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Name:
N-Cyclohexyl-2-pyrrolidone 99%
Synonym:
CHP; 1-Cyclohexyl-2-pyrrolidone; N-Cyclohexylpyrrolidinone; N-Cyclohexylpyrrolidone
CAS:
6837-24-7
Section 1 - Chemical Product
MSDS Name:N-Cyclohexyl-2-pyrrolidone 99%
Synonym:CHP; 1-Cyclohexyl-2-pyrrolidone; N-Cyclohexylpyrrolidinone; N-Cyclohexylpyrrolidone
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
6837-24-7 N-Cyclohexyl-2-pyrrolidinone 99 229-919-7
Hazard Symbols: T+
Risk Phrases: 21/22 26 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Very toxic by inhalation. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
Causes severe skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May be fatal if inhaled. Causes respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Use only with adequate ventilation. Do not breathe vapor or mist.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6837-24-7: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear almost colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.05 mm Hg @ 25 deg C
Viscosity: 11.5 mPa.s
Boiling Point: 154 deg C @ 7 mm Hg
Freezing/Melting Point: 12 deg C
Autoignition Temperature: 225 deg C ( 437.00 deg F)
Flash Point: 145 deg C ( 293.00 deg F)
Explosion Limits, lower: 1.00%
Explosion Limits, upper: 11.80%
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.0070 g/cm3
Molecular Formula: C10H17NO
Molecular Weight: 167.25

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. Product may develop color with aging.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 6837-24-7: UY5748450 LD50/LC50:
CAS# 6837-24-7: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, skin: 500 mg/24H Severe; Inhalation, rat: LC50 = 120 ppm/1H; Oral, rabbit: LD50 = 657 mg/kg; Oral, rat: LD50 = 370 mg/kg; Skin, rabbit: LD50 = 1600 mg/kg.
Not available.
Carcinogenicity:
N-Cyclohexyl-2-pyrrolidinone - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: I
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: I
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: I

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 26 Very toxic by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 6837-24-7: 1
Canada
CAS# 6837-24-7 is listed on Canadas NDSL List.
CAS# 6837-24-7 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6837-24-7 is listed on the TSCA inventory.