Name:
Manganese Standard metal Solution
Synonym:
Non
CAS:
7439-96-5
Section 1 - Chemical Product
MSDS Name:Manganese Standard metal Solution
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7439-96-5 | Manganese | 1000 ppm | 231-105-1 |
| Hazard Symbols: C Risk Phrases: 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the digestive tract.
Inhalation:
May be fatal if inhaled. Effects may be delayed.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth.
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the digestive tract.
Inhalation:
May be fatal if inhaled. Effects may be delayed.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Skin:
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Substance is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Substance is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate Personal protection. (See Exposure Controls, Personal Protection section). Neutralize spill with sodium bicarbonate. Use water spray to disperse the gas/vapor.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate Personal protection. (See Exposure Controls, Personal Protection section). Neutralize spill with sodium bicarbonate. Use water spray to disperse the gas/vapor.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get on skin or in eyes. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get on skin or in eyes. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR ??1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirators use.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR ??1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirators use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: colourless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.0
Molecular Formula: Solution
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Nitric acid reacts with over 150 chemical combinations. Refer to NFPA Fire Protection Guide for specifics. Reacts explosively with organic materials and combustibles.
Hazardous Decomposition Products:
Nitrogen oxides.
Hazardous Polymerization: Has not been reported
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Nitric acid reacts with over 150 chemical combinations. Refer to NFPA Fire Protection Guide for specifics. Reacts explosively with organic materials and combustibles.
Hazardous Decomposition Products:
Nitrogen oxides.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7439-96-5: OO9275000 CAS# 7697-37-2: QU5775000 QU5900000 LD50/LC50:
CAS# 7439-96-5: Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 9 gm/kg.
CAS# 7697-37-2: Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
Carcinogenicity:
Manganese - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Nitric acid 1M - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
CAS# 7439-96-5: OO9275000 CAS# 7697-37-2: QU5775000 QU5900000 LD50/LC50:
CAS# 7439-96-5: Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 9 gm/kg.
CAS# 7697-37-2: Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
Carcinogenicity:
Manganese - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Nitric acid 1M - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Nitric Acid: Mosquito fish: TLm=72 ppm/96H (fresh water) Cockle: LC50=330-1000 ppm/48H (salt water)
Nitric Acid: Mosquito fish: TLm=72 ppm/96H (fresh water) Cockle: LC50=330-1000 ppm/48H (salt water)
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, NOS
Hazard Class: 8
UN Number: 3264
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, NOS
Hazard Class: 8
UN Number: 3264
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, NOS
Dangerous Goods Code: 8
UN Number: 3264
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7439-96-5: No information available.
CAS# 7697-37-2: 1
United Kingdom Occupational Exposure Limits
CAS# 7439-96-5: OES-United Kingdom, TWA fume, as Mn: 1 mg/m3 TWA;
metal, as Mn: 5 mg/m3 TWA
CAS# 7439-96-5: OES-United Kingdom, STEL fume, as Mn: 3 mg/m3 STEL
Canada
CAS# 7439-96-5 is listed on Canadas DSL List.
CAS# 7697-37-2 is listed on Canadas DSL List.
CAS# 7439-96-5 is listed on Canadas Ingredient Disclosure List.
CAS# 7697-37-2 is listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 7439-96-5: OEL-ARAB Republic of Egypt:TWA 5 mg/m3
OEL-AUSTRALIA:TWA 1 mg/m3;STEL 3 mg/m3 (fume)
OEL-BELGIUM:TWA 1 mg/m3;STEL 3 mg/m3 (fume)
OEL-DENMARK:TWA 1 mg/m3 (fume)
OEL-DENMARK:TWA 2.5 mg/m3
OEL-FINLAND:TWA 1 mg/m3 (fume)
OEL-FINLAND:TWA 2.5 mg/m3
OEL-FRANCE:TWA 1 mg/m3 (fume)
OEL-GERMANY:TWA 5 mg/m3
OEL-THE PHILIPPINES:TWA 5 mg/m3
OEL-RUSSIA:STEL 0.2 mg/m3 (fume)
OEL-SWEDEN:TWA 2.5 mg/m3
OEL-SWITZERLAND:TWA 1 mg/m3 (fume)
OEL-SWITZERLAND:TWA 5 mg/m3
OEL-THAILAND:TWA 5 mg/m3
OEL-TURKEY:TWA 5 mg/m3 (fume)
OEL-UNITED KINGDOM:TWA 1 mg/m3;STEL 3 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 7697-37-2: OEL-ARAB Republic of Egypt:TWA 2 ppm (5 mg/m3)
OEL-AUSTRALIA:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3)
OEL-BELGIUM:TWA 2 ppm (5.2 mg/m3);STEL 4 ppm (10 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 2.5 mg/m3;STEL 5 mg/m3
OEL-DENMARK:TWA 2 ppm (5 mg/m3)
OEL-FINLAND:TWA 2 ppm (5 mg/m3);STEL 5 ppm (13 mg/m3);Skin
OEL-FRANCE:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3)
OEL-GERMANY:TWA 10 ppm (25 mg/m3)
OEL-HUNGARY:STEL 5 mg/m3
OEL-JAPAN:TWA 2 ppm (5.2 mg/m3)
OEL-THE PHILIPPINES:TWA 2 ppm (5 mg/m3)
OEL-POLAND:TWA 10 mg/m3
OEL-RUSSIA:TWA 2 ppm;STEL 2 mg/m3;Skin
OEL-SWEDEN:TWA 2 ppm (5 mg/m3);STEL 5 ppm (13 mg/m3)
OEL-SWITZERLAND:TWA 2 ppm (5 mg/m3);STEL 4 ppm (1 mg/m3)
OEL-THAILAND:TWA 2 ppm (5 mg/m3)
OEL-TURKEY:TWA 2 ppm (5 mg/m3)
OEL-UNITED KINGDOM:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7439-96-5 is listed on the TSCA inventory.
CAS# 7697-37-2 is listed on the TSCA inventory.
