Name:
Methylated Spirit (Mineralized)
Synonym:
Non
CAS:
64-17-5
Section 1 - Chemical Product
MSDS Name:Methylated Spirit (Mineralized)
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-17-5 | Ethyl alcohol | 90% | 200-578-6 |
| Hazard Symbols: XN F Risk Phrases: 11 20/21/22 68/20/21/22 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Harmful : possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause painful sensitization to light. May cause blindness. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. Methanol can be absorbed through the skin, producing systemic effects that include visual disturbances.
Ingestion:
May be fatal or cause blindness if swallowed. May cause irritation of the digestive tract. May cause systemic toxicity with acidosis.
May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
May cause respiratory tract irritation. May cause liver and kidney damage. May cause visual impairment and possible permanent blindness.
May cause effects similar to those described for ingestion.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. May cause liver and kidney damage. May cause reproductive and fetal effects. Methanol is only very slowly eliminated from the body. Because of this slow elimination, methanol should be regarded as a cumulative poison. Though a single exposure may cause no effect, daily exposures may result in the accumulation of a harmful amount.
Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Harmful : possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause painful sensitization to light. May cause blindness. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. Methanol can be absorbed through the skin, producing systemic effects that include visual disturbances.
Ingestion:
May be fatal or cause blindness if swallowed. May cause irritation of the digestive tract. May cause systemic toxicity with acidosis.
May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
May cause respiratory tract irritation. May cause liver and kidney damage. May cause visual impairment and possible permanent blindness.
May cause effects similar to those described for ingestion.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. May cause liver and kidney damage. May cause reproductive and fetal effects. Methanol is only very slowly eliminated from the body. Because of this slow elimination, methanol should be regarded as a cumulative poison. Though a single exposure may cause no effect, daily exposures may result in the accumulation of a harmful amount.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Effects may be delayed. Ethanol may inhibit methanol metabolism.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Effects may be delayed. Ethanol may inhibit methanol metabolism.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May be ignited by heat, sparks, and flame. Vapors may form an explosive mixture with air.
Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May be ignited by heat, sparks, and flame. Vapors may form an explosive mixture with air.
Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Wash area with soap and water. Remove all sources of ignition.
Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Spills/Leaks:
Wash area with soap and water. Remove all sources of ignition.
Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 64-17-5: United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE France - VME: 1000 ppm VME; 1900 mg/m3 VME France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 960 mg/m3 TWA Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA Netherlands: 500 ppm MAC; 1000 mg/m3 MAC Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED CAS# 67-56-1: United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL United States OSHA: 200 ppm TWA; 260 mg/m3 TWA Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE France - VME: 200 ppm VME; 260 mg/m3 VME France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE Germany: 200 ppm TWA; 270 mg/m3 TWA Germany: Skin absorber Japan: 200 ppm OEL; 260 mg/m3 OEL Malaysia: 200 ppm TWA; 262 mg/m3 TWA Netherlands: 200 ppm MAC; 260 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC CAS# 110-86-1: United Kingdom, WEL - TWA: 5 ppm TWA; 16 mg/m3 TWA United Kingdom, WEL - STEL: 10 ppm STEL; 33 mg/m3 STEL United States OSHA: 5 ppm TWA; 15 mg/m3 TWA Belgium - TWA: 5 ppm VLE; 16 mg/m3 VLE France - VME: 5 ppm VME; 15 mg/m3 VME France - VLE: 10 ppm VLE; 30 mg/m3 VLE Germany: 5 ppm TWA; 16 mg/m3 TWA Germany: Skin absorber Malaysia: 5 ppm TWA; 16 mg/m3 TWA Netherlands: 0.3 ppm MAC; 0.9 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 5 ppm VLA-ED; 15 mg/m3 VLA-ED CAS# 8004-87-3: Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 64-17-5: United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE France - VME: 1000 ppm VME; 1900 mg/m3 VME France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 960 mg/m3 TWA Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA Netherlands: 500 ppm MAC; 1000 mg/m3 MAC Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED CAS# 67-56-1: United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL United States OSHA: 200 ppm TWA; 260 mg/m3 TWA Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE France - VME: 200 ppm VME; 260 mg/m3 VME France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE Germany: 200 ppm TWA; 270 mg/m3 TWA Germany: Skin absorber Japan: 200 ppm OEL; 260 mg/m3 OEL Malaysia: 200 ppm TWA; 262 mg/m3 TWA Netherlands: 200 ppm MAC; 260 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC CAS# 110-86-1: United Kingdom, WEL - TWA: 5 ppm TWA; 16 mg/m3 TWA United Kingdom, WEL - STEL: 10 ppm STEL; 33 mg/m3 STEL United States OSHA: 5 ppm TWA; 15 mg/m3 TWA Belgium - TWA: 5 ppm VLE; 16 mg/m3 VLE France - VME: 5 ppm VME; 15 mg/m3 VME France - VLE: 10 ppm VLE; 30 mg/m3 VLE Germany: 5 ppm TWA; 16 mg/m3 TWA Germany: Skin absorber Malaysia: 5 ppm TWA; 16 mg/m3 TWA Netherlands: 0.3 ppm MAC; 0.9 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 5 ppm VLA-ED; 15 mg/m3 VLA-ED CAS# 8004-87-3: Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear purple
Odor: Alcohol odor.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 18 deg C ( 64.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble in water.
Specific Gravity/Density:
Molecular Formula: Mixture
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Bromine trifluoride, fluorine, acids (mineral, non-oxidizing, e.g.
hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g. methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, sodium), nitrides (e.g. potassium nitride, sodium nitride), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents (strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide, potassium nitrate), reducing agents (strong, e.g. aluminum carbide, chlorosilane, hydrogen phosphide, lithium hydride), water reactive substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, formaldehyde.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Bromine trifluoride, fluorine, acids (mineral, non-oxidizing, e.g.
hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g. methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, sodium), nitrides (e.g. potassium nitride, sodium nitride), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents (strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide, potassium nitrate), reducing agents (strong, e.g. aluminum carbide, chlorosilane, hydrogen phosphide, lithium hydride), water reactive substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, formaldehyde.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 110-86-1: UR8400000 CAS# 8004-87-3: GC8425000 LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 110-86-1: Dermal, guinea pig: LD50 = 1 gm/kg; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = 28500 mg/m3/1H; Oral, mouse: LD50 = 1500 mg/kg; Oral, rat: LD50 = 891 mg/kg; Skin, rabbit: LD50 = 1121 mg/kg.
CAS# 8004-87-3: Oral, mouse: LD50 = 105 mg/kg; Oral, rat: LD50 = 413 mg/kg.
Carcinogenicity:
Ethyl alcohol - Not listed by ACGIH, IARC, or NTP.
Methyl alcohol - Not listed by ACGIH, IARC, or NTP.
Pyridine - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 5/17/02 Methyl violet - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 110-86-1: UR8400000 CAS# 8004-87-3: GC8425000 LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 110-86-1: Dermal, guinea pig: LD50 = 1 gm/kg; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = 28500 mg/m3/1H; Oral, mouse: LD50 = 1500 mg/kg; Oral, rat: LD50 = 891 mg/kg; Skin, rabbit: LD50 = 1121 mg/kg.
CAS# 8004-87-3: Oral, mouse: LD50 = 105 mg/kg; Oral, rat: LD50 = 413 mg/kg.
Carcinogenicity:
Ethyl alcohol - Not listed by ACGIH, IARC, or NTP.
Methyl alcohol - Not listed by ACGIH, IARC, or NTP.
Pyridine - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 5/17/02 Methyl violet - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing Group: II
IMO
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing Group: II
RID/ADR
Shipping Name: ETHANOL SOLUTION
Hazard Class: 3
UN Number: 1170
Packing group: II
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 110-86-1: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 68/20/21/22 Harmful : possible risk of
irreversible effects through inhalation, in contact
with skin and if swallowed.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 110-86-1: 2
CAS# 8004-87-3: No information available.
Canada
CAS# 64-17-5 is listed on Canadas DSL List.
CAS# 67-56-1 is listed on Canadas DSL List.
CAS# 110-86-1 is listed on Canadas DSL List.
CAS# 8004-87-3 is listed on Canadas DSL List.
CAS# 64-17-5 is listed on Canadas Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canadas Ingredient Disclosure List.
CAS# 110-86-1 is listed on Canadas Ingredient Disclosure List.
CAS# 8004-87-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 110-86-1 is listed on the TSCA inventory.
CAS# 8004-87-3 is listed on the TSCA inventory.
