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Name:
Methylsulfoxide-d6 with 0.03% TMS packaged in 0.75 ml ampoules 99.9
Synonym:
Dimethyl-d6 sulfoxid
CAS:
2206-27-1
Section 1 - Chemical Product
MSDS Name:Methylsulfoxide-d6 with 0.03% TMS packaged in 0.75 ml ampoules 99.9
Synonym:Dimethyl-d6 sulfoxid
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
2206-27-1 Methylsulfoxide-d6 with 0.03% TMS pack 99.9 ato 218-617-0
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury.
Skin:
Causes skin irritation. May cause irritation with burning pain, itching and redness. Substance is rapidly absorbed through the skin.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Will burn if involved in a fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Do not flush into a sewer. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
Handling:
Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Keep away from heat, sparks, and flame. Keep under a nitrogen blanket. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 2206-27-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Clear liquid
Color: colorless
Odor: odorless
pH: Not available.
Vapor Pressure: .42 mm Hg @20 deg C
Viscosity: Not available.
Boiling Point: 190 deg C @ 760.00mm Hg
Freezing/Melting Point: 20 deg C
Autoignition Temperature: 215 deg C ( 419.00 deg F)
Flash Point: 95 deg C ( 203.00 deg F)
Explosion Limits, lower: 3.5 vol %
Explosion Limits, upper: 42 vol %
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1900g/cm3
Molecular Formula: C2D6OS
Molecular Weight: 84.17

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, acid chlorides, phosphorus halides.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 2206-27-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methylsulfoxide-d6 with 0.03% TMS packaged in 0.75 ml ampoules - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 2206-27-1: No information available.
Canada
CAS# 2206-27-1 is listed on Canadas DSL List.
CAS# 2206-27-1 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2206-27-1 is not listed on the TSCA inventory.
It is for research and development use only.