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Name:
Molecular sieves 5a 8 to 12 mesh
Synonym:
Non
CAS:
1332-58-7
Section 1 - Chemical Product
MSDS Name:Molecular sieves 5a 8 to 12 mesh
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
1332-58-7 Kaolin <100.0 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
Dust is irritating to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Chronic:
Prolonged exposure to respirable crystalline quartz may cause delayed lung injury/fibrosis (silicosis).

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 1332-58-7: United Kingdom, WEL - TWA: 2 mg/m3 TWA (respirable dust) United Kingdom, WEL - STEL: 6 mg/m3 STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 2 mg/m3 VLE (respirable fraction) France - VME: 10 mg/m3 VME Malaysia: 2 mg/m3 TWA (particulate matter containing no asbestos <1% crystalline silic Netherlands: 10 mg/m3 MAC Russia: (listed as silica, amorphous): 1 mg/m3 TWA Spain: 2 mg/m3 VLA-ED (respirable fraction, this value is for the particulated matter t CAS# 1344-00-9: CAS# 1344-01-0: CAS# 12736-96-8: CAS# 14808-60-7: United Kingdom, WEL - TWA: (listed as silica, crystalline (genera form)): 0.3 mg/m3 TWA (respirable) United Kingdom, WEL - STEL: (listed as silica, crystalline (gener form)): 0.9 mg/m3 STEL (respirable) Belgium - TWA: 0.1 mg/m3 VLE (respirable dust) France - VME: 0.1 mg/m3 VME (listed under silica crystallines) Germany: 0.15 mg/m3 TWA (respirable fraction) Malaysia: 0.1 mg/m3 TWA (respirable fraction) Netherlands: 0.075 mg/m3 MAC (respirable dust) Russia: 1 mg/m3 TWA Spain: 0.1 mg/m3 VLA-ED (respirable fraction) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: beige
Odor: Odorless.
pH: 13.3-10.5 (5% slurry
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not applicable.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 2.1
Molecular Formula: Not applicable.
Molecular Weight:

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
None reported.
Hazardous Decomposition Products:
Irritating and toxic gases.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1332-58-7: GF1670500 CAS# 1344-00-9: VV8902500 CAS# 1344-01-0 unlisted.
CAS# 12736-96-8 unlisted.
CAS# 14808-60-7: VV7330000 LD50/LC50:
Not available.
CAS# 1344-00-9: Oral, rat: LD50 = >27 gm/kg.
CAS# 1344-01-0.
CAS# 12736-96-8.
CAS# 14808-60-7.
Carcinogenicity:
Kaolin - Not listed by ACGIH, IARC, or NTP.
Sodium aluminum silicate - Not listed by ACGIH, IARC, or NTP.
Silicic acid, aluminum calcium sodium salt - Not listed by ACGIH, IARC, or NTP.
Sodium potassium aluminum silicate - Not listed by ACGIH, IARC, or NTP.
Quartz - ACGIH: A2 - Suspected Human Carcinogen California: carcinogen, initial date 10/1/88 (airborne particles of re NTP: Known carcinogen (listed as Silica, crystalline (general f IARC: Group 1 carcinogen Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1332-58-7: 0
CAS# 1344-00-9: 0
CAS# 1344-01-0: No information available.
CAS# 12736-96-8: 0
CAS# 14808-60-7: No information available.
Canada
CAS# 1332-58-7 is listed on Canadas DSL List.
CAS# 1344-00-9 is listed on Canadas DSL List.
CAS# 1344-01-0 is listed on Canadas DSL List.
CAS# 12736-96-8 is listed on Canadas DSL List.
CAS# 14808-60-7 is listed on Canadas DSL List.
CAS# 1332-58-7 is not listed on Canadas Ingredient Disclosure List.
CAS# 1344-00-9 is not listed on Canadas Ingredient Disclosure List.
CAS# 1344-01-0 is not listed on Canadas Ingredient Disclosure List.
CAS# 12736-96-8 is not listed on Canadas Ingredient Disclosure List.
CAS# 14808-60-7 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1332-58-7 is listed on the TSCA inventory.
CAS# 1344-00-9 is listed on the TSCA inventory.
CAS# 1344-01-0 is listed on the TSCA inventory.
CAS# 12736-96-8 is listed on the TSCA inventory.
CAS# 14808-60-7 is listed on the TSCA inventory.