Name:
Phenanthrene
Synonym:
Non
CAS:
85-01-8
Section 1 - Chemical Product
MSDS Name:Phenanthrene
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 85-01-8 | Phenanthrene | 100.0 | 201-581-5 |
| Hazard Symbols: XN Risk Phrases: 20/21/22 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Do not let this chemical enter the environment.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Do not let this chemical enter the environment.
Section 7 - HANDLING and STORAGE
Handling:
Avoid contact with skin and eyes. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Avoid contact with skin and eyes. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 85-01-8: United States OSHA: 0.2 mg/m3 TWA (as benzene soluble fraction) (listed under Coal tar pitches).
Belgium - TWA: (listed as coal tar pitches): 0.2 mg/m3 VLE France - VME: (listed as coal tar pitches): 0.2 mg/m3 VME (vapors mists, benzene-soluble fraction) Germany: (listed as coal tar pitches): 0.2 mg/m3 VME (vapors and mists, benzene-soluble fraction) Malaysia: (listed as coal tar pitches): 0.2 mg/m3 TWA (as benzene solubles) Russia: 0.8 mg/m3 TWA Spain: (listed as coal tar pitches): 0.2 mg/m3 VLA-ED (benzene soluble fraction) Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 85-01-8: United States OSHA: 0.2 mg/m3 TWA (as benzene soluble fraction) (listed under Coal tar pitches).
Belgium - TWA: (listed as coal tar pitches): 0.2 mg/m3 VLE France - VME: (listed as coal tar pitches): 0.2 mg/m3 VME (vapors mists, benzene-soluble fraction) Germany: (listed as coal tar pitches): 0.2 mg/m3 VME (vapors and mists, benzene-soluble fraction) Malaysia: (listed as coal tar pitches): 0.2 mg/m3 TWA (as benzene solubles) Russia: 0.8 mg/m3 TWA Spain: (listed as coal tar pitches): 0.2 mg/m3 VLA-ED (benzene soluble fraction) Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 336 deg C
Freezing/Melting Point: 100 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C14H10
Molecular Weight: 178.07
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 85-01-8: SF7175000 LD50/LC50:
CAS# 85-01-8: Oral, mouse: LD50 = 700 mg/kg; Oral, rat: LD50 = 1.8 gm/kg.
Carcinogenicity:
Phenanthrene - NTP: Known carcinogen (listed as Coal tar pitches).
IARC: Group 1 carcinogen (listed as Coal tar pitches).
Other:
See actual entry in RTECS for complete information.
CAS# 85-01-8: SF7175000 LD50/LC50:
CAS# 85-01-8: Oral, mouse: LD50 = 700 mg/kg; Oral, rat: LD50 = 1.8 gm/kg.
Carcinogenicity:
Phenanthrene - NTP: Known carcinogen (listed as Coal tar pitches).
IARC: Group 1 carcinogen (listed as Coal tar pitches).
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
The product is chemically identically to the natural amino acid L-Serine and can therefore be degraded microbiologically.
The product is chemically identically to the natural amino acid L-Serine and can therefore be degraded microbiologically.
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 85-01-8: 5000 lb final RQ; 2270 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
WGK (Water Danger/Protection)
CAS# 85-01-8: No information available.
Canada
CAS# 85-01-8 is listed on Canadas DSL List.
CAS# 85-01-8 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 85-01-8 is listed on the TSCA inventory.
