Name:
Palladium on 1/8" Alumina Pellets (0.5% Pd)
Synonym:
None
CAS:
1314-08-5
Section 1 - Chemical Product
MSDS Name:Palladium on 1/8" Alumina Pellets (0.5% Pd)
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1314-08-5 | Palladiummonoxide | 215-218-3 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Dust may cause mechanical irritation. Causes redness and pain.
Skin:
Dust may cause mechanical irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause contact dermatitis.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
May cause bone marrow damage. Aluminum may be readily absorbed from the gastrointestinal tract.
Inhalation:
Dust is irritating to the respiratory tract. May cause chemical bronchitis with coughing and difficulty in breathing. May cause lung damage.
Chronic:
Chronic inhalation of fine dusts may cause lung damage. Animal studies have reported the development of tumors. Chronic ingestion of aluminum oxide may produce loss of appetite, hemolysis, renal deposition and bone marrow damage
Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Dust may cause mechanical irritation. Causes redness and pain.
Skin:
Dust may cause mechanical irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause contact dermatitis.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
May cause bone marrow damage. Aluminum may be readily absorbed from the gastrointestinal tract.
Inhalation:
Dust is irritating to the respiratory tract. May cause chemical bronchitis with coughing and difficulty in breathing. May cause lung damage.
Chronic:
Chronic inhalation of fine dusts may cause lung damage. Animal studies have reported the development of tumors. Chronic ingestion of aluminum oxide may produce loss of appetite, hemolysis, renal deposition and bone marrow damage
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Deferoxamine has been used to treat dialysis encephalopathy and osteomalacia and used to diagnose aluminum related osteodystrophy.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Deferoxamine has been used to treat dialysis encephalopathy and osteomalacia and used to diagnose aluminum related osteodystrophy.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Dust can be an explosion hazard when exposed to heat or flame. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Dust can be an explosion hazard when exposed to heat or flame. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Spills/Leaks:
Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limits.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Wet processing methods may be used to reduce dust generation.
Exposure Limits CAS# 1314-08-5: CAS# 1344-28-1: United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE (as Al) France - VME: 10 mg/m3 VME Japan: 0.5 mg/m3 OEL (respirable dust); 2 mg/m3 OEL (total dust) Malaysia: 10 mg/m3 TWA (particulate matter containing no asbestos <1% crystalline sili Netherlands: 10 mg/m3 MAC Spain: 10 mg/m3 VLA-ED CAS# 7440-05-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limits.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Wet processing methods may be used to reduce dust generation.
Exposure Limits CAS# 1314-08-5: CAS# 1344-28-1: United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE (as Al) France - VME: 10 mg/m3 VME Japan: 0.5 mg/m3 OEL (respirable dust); 2 mg/m3 OEL (total dust) Malaysia: 10 mg/m3 TWA (particulate matter containing no asbestos <1% crystalline sili Netherlands: 10 mg/m3 MAC Spain: 10 mg/m3 VLA-ED CAS# 7440-05-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Pellets
Color: grey
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 2000 deg C
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: Not applicable.
Molecular Weight: 106.42
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. Volatile at high temperatures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, alcohols, chlorine trifluoride, ethylene oxide, halocarbons, halogens, oxygen difluoride, phosphorus, sodium nitrate, sulfur, vinyl acetate, hydrogen peroxides, sodium tetrahydroborate, arsenic, isopropyl alcohol, heat, moisture, hydrogen bromide gas, formic acid.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, oxides of sulfur, oxides of phosphorus, irritating and toxic fumes and gases, hydrogen gas, aluminum fumes.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures. Volatile at high temperatures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, alcohols, chlorine trifluoride, ethylene oxide, halocarbons, halogens, oxygen difluoride, phosphorus, sodium nitrate, sulfur, vinyl acetate, hydrogen peroxides, sodium tetrahydroborate, arsenic, isopropyl alcohol, heat, moisture, hydrogen bromide gas, formic acid.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, oxides of sulfur, oxides of phosphorus, irritating and toxic fumes and gases, hydrogen gas, aluminum fumes.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1314-08-5 unlisted.
CAS# 1344-28-1: BD1200000 CAS# 7440-05-3: RT3480500 RT3593400 LD50/LC50:
Not available.
Not available.
Not available.
Carcinogenicity:
Palladiummonoxide - Not listed by ACGIH, IARC, or NTP.
Aluminum oxide - Not listed by ACGIH, IARC, or NTP.
Palladium - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 1314-08-5 unlisted.
CAS# 1344-28-1: BD1200000 CAS# 7440-05-3: RT3480500 RT3593400 LD50/LC50:
Not available.
Not available.
Not available.
Carcinogenicity:
Palladiummonoxide - Not listed by ACGIH, IARC, or NTP.
Aluminum oxide - Not listed by ACGIH, IARC, or NTP.
Palladium - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1314-08-5: 1
CAS# 1344-28-1: 0
CAS# 7440-05-3: 0
Canada
CAS# 1314-08-5 is listed on Canadas DSL List.
CAS# 1344-28-1 is listed on Canadas DSL List.
CAS# 7440-05-3 is listed on Canadas DSL List.
CAS# 1314-08-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 1344-28-1 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-05-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1314-08-5 is listed on the TSCA inventory.
CAS# 1344-28-1 is listed on the TSCA inventory.
CAS# 7440-05-3 is listed on the TSCA inventory.
