Name:
Magnesium perchlorate reagent ACS
Synonym:
Perchloric acid, magnesium sal
CAS:
10034-81-8
Section 1 - Chemical Product
MSDS Name:Magnesium perchlorate reagent ACS
Synonym:Perchloric acid, magnesium sal
Synonym:Perchloric acid, magnesium sal
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 10034-81-8 | Magnesium perchlorate, reagent ACS | ca. 100 | 233-108-3 |
| Hazard Symbols: XI O Risk Phrases: 36/37/38 8 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Contact with combustible material may cause fire.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.
Irritating to eyes, respiratory system and skin. Contact with combustible material may cause fire.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Some oxidizers may react explosively with hydrocarbons(fuel). May accelerate burning if involved in a fire. Containers may explode when heated. Runoff to sewer may create fire or explosion hazard.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool fire-exposed containers. Do NOT get water inside containers. Contact professional fire-fighters immediately. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Some oxidizers may react explosively with hydrocarbons(fuel). May accelerate burning if involved in a fire. Containers may explode when heated. Runoff to sewer may create fire or explosion hazard.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool fire-exposed containers. Do NOT get water inside containers. Contact professional fire-fighters immediately. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. Do not use combustible materials such as paper towels to clean up spill.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. Do not use combustible materials such as paper towels to clean up spill.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Do not ingest or inhale. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Store protected from moisture.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Do not ingest or inhale. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Store protected from moisture.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10034-81-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10034-81-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystalline powder
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 251 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >250 deg C
Solubility in water: 993 g/L water (25C)
Specific Gravity/Density: 2.60 g/mL @ 25C
Molecular Formula: Mg(ClO4)2
Molecular Weight: 223.21
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. Combines vigorously with water with the evolution of heat.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture, excess heat, combustible materials, organic materials, reducing agents, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, moisture, organic matter, trimethyl phosphate, alkenes, hydrazine, alcohols, metal powders, strong reducing agents, strong acids, mineral acids, ammonia, butyl fluoride, phosphorus, dimethyl sulfoxide, ethylene oxide, hydrocarbons.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of magnesium.
Hazardous Polymerization: Will not occur.
Stable at room temperature in closed containers under normal storage and handling conditions. Combines vigorously with water with the evolution of heat.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture, excess heat, combustible materials, organic materials, reducing agents, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, moisture, organic matter, trimethyl phosphate, alkenes, hydrazine, alcohols, metal powders, strong reducing agents, strong acids, mineral acids, ammonia, butyl fluoride, phosphorus, dimethyl sulfoxide, ethylene oxide, hydrocarbons.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of magnesium.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10034-81-8: SC8925000 LD50/LC50:
Not available.
Carcinogenicity:
Magnesium perchlorate, reagent ACS - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 10034-81-8: SC8925000 LD50/LC50:
Not available.
Carcinogenicity:
Magnesium perchlorate, reagent ACS - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: MAGNESIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1475
Packing Group: II
IMO
Shipping Name: MAGNESIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1475
Packing Group: II
RID/ADR
Shipping Name: MAGNESIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1475
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 10034-81-8: 1
Canada
CAS# 10034-81-8 is listed on Canadas DSL List.
CAS# 10034-81-8 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10034-81-8 is listed on the TSCA inventory.
