Name:
Niobium atomic absorption standard solution 1 mg/ml Nb in 5% HF
Synonym:
None
CAS:
7440-03-1
Section 1 - Chemical Product
MSDS Name:Niobium atomic absorption standard solution 1 mg/ml Nb in 5% HF
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7440-03-1 | Niobium | <1 | 231-113-5 |
| Hazard Symbols: T+ C Risk Phrases: 26/27/28 35 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Causes severe burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
Very toxic by inhalation, in contact with skin and if swallowed.
Causes severe burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Spills of HF should be flushed until medical attention arrives. SPEEDY ACTION IS CRITICAL! GET MEDICAL ATTENTION IMMEDIATELY! Skin:
Get medical aid immediately. Wash clothing before reuse. Destroy contaminated shoes. Spills of HF should be flushed until medical attention arrives. SPEEDY ACTION IS CRITICAL! GET MEDICAL ATTENTION IMMEDIATELY.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
Get medical aid immediately. Wash clothing before reuse. Destroy contaminated shoes. Spills of HF should be flushed until medical attention arrives. SPEEDY ACTION IS CRITICAL! GET MEDICAL ATTENTION IMMEDIATELY.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Keep containers tightly closed. Store in a cool, dry area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Keep containers tightly closed. Store in a cool, dry area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7440-03-1: Germany: 5 mg/m3 TWA (inhalable fraction) CAS# 7664-39-3: United Kingdom, WEL - TWA: 1.8 ppm TWA (as F); 1.5 mg/m3 TWA (as United Kingdom, WEL - STEL: 3 ppm STEL (as F); 2.5 mg/m3 STEL (as United States OSHA: 3 ppm TWA Belgium - TWA: 1.8 ppm VLE; 1.5 mg/m3 VLE Belgium - STEL: 3 ppm VLE; 2.5 mg/m3 VLE France - VLE: 3 ppm VLE; 2.5 mg/m3 VLE Germany: 3 ppm TWA; 2.5 mg/m3 TWA Germany: Skin absorber Japan: 3 ppm Ceiling; 2.5 mg/m3 Ceiling Malaysia: 3 ppm Ceiling (as F); 2.3 mg/m3 Ceiling (as F) Netherlands: 3.3 ppm STEL; 2.5 mg/m3 STEL (as F) Russia: 0.5 mg/m3 TWA Russia: 0.1 mg/m3 STEL Spain: 1.8 ppm VLA-ED; 1.5 mg/m3 VLA-ED Spain: 3 ppm VLA-EC; 2.5 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7440-03-1: Germany: 5 mg/m3 TWA (inhalable fraction) CAS# 7664-39-3: United Kingdom, WEL - TWA: 1.8 ppm TWA (as F); 1.5 mg/m3 TWA (as United Kingdom, WEL - STEL: 3 ppm STEL (as F); 2.5 mg/m3 STEL (as United States OSHA: 3 ppm TWA Belgium - TWA: 1.8 ppm VLE; 1.5 mg/m3 VLE Belgium - STEL: 3 ppm VLE; 2.5 mg/m3 VLE France - VLE: 3 ppm VLE; 2.5 mg/m3 VLE Germany: 3 ppm TWA; 2.5 mg/m3 TWA Germany: Skin absorber Japan: 3 ppm Ceiling; 2.5 mg/m3 Ceiling Malaysia: 3 ppm Ceiling (as F); 2.3 mg/m3 Ceiling (as F) Netherlands: 3.3 ppm STEL; 2.5 mg/m3 STEL (as F) Russia: 0.5 mg/m3 TWA Russia: 0.1 mg/m3 STEL Spain: 1.8 ppm VLA-ED; 1.5 mg/m3 VLA-ED Spain: 3 ppm VLA-EC; 2.5 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: miscible
Specific Gravity/Density: 1.010 g/L
Molecular Formula: mixture
Molecular Weight: N/A
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Amines, metals, strong bases.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Amines, metals, strong bases.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7440-03-1: QT9900000 CAS# 7664-39-3: MW7875000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
Not available.
CAS# 7664-39-3: Inhalation, mouse: LC50 = 342 ppm/1H; Inhalation, mouse: LC50 = 5000 mg/m3/5M; Inhalation, mouse: LC50 = 270 mg/m3/60M; Inhalation, rat: LC50 = 1276 ppm/1H; Inhalation, rat: LC50 = 1100 mg/m3/60M.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Niobium - Not listed by ACGIH, IARC, or NTP.
Hydrogen fluoride - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7440-03-1: QT9900000 CAS# 7664-39-3: MW7875000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
Not available.
CAS# 7664-39-3: Inhalation, mouse: LC50 = 342 ppm/1H; Inhalation, mouse: LC50 = 5000 mg/m3/5M; Inhalation, mouse: LC50 = 270 mg/m3/60M; Inhalation, rat: LC50 = 1276 ppm/1H; Inhalation, rat: LC50 = 1100 mg/m3/60M.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Niobium - Not listed by ACGIH, IARC, or NTP.
Hydrogen fluoride - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: HYDROFLUORIC ACID
Hazard Class: 8 (6.1)
UN Number: 1790
Packing Group: II
IMO
Shipping Name: HYDROFLUORIC ACID
Hazard Class: 8 (6.1)
UN Number: 1790
Packing Group: II
RID/ADR
Shipping Name: HYDROFLUORIC ACID SOLUTION
Hazard Class: 8
UN Number: 1790
Packing group: II
USA RQ: CAS# 7664-39-3: 100 lb final RQ; 45.4 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ C
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7440-03-1: No information available.
CAS# 7664-39-3: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7440-03-1 is listed on Canadas DSL List.
CAS# 7664-39-3 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 7440-03-1 is not listed on Canadas Ingredient Disclosure List.
CAS# 7664-39-3 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-03-1 is listed on the TSCA inventory.
CAS# 7664-39-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
