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Name:
OptiPhase MP
Synonym:
None
CAS:
0-00-0
Section 1 - Chemical Product
MSDS Name:OptiPhase MP
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
0-00-0 Acetic acid 0-2.0 200-580-7
Hazard Symbols: XN F
Risk Phrases: 10 20/21 38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and in contact with skin.
Irritating to skin.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
May cause severe skin irritation. May be harmful if absorbed through the skin. Prolonged exposure may cause the formation of vesicles (blisters). Contact with the skin may cause erythema (redness), dryness, and defatting.
Ingestion:
Aspiration hazard. May cause irritation of the digestive tract. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May cause blood abnormalities.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Inhalation of vapor may cause respiratory tract irritation.
Prolonged exposure may result in dizziness and general weakness.
Irritation may lead to chemical pneumonitis and pulmonary edema.
Chronic:
Chronic exposure to organic solvents has been associated with various neurotoxic effects including permanent brain and nervous system damage.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Discard contaminated clothing in a manner which limits further exposure.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May be ignited by heat, sparks, and flame. Vapors may form an explosive mixture with air. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Avoid storage in glass containers.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 0-00-0: CAS# 0-00-1: CAS# 0-00-2: CAS# 64-19-7: United States OSHA: 10 ppm TWA; 25 mg/m3 TWA Belgium - TWA: 10 ppm VLE; 25 mg/m3 VLE Belgium - STEL: 15 ppm VLE; 38 mg/m3 VLE France - VLE: 10 ppm VLE; 25 mg/m3 VLE Germany: 10 ppm TWA; 25 mg/m3 TWA Japan: 10 ppm OEL; 25 mg/m3 OEL Malaysia: 10 ppm TWA; 25 mg/m3 TWA Netherlands: 10 ppm MAC; 25 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 10 ppm VLA-ED; 25 mg/m3 VLA-ED Spain: 15 ppm VLA-EC; 37 mg/m3 VLA-EC CAS# 111-42-2: Belgium - TWA: 0.46 ppm VLE; 2 mg/m3 VLE France - VME: 3 ppm VME; 15 mg/m3 VME Germany: 15 mg/m3 TWA (inhalable fraction) Germany: Skin absorber Malaysia: 0.46 ppm TWA; 2 mg/m3 TWA Netherlands: 0.46 ppm MAC; 2 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 0.46 ppm VLA-ED; 2 mg/m3 VLA-ED CAS# 1330-20-7: United Kingdom, WEL - TWA: 50 ppm TWA; 220 mg/m3 TWA United Kingdom, WEL - STEL: 100 ppm STEL; 441 mg/m3 STEL United States OSHA: 100 ppm TWA; 435 mg/m3 TWA Belgium - TWA: 50 ppm VLE; 221 mg/m3 VLE Belgium - STEL: 150 ppm VLE; 442 mg/m3 VLE France - VME: 100 ppm VME; 435 mg/m3 VME France - VLE: 150 ppm VLE; 650 mg/m3 VLE Germany: 100 ppm TWA; 440 mg/m3 TWA Germany: Skin absorber Japan: 50 ppm OEL; 217 mg/m3 OEL Malaysia: 199 ppm TWA; 434 mg/m3 TWA Netherlands: 50 ppm MAC; 210 mg/m3 MAC Russia: 50 mg/m3 TWA Spain: 50 ppm VLA-ED; 221 mg/m3 VLA-ED Spain: 100 ppm VLA-EC; 442 mg/m3 VLA-EC CAS# 16940-66-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 6.2 mm Hg @20C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 24 deg C ( 75.20 deg F)
Explosion Limits, lower: 1.0%
Explosion Limits, upper: 7.0%
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 0.86
Molecular Formula:
Molecular Weight:

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Acids, sulfuric acid, dimethyl formamide, acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), caustics (e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), fluorides (inorganic, e.g. ammonium fluoride, calcium fluoride, cesium fluoride), isocyanates (e.g. methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals as powders (e.g. hafnium, raney nickel), metals and metal compounds (toxic, e.g. beryllium, lead acetate, nickel carbonyl, tetraethyl lead),.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 0-00-0 unlisted.
CAS# 0-00-1 unlisted.
CAS# 0-00-2 unlisted.
CAS# 64-19-7: AF1225000 CAS# 111-42-2: KL2975000 CAS# 1330-20-7: ZE2100000 CAS# 16940-66-2: ED3325000 LD50/LC50:
Not available.
Not available.
Not available.
CAS# 64-19-7: Draize test, rabbit, skin: 50 mg/24H Mild; Inhalation, mouse: LC50 = 5620 ppm/1H; Oral, rat: LD50 = 3310 mg/kg; Skin, rabbit: LD50 = 1060 uL/kg.
CAS# 111-42-2: Dermal, guinea pig: LD50 = 11900 uL/kg; Draize test, rabbit, eye: 5500 mg Severe; Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 3300 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat: LD50 = 620 uL/kg; Skin, rabbit: LD50 = 7640 uL/kg.
CAS# 1330-20-7: Draize test, rabbit, eye: 87 mg Mild; Draize test, rabbit, eye: 5 mg/24H Severe; Draize test, rabbit, skin: 100% Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate; Inhalation, rat: LC50 = 5000 ppm/4H; Oral, mouse: LD50 = 2119 mg/kg; Oral, rat: LD50 = 4300 mg/kg; Skin, rabbit: LD50 = >1700 mg/kg.
CAS# 16940-66-2: Inhalation, rat: LC50 = 36 mg/m3; Oral, mouse: LD50 = 50 mg/kg; Oral, rabbit: LD50 = 50 mg/kg; Oral, rat: LD50 = 162 mg/kg; Skin, rabbit: LD50 = 230 mg/kg.
Carcinogenicity:
Nonyl phenol (9 mole) ethoxylate - Not listed by ACGIH, IARC, or NTP.
Nonyl phenol (10 mole) ethoxylate - Not listed by ACGIH, IARC, or NTP.
Polyoxyethylene alkylphenylether phosphate - Not listed by ACGIH, IARC, or NTP.
Acetic acid - Not listed by ACGIH, IARC, or NTP.
Diethanolamine - Not listed by ACGIH, IARC, or NTP.
Xylenes (o-, m-, p- isomers) - Not listed by ACGIH, IARC, or NTP.
Sodium borohydride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Acute and long-term toxicity to fish and invertebrates: LD50 for goldfish is 13 mg/L/24 Hr.

Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: FLAMMABLE LIQUID, NOS
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, NOS
Hazard Class: 3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, NOS
Hazard Class: 3
UN Number: 1993
Packing group: III
USA RQ: CAS# 64-19-7: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 111-42-2: 100 lb final RQ; 45.4 kg final RQ
USA RQ: CAS# 1330-20-7: 100 lb final RQ; 45.4 kg final RQ

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 38 Irritating to skin.
Safety Phrases:
S 25 Avoid contact with eyes.
WGK (Water Danger/Protection)
CAS# 0-00-0: No information available.
CAS# 0-00-1: No information available.
CAS# 0-00-2: No information available.
CAS# 64-19-7: 1
CAS# 111-42-2: 1
CAS# 1330-20-7: 2
CAS# 16940-66-2: 2
Canada
CAS# 64-19-7 is listed on Canadas DSL List.
CAS# 111-42-2 is listed on Canadas DSL List.
CAS# 1330-20-7 is listed on Canadas DSL List.
CAS# 16940-66-2 is listed on Canadas DSL List.
CAS# 0-00-0 is not listed on Canadas Ingredient Disclosure List.
CAS# 0-00-1 is not listed on Canadas Ingredient Disclosure List.
CAS# 0-00-2 is not listed on Canadas Ingredient Disclosure List.
CAS# 64-19-7 is listed on Canadas Ingredient Disclosure List.
CAS# 111-42-2 is listed on Canadas Ingredient Disclosure List.
CAS# 1330-20-7 is not listed on Canadas Ingredient Disclosure List.
CAS# 16940-66-2 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 0-00-0 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 0-00-1 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 0-00-2 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 64-19-7 is listed on the TSCA inventory.
CAS# 111-42-2 is listed on the TSCA inventory.
CAS# 1330-20-7 is listed on the TSCA inventory.
CAS# 16940-66-2 is listed on the TSCA inventory.