Name:
Methyl Methacrylate-D8 99.5 Atom % D Stabilized with 100 ppm
Synonym:
Methyl Methacrylate Monomer; Methacrylic Acid Methyl Ester; alpha-Methacrylic Acid
CAS:
0-00-1
Section 1 - Chemical Product
MSDS Name:Methyl Methacrylate-D8 99.5 Atom % D Stabilized with 100 ppm
Synonym:Methyl Methacrylate Monomer; Methacrylic Acid Methyl Ester; alpha-Methacrylic Acid
Synonym:Methyl Methacrylate Monomer; Methacrylic Acid Methyl Ester; alpha-Methacrylic Acid
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 0-00-1 |
| Hazard Symbols: XI F Risk Phrases: |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and skin.
May cause sensitization by skin contact.Hygroscopic (absorbs moisture from the air).Corrosive.Light sensitive.Air sensitive.Heat sensitive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns. May cause eye injury. Lachrymator (substance which increases the flow of tears).
Skin:
May cause severe skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause allergic reaction.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause allergic respiratory reaction. May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. May cause reproductive and fetal effects. Repeated exposure may cause tingling in the extremities and other nervous system abnormalities.
Highly flammable. Irritating to eyes, respiratory system and skin.
May cause sensitization by skin contact.Hygroscopic (absorbs moisture from the air).Corrosive.Light sensitive.Air sensitive.Heat sensitive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns. May cause eye injury. Lachrymator (substance which increases the flow of tears).
Skin:
May cause severe skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause allergic reaction.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause allergic respiratory reaction. May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. May cause reproductive and fetal effects. Repeated exposure may cause tingling in the extremities and other nervous system abnormalities.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Vapor may cause flash fire. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May polymerize explosively when involved in a fire. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Vapor may cause flash fire. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May polymerize explosively when involved in a fire. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid ingestion and inhalation. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator/flammables. After opening, purge container with nitrogen before reclosing.
Periodically test for peroxide formation on long-term storage.
Addition of water or appropriate reducing materials will lessen peroxide formation.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid ingestion and inhalation. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator/flammables. After opening, purge container with nitrogen before reclosing.
Periodically test for peroxide formation on long-term storage.
Addition of water or appropriate reducing materials will lessen peroxide formation.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 0-00-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 0-00-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: sweetish odor - sharp odor
pH: Not available.
Vapor Pressure: 28 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 212 deg F
Freezing/Melting Point: -54.4 deg F
Autoignition Temperature: 790 deg F ( 421.11 deg C)
Flash Point: 50 deg F ( 10.00 deg C)
Explosion Limits, lower: 1.7
Explosion Limits, upper: 8.2
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 0.94 (water=1)
Molecular Formula: C5D8O2
Molecular Weight: 108.1108
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable. However, may decompose if heated. On long term storage, substances with similar functional groups form explosive peroxides.
Conditions to Avoid:
High temperatures, incompatible materials, light, ignition sources, exposure to air.
Incompatibilities with Other Materials:
Substance is incompatible with polymerization catalysts (peroxides, persulfates), nitric acid, strong oxidizers, amines, halogens, bases, light, heat.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.
Stable. However, may decompose if heated. On long term storage, substances with similar functional groups form explosive peroxides.
Conditions to Avoid:
High temperatures, incompatible materials, light, ignition sources, exposure to air.
Incompatibilities with Other Materials:
Substance is incompatible with polymerization catalysts (peroxides, persulfates), nitric acid, strong oxidizers, amines, halogens, bases, light, heat.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 0-00-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl Methacrylate-D8 - Not listed by ACGIH, IARC, or NTP.
CAS# 0-00-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl Methacrylate-D8 - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: METHYL METHACRYLATE MONOMER, INHIBITED
Hazard Class: 3
UN Number: 1247
Packing Group: II
IMO
Shipping Name: METHYL METHACRYLATE MONOMER, INHIBITED
Hazard Class: 3.2
UN Number: 1247
Packing Group: II
RID/ADR
Shipping Name: METHYLMETHACRYLATE MONOMER, INHIBITED
Hazard Class: 3
UN Number: 1247
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 0-00-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 0-00-1 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 0-00-1 is not listed on the TSCA inventory.
It is for research and development use only.
