Name:
N-Vinyl-2-pyrrolidone stabilized with Kerobit custom grade
Synonym:
N-Vinylbutyrolactam; 1-Vinyl-2-pyrrolidone; 1-Vinyl-2-pyrrolidinone; 1-Ethenyl-2-pyrrolidinone; N-Vinyl-2-pyrrolidinone; N-Vinyl-2-pyrrolidone
CAS:
88-12-0
Section 1 - Chemical Product
MSDS Name:N-Vinyl-2-pyrrolidone stabilized with Kerobit custom grade
Synonym:N-Vinylbutyrolactam; 1-Vinyl-2-pyrrolidone; 1-Vinyl-2-pyrrolidinone; 1-Ethenyl-2-pyrrolidinone; N-Vinyl-2-pyrrolidinone; N-Vinyl-2-pyrrolidone
Synonym:N-Vinylbutyrolactam; 1-Vinyl-2-pyrrolidone; 1-Vinyl-2-pyrrolidinone; 1-Ethenyl-2-pyrrolidinone; N-Vinyl-2-pyrrolidinone; N-Vinyl-2-pyrrolidone
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 88-12-0 | N-Vinyl-2-pyrrolidone | 99 | 201-800-4 |
| Hazard Symbols: XN Risk Phrases: 20/21/22 37 40 41 48/20 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to respiratory system. Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. Harmful : danger of serious damage to health by prolonged exposure through inhalation.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause nausea and vomiting. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled. May cause headache. Inhalation of vapors will cause coughing or breathing difficulty.
Chronic:
Chronic exposure may cause liver damage. Chronic exposure may cause lung damage.
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to respiratory system. Limited evidence of a carcinogenic effect. Risk of serious damage to eyes. Harmful : danger of serious damage to health by prolonged exposure through inhalation.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause nausea and vomiting. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled. May cause headache. Inhalation of vapors will cause coughing or breathing difficulty.
Chronic:
Chronic exposure may cause liver damage. Chronic exposure may cause lung damage.
Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire.
Polymerizes readily if not inhibited; heat can initiate reaction.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire.
Polymerizes readily if not inhibited; heat can initiate reaction.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid breathing vapor or mist. Do not get in eyes. Avoid contact with skin and clothing.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store at around 20C.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid breathing vapor or mist. Do not get in eyes. Avoid contact with skin and clothing.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store at around 20C.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 88-12-0: France - VME: 0.1 ppm VME Germany: 0.1 ppm TWA; 0.5 mg/m3 TWA Germany: Skin absorber Russia: 1 mg/m3 TWA CAS# 101-96-2: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 88-12-0: France - VME: 0.1 ppm VME Germany: 0.1 ppm TWA; 0.5 mg/m3 TWA Germany: Skin absorber Russia: 1 mg/m3 TWA CAS# 101-96-2: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: colorless - yellow
Odor: characteristic odor
pH: 9-10(100g/l aq.sol.)
Vapor Pressure: 0.114 mm Hg @ 25 deg C
Viscosity: 2.4 mPa.s@ 20 deg C
Boiling Point: 90-92 deg C @ 13 mm Hg
Freezing/Melting Point: 13-14 deg C
Autoignition Temperature: Not available.
Flash Point: 95 deg C ( 203.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.0430g/cm3
Molecular Formula: C6H9NO
Molecular Weight: 111.14
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Becomes yellow over time. This material is a monomer and may polymerize under certain conditions if the stabilizer is lost.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, polymerizing initiators.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
Becomes yellow over time. This material is a monomer and may polymerize under certain conditions if the stabilizer is lost.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, polymerizing initiators.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 88-12-0: UY6107000 CAS# 101-96-2: SS9040000 LD50/LC50:
CAS# 88-12-0: Draize test, rabbit, eye: 100 mg Severe; Inhalation, rat: LC50 = 3200 mg/m3/4H; Oral, rat: LD50 = 1470 mg/kg; Skin, rabbit: LD50 = 560 mg/kg.
CAS# 101-96-2: Dermal, guinea pig: LD50 = 5 gm/kg; Draize test, rabbit, eye: 100 uL/24H Severe; Draize test, rabbit, skin: 500 uL/24H Severe; Oral, rat: LD50 = 148 mg/kg; Skin, rabbit: LD50 = 2806 mg/kg.
Carcinogenicity:
N-Vinyl-2-pyrrolidone - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to N,N-Di-sec-butyl-p-phenylenediamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 88-12-0: UY6107000 CAS# 101-96-2: SS9040000 LD50/LC50:
CAS# 88-12-0: Draize test, rabbit, eye: 100 mg Severe; Inhalation, rat: LC50 = 3200 mg/m3/4H; Oral, rat: LD50 = 1470 mg/kg; Skin, rabbit: LD50 = 560 mg/kg.
CAS# 101-96-2: Dermal, guinea pig: LD50 = 5 gm/kg; Draize test, rabbit, eye: 100 uL/24H Severe; Draize test, rabbit, skin: 500 uL/24H Severe; Oral, rat: LD50 = 148 mg/kg; Skin, rabbit: LD50 = 2806 mg/kg.
Carcinogenicity:
N-Vinyl-2-pyrrolidone - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to N,N-Di-sec-butyl-p-phenylenediamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Log Pow 0.4
Log Pow 0.4
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Toxic liquid, organic, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: Toxic liquid, organic, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: Toxic liquid, organic, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 37 Irritating to respiratory system.
R 40 Limited evidence of a carcinogenic effect.
R 41 Risk of serious damage to eyes.
R 48/20 Harmful : danger of serious damage to health
by prolonged exposure through inhalation.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 88-12-0: 3
CAS# 101-96-2: 2
Canada
CAS# 88-12-0 is listed on Canadas DSL List.
CAS# 101-96-2 is listed on Canadas DSL List.
CAS# 88-12-0 is listed on Canadas Ingredient Disclosure List.
CAS# 101-96-2 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88-12-0 is listed on the TSCA inventory.
CAS# 101-96-2 is listed on the TSCA inventory.
