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Name:
Phenethylamine
Synonym:
beta-Aminoethylbenzene; 1-Amino-2-phenylethane; 2-Amino-1-phenylethane; Benzeneethanamine; beta-Phenethylamine; 1-Phenyl-2-aminoethane; Phenylethylamine; beta-Phenylethylamine; omega-Phenylethylamine; 2-Phenylethylamine; PEA
CAS:
64-04-0
Section 1 - Chemical Product
MSDS Name:Phenethylamine
Synonym:beta-Aminoethylbenzene; 1-Amino-2-phenylethane; 2-Amino-1-phenylethane; Benzeneethanamine; beta-Phenethylamine; 1-Phenyl-2-aminoethane; Phenylethylamine; beta-Phenylethylamine; omega-Phenylethylamine; 2-Phenylethylamine; PEA
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
64-04-0 Phenethylamine 99 200-574-4
Hazard Symbols: C
Risk Phrases: 22 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal tract burns. May cause central nervous system effects.
Inhalation:
May cause severe irritation of the respiratory tract with possible burns. Inhalation at high concentrations may cause CNS depression and asphixiation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid and vapor.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat and flame. Do not breathe vapor or mist.
Storage:
Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Storage under a nitrogen blanket has been recommended.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 64-04-0: Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear colorless to light yellow
Odor: fish-like
pH: Strong base
Vapor Pressure: 0.3 mm Hg @ 20 deg C
Viscosity: 2.4 mPa-s @ 23 deg C
Boiling Point: 197-200 deg C
Freezing/Melting Point: -60 deg C
Autoignition Temperature: 425 deg C ( 797.00 deg F)
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: 1.0%
Explosion Limits, upper: 5.5%
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 0.96 g/ml @ 20C
Molecular Formula: C8H11N
Molecular Weight: 121.18

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. Absorbs carbon dioxide from the air.
Conditions to Avoid:
Ignition sources, excess heat, prolonged exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid anhydrides, acid chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-04-0: SG8750000 LD50/LC50:
Not available.
Oral, rat: LD50 = 400-800 mg/kg (Kodak) mg/kg (Kodak) (Kodak) Carcinogenicity:
Phenethylamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 64-04-0: 1
Canada
CAS# 64-04-0 is listed on Canadas DSL List.
CAS# 64-04-0 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-04-0 is listed on the TSCA inventory.