Name:
Nitric acid-d 68 wt. % solution in d2o 99+ atom % d
Synonym:
CAS:
13587-52-5
Section 1 - Chemical Product
MSDS Name:Nitric acid-d 68 wt. % solution in d2o 99+ atom % d
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 13587-52-5 | Nitric acid-d, 68 wt. % solution in D2 | 237-024-8 |
| Hazard Symbols: C Risk Phrases: 35 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes severe burns.Oxidizer.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the digestive tract.
Inhalation:
May be fatal if inhaled. Effects may be delayed. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth.
Causes severe burns.Oxidizer.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the digestive tract.
Inhalation:
May be fatal if inhaled. Effects may be delayed. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Substance is noncombustible.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool fire-exposed containers. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Substance is noncombustible.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool fire-exposed containers. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Neutralize spill with sodium bicarbonate. Use water spray to disperse the gas/vapor.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Neutralize spill with sodium bicarbonate. Use water spray to disperse the gas/vapor.
Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area. Store under an inert atmosphere.
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area. Store under an inert atmosphere.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 13587-52-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 13587-52-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: DNO3
Molecular Weight: 64.02
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Decomposes when in contact with air, light, or organic matter.
Conditions to Avoid:
High temperatures, incompatible materials, light, combustible materials, organic materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, bases, metals.
Hazardous Decomposition Products:
Nitrogen oxides.
Hazardous Polymerization: Will not occur.
Decomposes when in contact with air, light, or organic matter.
Conditions to Avoid:
High temperatures, incompatible materials, light, combustible materials, organic materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, bases, metals.
Hazardous Decomposition Products:
Nitrogen oxides.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13587-52-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nitric acid-d, 68 wt. % solution in D2O - Not listed by ACGIH, IARC, or NTP.
CAS# 13587-52-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nitric acid-d, 68 wt. % solution in D2O - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
For nitric acid: Mosquito fish: TLm=72 ppm/96H (fresh water) Cockle: LC50=330-1000 ppm/48H (salt water)
For nitric acid: Mosquito fish: TLm=72 ppm/96H (fresh water) Cockle: LC50=330-1000 ppm/48H (salt water)
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: II
IMO
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: II
RID/ADR
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13587-52-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13587-52-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13587-52-5 is not listed on the TSCA inventory.
It is for research and development use only.
