rat: LD50 = 240 mg/kg; Skin, rabbit: LD50 = 390 uL/kg; Skin, rat: LD50 = 1680 mg/kg.
CAS# 7550-35-8: Oral, mouse: LD50 = 1840 mg/kg; Oral, mouse: LD50 = 2353 mg/kg; Oral, rat: LD50 = 1800 mg/kg.
Carcinogenicity:
2,2,2-Trifluoroethanol - Not listed by ACGIH, IARC, or NTP.
Lithium bromide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1992
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1992
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1992
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
R 62 Possible risk of impaired fertility.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-89-8: 1
CAS# 7550-35-8: 1
Canada
CAS# 75-89-8 is listed on Canadas DSL List.
CAS# 7550-35-8 is listed on Canadas DSL List.
CAS# 75-89-8 is not listed on Canadas Ingredient Disclosure List.
CAS# 7550-35-8 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-89-8 is listed on the TSCA inventory.
CAS# 7550-35-8 is listed on the TSCA inventory.
