Name:
Nitromethane-d3 99 atom % d
Synonym:
Nitrocarbol; N
CAS:
13031-32-8
Section 1 - Chemical Product
MSDS Name:Nitromethane-d3 99 atom % d
Synonym:Nitrocarbol; N
Synonym:Nitrocarbol; N
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 13031-32-8 | Nitromethane-d3 | 235-892-2 |
| Hazard Symbols: XN Risk Phrases: 10 22 5 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Heating may cause an explosion.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation. Vapors may cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May be absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), rapid heart rate and chocolate-brown colored blood. May be harmful if swallowed.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause liver and kidney damage. May cause narcotic effects in high concentration. May cause thryoid effects. May cause blood changes.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate, unconsciousness and possible death.
Flammable. Harmful if swallowed. Heating may cause an explosion.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation. Vapors may cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May be absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), rapid heart rate and chocolate-brown colored blood. May be harmful if swallowed.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause liver and kidney damage. May cause narcotic effects in high concentration. May cause thryoid effects. May cause blood changes.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate, unconsciousness and possible death.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam.
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed container. Keep under a nitrogen blanket. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed container. Keep under a nitrogen blanket. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 13031-32-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 13031-32-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear, colorless
Odor: Disagreeable, fruity odor.
pH: Not available.
Vapor Pressure: 27.8 mm Hg @20C
Viscosity: Not available.
Boiling Point: 100 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 35 deg C ( 95.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1830g/cm3
Molecular Formula: CD3NO2
Molecular Weight: 64.06
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. Substance is shock sensitive and thermally unstable.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Acetone, alkylmetal halides, aluminum chloride, aluminum chloride + ethylene, aluminum chloride + organic matter, ammonium salts + organic solvents, bis(2-aminoethyl)amine, boron trifluoride etherate + silver oxide, amines, aniline, bases, calcium hydroxide, calcium hypochlorite, copper, copper alloys, 1,2-diaminoethane + N,2,4,6-Tetranitro-N-methylaniline, formaldehyde, haloforms, hydrazine + methanol, formic acid, hexamethylbenzene, hydrocarbons, hydroxides, inorganic bases, lead, lead alloys, lithium perchlorate, methylamine, morpholine, nitric acid, organic amines, oxidants, phosphoric acid, potassium hydroxide, reducing agents, silver nitrate (aqueous), sodium hydroxide, strong acids, sulfuric acid, aluminum powder, metal oxides, molecular sieves, nickel, sodium hydride.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures. Substance is shock sensitive and thermally unstable.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Acetone, alkylmetal halides, aluminum chloride, aluminum chloride + ethylene, aluminum chloride + organic matter, ammonium salts + organic solvents, bis(2-aminoethyl)amine, boron trifluoride etherate + silver oxide, amines, aniline, bases, calcium hydroxide, calcium hypochlorite, copper, copper alloys, 1,2-diaminoethane + N,2,4,6-Tetranitro-N-methylaniline, formaldehyde, haloforms, hydrazine + methanol, formic acid, hexamethylbenzene, hydrocarbons, hydroxides, inorganic bases, lead, lead alloys, lithium perchlorate, methylamine, morpholine, nitric acid, organic amines, oxidants, phosphoric acid, potassium hydroxide, reducing agents, silver nitrate (aqueous), sodium hydroxide, strong acids, sulfuric acid, aluminum powder, metal oxides, molecular sieves, nickel, sodium hydride.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13031-32-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nitromethane-d3 - Not listed by ACGIH, IARC, or NTP.
CAS# 13031-32-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nitromethane-d3 - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
see Dictionary of Substances and their Effects.
see Dictionary of Substances and their Effects.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: NITROMETHANE
Hazard Class: 3
UN Number: 1261
Packing Group: II
IMO
Shipping Name: NITROMETHANE
Hazard Class: 3.3
UN Number: 1261
Packing Group: II
RID/ADR
Shipping Name: NITROMETHANE
Hazard Class: 3
UN Number: 1261
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 5 Heating may cause an explosion.
Safety Phrases:
S 41 In case of fire and/or explosion do not breathe
fumes.
WGK (Water Danger/Protection)
CAS# 13031-32-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13031-32-8 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13031-32-8 is not listed on the TSCA inventory.
It is for research and development use only.
