Name:
Palladium on calcium carbonate 5% Pd
Synonym:
None
CAS:
471-34-1
Section 1 - Chemical Product
MSDS Name:Palladium on calcium carbonate 5% Pd
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 471-34-1 | Carbonic acid, calcium salt (1:1) | 95 | 207-439-9 |
| Hazard Symbols: None Listed. Risk Phrases: 43 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
May cause sensitization by skin contact.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Chronic ingestion may cause hypercalcemia, alkalosis, and kidney damage. May also produce "milk-alkali syndrome" characterized by neurological symptoms such as irritability, lethargy, stupor, and coma.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic ingestion may cause hypercalcemia, alkalosis, and kidney damage. May also produce "milk-alkali syndrome" characterized by neurological symptoms such as irritability, lethargy, stupor, and coma.
May cause sensitization by skin contact.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Chronic ingestion may cause hypercalcemia, alkalosis, and kidney damage. May also produce "milk-alkali syndrome" characterized by neurological symptoms such as irritability, lethargy, stupor, and coma.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic ingestion may cause hypercalcemia, alkalosis, and kidney damage. May also produce "milk-alkali syndrome" characterized by neurological symptoms such as irritability, lethargy, stupor, and coma.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Minimize dust generation and accumulation.
Avoid breathing dust, vapor, mist, or gas. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep away from strong acids.
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Minimize dust generation and accumulation.
Avoid breathing dust, vapor, mist, or gas. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep away from strong acids.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 471-34-1: United Kingdom, WEL - TWA: (listed as calcium carbonate): 10 mg/m TWA (inhalable dust); 4 mg/m3 TWA (respirable dust) United Kingdom, WEL - STEL: (listed as calcium carbonate): 30 mg/ STEL (inhalable dust); 12 mg/m3 STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) (listed under Calcium carbonate).
Belgium - TWA: (listed as calcium carbonate): 10 mg/m3 VLE France - VME: (listed as calcium carbonate): 10 mg/m3 VME Germany: (listed as calcium carbonate): 10 mg/m3 VME Japan: (listed as calcium carbonate): 1 mg/m3 OEL (respirable dus 4 mg/m3 OEL (total dust) Malaysia: (listed as calcium carbonate): 10 mg/m3 TWA (particulat matter containing no asbestos and <1% crystalline sili Netherlands: 10 mg/m3 MAC Russia: 6 mg/m3 TWA Spain: 10 mg/m3 VLA-ED CAS# 7440-05-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate ventilation to keep airborne concentrations low. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 471-34-1: United Kingdom, WEL - TWA: (listed as calcium carbonate): 10 mg/m TWA (inhalable dust); 4 mg/m3 TWA (respirable dust) United Kingdom, WEL - STEL: (listed as calcium carbonate): 30 mg/ STEL (inhalable dust); 12 mg/m3 STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) (listed under Calcium carbonate).
Belgium - TWA: (listed as calcium carbonate): 10 mg/m3 VLE France - VME: (listed as calcium carbonate): 10 mg/m3 VME Germany: (listed as calcium carbonate): 10 mg/m3 VME Japan: (listed as calcium carbonate): 1 mg/m3 OEL (respirable dus 4 mg/m3 OEL (total dust) Malaysia: (listed as calcium carbonate): 10 mg/m3 TWA (particulat matter containing no asbestos and <1% crystalline sili Netherlands: 10 mg/m3 MAC Russia: 6 mg/m3 TWA Spain: 10 mg/m3 VLA-ED CAS# 7440-05-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: gray or dark gray
Odor: Odorless.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: >600 deg C
Solubility in water: insoluble
Specific Gravity/Density: 12.02 g/cm3
Molecular Formula: Not applicable.
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, acids.
Incompatibilities with Other Materials:
Fluorine, acids, aluminum, ammonium salts, mercury + hydrogen, hydrogen + hydrogen peroxide, isopropyl alcohol, formic acid and sodium tetrahydroborate.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen gas, calcium oxide.
Hazardous Polymerization: Has not been reported
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, acids.
Incompatibilities with Other Materials:
Fluorine, acids, aluminum, ammonium salts, mercury + hydrogen, hydrogen + hydrogen peroxide, isopropyl alcohol, formic acid and sodium tetrahydroborate.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen gas, calcium oxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 471-34-1: FF9335000 CAS# 7440-05-3: RT3480500 RT3593400 LD50/LC50:
CAS# 471-34-1: Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, rat: LD50 = 6450 mg/kg.
CAS# 7440-05-3.
Carcinogenicity:
Carbonic acid, calcium salt (1:1) - Not listed by ACGIH, IARC, or NTP.
Palladium - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 471-34-1: FF9335000 CAS# 7440-05-3: RT3480500 RT3593400 LD50/LC50:
CAS# 471-34-1: Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, rat: LD50 = 6450 mg/kg.
CAS# 7440-05-3.
Carcinogenicity:
Carbonic acid, calcium salt (1:1) - Not listed by ACGIH, IARC, or NTP.
Palladium - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
This chemical is expected to cause no oxygen depletion in aquatic systems. It has a low potential to affect aquatic organisms. Acute aquatic effects: 48-hour LC50; Mosquito fish: 56,000 mg/L.
This chemical is expected to cause no oxygen depletion in aquatic systems. It has a low potential to affect aquatic organisms. Acute aquatic effects: 48-hour LC50; Mosquito fish: 56,000 mg/L.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 471-34-1: 0
CAS# 7440-05-3: 0
Canada
CAS# 471-34-1 is listed on Canadas DSL List.
CAS# 7440-05-3 is listed on Canadas DSL List.
CAS# 471-34-1 is not listed on Canadas Ingredient Disclosure List.
CAS# 7440-05-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 471-34-1 is listed on the TSCA inventory.
CAS# 7440-05-3 is listed on the TSCA inventory.
