Name:
Molecular Sieves
Synonym:
Non
CAS:
1332-58-7
Section 1 - Chemical Product
MSDS Name:Molecular Sieves
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1332-58-7 | Kaolin | <100.0 | unlisted |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Low hazard for usual industrial handling.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
Prolonged exposure to respirable crystalline quartz may cause delayed lung injury/fibrosis (silicosis).
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Low hazard for usual industrial handling.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
Prolonged exposure to respirable crystalline quartz may cause delayed lung injury/fibrosis (silicosis).
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place.
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 1332-58-7: United Kingdom, WEL - TWA: 2 mg/m3 TWA (respirable dust) United Kingdom, WEL - STEL: 6 mg/m3 STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 2 mg/m3 VLE (respirable fraction) France - VME: 10 mg/m3 VME Malaysia: 2 mg/m3 TWA (particulate matter containing no asbestos <1% crystalline silic Netherlands: 10 mg/m3 MAC Russia: (listed as silica, amorphous): 1 mg/m3 TWA Spain: 2 mg/m3 VLA-ED (respirable fraction, this value is for the particulated matter t CAS# 1344-00-9: CAS# 1344-01-0: CAS# 12736-96-8: CAS# 14808-60-7: United Kingdom, WEL - TWA: (listed as silica, crystalline (genera form)): 0.3 mg/m3 TWA (respirable) United Kingdom, WEL - STEL: (listed as silica, crystalline (gener form)): 0.9 mg/m3 STEL (respirable) Belgium - TWA: 0.1 mg/m3 VLE (respirable dust) France - VME: 0.1 mg/m3 VME (listed under silica crystallines) Germany: 0.15 mg/m3 TWA (respirable fraction) Malaysia: 0.1 mg/m3 TWA (respirable fraction) Netherlands: 0.075 mg/m3 MAC (respirable dust) Russia: 1 mg/m3 TWA Spain: 0.1 mg/m3 VLA-ED (respirable fraction) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 1332-58-7: United Kingdom, WEL - TWA: 2 mg/m3 TWA (respirable dust) United Kingdom, WEL - STEL: 6 mg/m3 STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 2 mg/m3 VLE (respirable fraction) France - VME: 10 mg/m3 VME Malaysia: 2 mg/m3 TWA (particulate matter containing no asbestos <1% crystalline silic Netherlands: 10 mg/m3 MAC Russia: (listed as silica, amorphous): 1 mg/m3 TWA Spain: 2 mg/m3 VLA-ED (respirable fraction, this value is for the particulated matter t CAS# 1344-00-9: CAS# 1344-01-0: CAS# 12736-96-8: CAS# 14808-60-7: United Kingdom, WEL - TWA: (listed as silica, crystalline (genera form)): 0.3 mg/m3 TWA (respirable) United Kingdom, WEL - STEL: (listed as silica, crystalline (gener form)): 0.9 mg/m3 STEL (respirable) Belgium - TWA: 0.1 mg/m3 VLE (respirable dust) France - VME: 0.1 mg/m3 VME (listed under silica crystallines) Germany: 0.15 mg/m3 TWA (respirable fraction) Malaysia: 0.1 mg/m3 TWA (respirable fraction) Netherlands: 0.075 mg/m3 MAC (respirable dust) Russia: 1 mg/m3 TWA Spain: 0.1 mg/m3 VLA-ED (respirable fraction) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white to tan
Odor: odorless
pH: 13.3-10.5 (5% slurry
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not applicable.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 2.1
Molecular Formula: Mixture
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
None reported.
Hazardous Decomposition Products:
Carbon monoxide, silicon dioxide, aluminum oxide.
Hazardous Polymerization: Has not been reported.
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
None reported.
Hazardous Decomposition Products:
Carbon monoxide, silicon dioxide, aluminum oxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1332-58-7: GF1670500 CAS# 1344-00-9: VV8902500 CAS# 1344-01-0 unlisted.
CAS# 12736-96-8 unlisted.
CAS# 14808-60-7: VV7330000 LD50/LC50:
Not available.
CAS# 1344-00-9: Oral, rat: LD50 = >27 gm/kg.
CAS# 1344-01-0.
CAS# 12736-96-8.
CAS# 14808-60-7.
Carcinogenicity:
Kaolin - Not listed by ACGIH, IARC, or NTP.
Sodium aluminum silicate - Not listed by ACGIH, IARC, or NTP.
Silicic acid, aluminum calcium sodium salt - Not listed by ACGIH, IARC, or NTP.
Sodium potassium aluminum silicate - Not listed by ACGIH, IARC, or NTP.
Quartz - ACGIH: A2 - Suspected Human Carcinogen California: carcinogen, initial date 10/1/88 (airborne particles of re NTP: Known carcinogen (listed as Silica, crystalline (general f IARC: Group 1 carcinogen Other:
See actual entry in RTECS for complete information.
CAS# 1332-58-7: GF1670500 CAS# 1344-00-9: VV8902500 CAS# 1344-01-0 unlisted.
CAS# 12736-96-8 unlisted.
CAS# 14808-60-7: VV7330000 LD50/LC50:
Not available.
CAS# 1344-00-9: Oral, rat: LD50 = >27 gm/kg.
CAS# 1344-01-0.
CAS# 12736-96-8.
CAS# 14808-60-7.
Carcinogenicity:
Kaolin - Not listed by ACGIH, IARC, or NTP.
Sodium aluminum silicate - Not listed by ACGIH, IARC, or NTP.
Silicic acid, aluminum calcium sodium salt - Not listed by ACGIH, IARC, or NTP.
Sodium potassium aluminum silicate - Not listed by ACGIH, IARC, or NTP.
Quartz - ACGIH: A2 - Suspected Human Carcinogen California: carcinogen, initial date 10/1/88 (airborne particles of re NTP: Known carcinogen (listed as Silica, crystalline (general f IARC: Group 1 carcinogen Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 1332-58-7: 0
CAS# 1344-00-9: 0
CAS# 1344-01-0: No information available.
CAS# 12736-96-8: 0
CAS# 14808-60-7: No information available.
Canada
CAS# 1332-58-7 is listed on Canadas DSL List.
CAS# 1344-00-9 is listed on Canadas DSL List.
CAS# 1344-01-0 is listed on Canadas DSL List.
CAS# 12736-96-8 is listed on Canadas DSL List.
CAS# 14808-60-7 is listed on Canadas DSL List.
CAS# 1332-58-7 is not listed on Canadas Ingredient Disclosure List.
CAS# 1344-00-9 is not listed on Canadas Ingredient Disclosure List.
CAS# 1344-01-0 is not listed on Canadas Ingredient Disclosure List.
CAS# 12736-96-8 is not listed on Canadas Ingredient Disclosure List.
CAS# 14808-60-7 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1332-58-7 is listed on the TSCA inventory.
CAS# 1344-00-9 is listed on the TSCA inventory.
CAS# 1344-01-0 is listed on the TSCA inventory.
CAS# 12736-96-8 is listed on the TSCA inventory.
CAS# 14808-60-7 is listed on the TSCA inventory.
