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Name:
Magnesium turnings 99.9+%
Synonym:
Magnesium metal (ribbons/turnings
CAS:
7439-95-4
Section 1 - Chemical Product
MSDS Name:Magnesium turnings 99.9+%
Synonym:Magnesium metal (ribbons/turnings
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
7439-95-4
Hazard Symbols: F
Risk Phrases:

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Contact with water liberates highly flammable gases.Air sensitive.Moisture sensitive.Water-Reactive.
Potential Health Effects
Eye:
Dust may cause mechanical irritation.
Skin:
May cause skin irritation. Particles embedded in the skin may cause "chemical gas gangrene" with symptoms of persistent lesions, inflammation and gas bubbles under the skin.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Flammable solid. May react with acids or moisture to form explosive hydrogen gas.
Extinguishing Media:
Use only graphite powder, soda ash, powdered sodium chloride, or an appropriate metal-fire-extinguishing dry powder. Do NOT use water, carbon dioxide, or foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Water free area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: silver
Odor: None reported.
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 1107 deg C @ 760.00mm Hg
Freezing/Melting Point: 651 deg C
Autoignition Temperature: 883 deg F ( 472.78 deg C)
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts with water
Specific Gravity/Density: 1.7400g/cm3
Molecular Formula: Mg
Molecular Weight: 24.30

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to air, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxygen, moisture, chlorinated solvents, methanol, hydrogen peroxide, oxidizing agents, sulfur compounds, metal oxides, metal cyanides, metal oxide salts, fluorine, carbonates, halogens, phosphates.
Hazardous Decomposition Products:
Oxides of magnesium.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7439-95-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Magnesium - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: MAGNESIUM
Hazard Class: 4.1
UN Number: 1869
Packing Group: III
IMO
Shipping Name: MAGNESIUM
Hazard Class: 4.1
UN Number: 1869
Packing Group: III
RID/ADR
Shipping Name: MAGNESIUM
Hazard Class: 4.1
UN Number: 1869
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
R 15 Contact with water liberates highly flammable
gases.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 43A In case of fire, use dry chemical (never use
water).
WGK (Water Danger/Protection)
CAS# 7439-95-4: No information available.
United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7439-95-4 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 7439-95-4 is not listed on the TSCA inventory.
It is for research and development use only.