Name:
Nitric Acid SG1.5-Fuming
Synonym:
Azotic acid; Engravers nitrate; Hydrogen nitrate
CAS:
7697-37-2
Section 1 - Chemical Product
MSDS Name:Nitric Acid SG1.5-Fuming
Synonym:Azotic acid; Engravers nitrate; Hydrogen nitrate
Synonym:Azotic acid; Engravers nitrate; Hydrogen nitrate
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7697-37-2 | Nitric acid | 100 | 231-714-2 |
| Hazard Symbols: O C Risk Phrases: 35 8 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes severe burns. Contact with combustible material may cause fire.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the digestive tract.
Inhalation:
May be fatal if inhaled. Effects may be delayed. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth.
Causes severe burns. Contact with combustible material may cause fire.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the digestive tract.
Inhalation:
May be fatal if inhaled. Effects may be delayed. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Use water spray to keep fire-exposed containers cool.
Substance is noncombustible. Contact with metals may evolve flammable hydrogen gas. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Use water spray to keep fire-exposed containers cool.
Substance is noncombustible. Contact with metals may evolve flammable hydrogen gas. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Neutralize spill with sodium bicarbonate. Use water spray to disperse the gas/vapor. Provide ventilation. Evacuate unnecessary personnel. Approach spill from upwind. Control runoff and isolate discharged material for proper disposal.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Neutralize spill with sodium bicarbonate. Use water spray to disperse the gas/vapor. Provide ventilation. Evacuate unnecessary personnel. Approach spill from upwind. Control runoff and isolate discharged material for proper disposal.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from metals. Store away from alkalies. Bottles should be vented periodically in order to overcome pressure buildup.
Separate from organic materials.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from metals. Store away from alkalies. Bottles should be vented periodically in order to overcome pressure buildup.
Separate from organic materials.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear chemical goggles and a face shield.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear chemical goggles and a face shield.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless or slight yellow
Odor: Not available.
pH: 1.0
Vapor Pressure: 62 mm Hg @25C
Viscosity: Not available.
Boiling Point: 83 deg C
Freezing/Melting Point: -42 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 1.50
Molecular Formula: HNO3
Molecular Weight: 63.01
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Decomposes when in contact with air, light, or organic matter.
Conditions to Avoid:
High temperatures, moisture.
Incompatibilities with Other Materials:
Combustible materials, easily oxidizable materials, organic solvents, metal powders, carbides, cyanides (e.g. potassium cyanide, sodium cyanide), alkalies.
Hazardous Decomposition Products:
Nitrogen oxides, hydrogen gas.
Hazardous Polymerization: Has not been reported.
Decomposes when in contact with air, light, or organic matter.
Conditions to Avoid:
High temperatures, moisture.
Incompatibilities with Other Materials:
Combustible materials, easily oxidizable materials, organic solvents, metal powders, carbides, cyanides (e.g. potassium cyanide, sodium cyanide), alkalies.
Hazardous Decomposition Products:
Nitrogen oxides, hydrogen gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7697-37-2: QU5775000 QU5900000 LD50/LC50:
CAS# 7697-37-2: Inhalation, rat: LC50 = 260 mg/m3/30M; Inhalation, rat: LC50 = 130 mg/m3/4H; Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
Carcinogenicity:
Nitric acid - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7697-37-2: QU5775000 QU5900000 LD50/LC50:
CAS# 7697-37-2: Inhalation, rat: LC50 = 260 mg/m3/30M; Inhalation, rat: LC50 = 130 mg/m3/4H; Inhalation, rat: LC50 = 67 ppm(NO2)/4H.
Carcinogenicity:
Nitric acid - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Mosquito fish: TLm=72 ppm/96H (fresh water) Cockle: LC50=330-1000 ppm/48H (salt water)
Mosquito fish: TLm=72 ppm/96H (fresh water) Cockle: LC50=330-1000 ppm/48H (salt water)
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Nitric acid
Hazard Class: 8
UN Number: 2031
Packing Group: I
IMO
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: I
RID/ADR
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing group: I
USA RQ:CAS# 7697-37-2: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 35 Causes severe burns.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7697-37-2: 1
United Kingdom Occupational Exposure Limits
CAS# 7697-37-2: OES-United Kingdom, TWA 2 ppm TWA; 5.2 mg/m3 TWA
CAS# 7697-37-2: OES-United Kingdom, STEL 4 ppm STEL; 10 mg/m3 STEL
United Kingdom Maximum Exposure Limits
Canada
CAS# 7697-37-2 is listed on Canadas DSL List.
CAS# 7697-37-2 is listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 7697-37-2: OEL-ARAB Republic of Egypt:TWA 2 ppm (5 mg/m3)
OEL-AUSTRALIA:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3)
OEL-BELGIUM:TWA 2 ppm (5.2 mg/m3);STEL 4 ppm (10 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 2.5 mg/m3;STEL 5 mg/m3
OEL-DENMARK:TWA 2 ppm (5 mg/m3)
OEL-FINLAND:TWA 2 ppm (5 mg/m3);STEL 5 ppm (13 mg/m3);Skin
OEL-FRANCE:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3)
OEL-GERMANY:TWA 10 ppm (25 mg/m3)
OEL-HUNGARY:STEL 5 mg/m3
OEL-JAPAN:TWA 2 ppm (5.2 mg/m3)
OEL-THE PHILIPPINES:TWA 2 ppm (5 mg/m3)
OEL-POLAND:TWA 10 mg/m3
OEL-RUSSIA:TWA 2 ppm;STEL 2 mg/m3;Skin
OEL-SWEDEN:TWA 2 ppm (5 mg/m3);STEL 5 ppm (13 mg/m3)
OEL-SWITZERLAND:TWA 2 ppm (5 mg/m3);STEL 4 ppm (1 mg/m3)
OEL-THAILAND:TWA 2 ppm (5 mg/m3)
OEL-TURKEY:TWA 2 ppm (5 mg/m3)
OEL-UNITED KINGDOM:TWA 2 ppm (5 mg/m3);STEL 4 ppm (10 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7697-37-2 is listed on the TSCA inventory.
