Name:
Naphthalene-d8 98+ atom % D
Synonym:
(2H8)Naphthalen
CAS:
1146-65-2
Section 1 - Chemical Product
MSDS Name:Naphthalene-d8 98+ atom % D
Synonym:(2H8)Naphthalen
Synonym:(2H8)Naphthalen
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1146-65-2 | Naphthalene-d8 | 98+ | 214-552-7 |
| Hazard Symbols: XN Risk Phrases: 20/21/22 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause lacrimation (tearing), blurred vision, and photophobia.
May cause chemical conjunctivitis and corneal damage. Absorption of more than 15 ppm into the eye may cause cataracts, optical neuritis, corneal injury, and eye irritation.
Skin:
May be harmful if absorbed through the skin. May cause skin irritation and possible burns.
Ingestion:
May cause liver and kidney damage. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea.
Exposure may cause anemia and other blood abnormalities. May be harmful if swallowed. May cause nausea, vomiting, abdominal pain, and increased salivation.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to those described for ingestion. Olfactory fatigue may occur. Can produce delayed pulmonary edema. Material volatilizes at room temperature.
Chronic:
Chronic inhalation, skin absorption or ingestion of naphthalene have caused severe hemolytic anemia.
Harmful by inhalation, in contact with skin and if swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause lacrimation (tearing), blurred vision, and photophobia.
May cause chemical conjunctivitis and corneal damage. Absorption of more than 15 ppm into the eye may cause cataracts, optical neuritis, corneal injury, and eye irritation.
Skin:
May be harmful if absorbed through the skin. May cause skin irritation and possible burns.
Ingestion:
May cause liver and kidney damage. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea.
Exposure may cause anemia and other blood abnormalities. May be harmful if swallowed. May cause nausea, vomiting, abdominal pain, and increased salivation.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to those described for ingestion. Olfactory fatigue may occur. Can produce delayed pulmonary edema. Material volatilizes at room temperature.
Chronic:
Chronic inhalation, skin absorption or ingestion of naphthalene have caused severe hemolytic anemia.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:
Individuals with a glucose-6-phosphate dehyrogenase deficiency are hypersensitive to the effects of naphthalene.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:
Individuals with a glucose-6-phosphate dehyrogenase deficiency are hypersensitive to the effects of naphthalene.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Dust can be an explosion hazard when exposed to heat or flame. Flammable solid. May burn rapidly with flare burning effect. May re-ignite after fire is extinguished.
Extinguishing Media:
Use carbon dioxide or dry chemical. Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Dust can be an explosion hazard when exposed to heat or flame. Flammable solid. May burn rapidly with flare burning effect. May re-ignite after fire is extinguished.
Extinguishing Media:
Use carbon dioxide or dry chemical. Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Scoop up with a nonsparking tool, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.
Spills/Leaks:
Scoop up with a nonsparking tool, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Use spark-proof tools and explosion proof equipment. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. Separate from oxidizing materials.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Use spark-proof tools and explosion proof equipment. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. Separate from oxidizing materials.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 1146-65-2: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 1146-65-2: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystals
Color: white
Odor: none reported
pH: Not available.
Vapor Pressure: 0.3 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 81 - 83 deg C
Autoignition Temperature: 979 deg F ( 526.11 deg C)
Flash Point: 174 deg F ( 78.89 deg C)
Explosion Limits, lower: 0.9 vol %
Explosion Limits, upper: 5.9 vol %
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C10D8
Molecular Weight: 136.22
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, moisture.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, moisture.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1146-65-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Naphthalene-d8 - Not listed by ACGIH, IARC, or NTP.
CAS# 1146-65-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Naphthalene-d8 - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: NAPHTHALENE, REFINED
Hazard Class: 4.1
UN Number: 1334
Packing Group: III
IMO
Shipping Name: NAPHTHALENE, REFINED
Hazard Class: 4.1
UN Number: 1334
Packing Group: III
RID/ADR
Shipping Name: NAPHTHALENE, REFINED
Hazard Class: 4.1
UN Number: 1334
Packing group: III
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 1146-65-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1146-65-2 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1146-65-2 is not listed on the TSCA inventory.
It is for research and development use only.
