Name:
Phenol 99+% Loose Crystals Biochemical Grade
Synonym:
Carbolic Acid; Phenylic Acid; Hydroxybenzene; Monohydroxybenzene; Phenyl Hydroxide
CAS:
108-95-2
Section 1 - Chemical Product
MSDS Name:Phenol 99+% Loose Crystals Biochemical Grade
Synonym:Carbolic Acid; Phenylic Acid; Hydroxybenzene; Monohydroxybenzene; Phenyl Hydroxide
Synonym:Carbolic Acid; Phenylic Acid; Hydroxybenzene; Monohydroxybenzene; Phenyl Hydroxide
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 108-95-2 | Phenol | 99+% | 203-632-7 |
| Hazard Symbols: T Risk Phrases: 34 24/25 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns. Toxic in contact with skin and if swallowed.Corrosive.Air sensitive.Hygroscopic.
Potential Health Effects
Eye:
Contact with liquid or vapor causes severe burns and possible irreversible eye damage. May cause chemical conjunctivitis and corneal damage.
Skin:
Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the digestive tract. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
May cause perforation of the digestive tract. Causes digestive tract burns with immediate pain, swelling of the throat, convulsions, and possible coma.
Inhalation:
Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May be fatal if exposed to high concentrations. Aspiration may lead to pulmonary edema. May also cause pallor, loss of appetite, nausea, vomiting, diarrhea, weakness, darkened urine, headache, sweating, convulsions, cyanosis, unconsciousness, fatigue, pulmonary edema and coma.
Inhalation at high concentrations may cause CNS depression and asphixiation.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. May cause liver and kidney damage. May cause reproductive and fetal effects. Effects may be delayed. Laboratory experiments have resulted in mutagenic effects.
Repeated skin contact may cause dermatitis with dark pigmentation of the skin. Animal studies have reported the development of tumors.
Causes burns. Toxic in contact with skin and if swallowed.Corrosive.Air sensitive.Hygroscopic.
Potential Health Effects
Eye:
Contact with liquid or vapor causes severe burns and possible irreversible eye damage. May cause chemical conjunctivitis and corneal damage.
Skin:
Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the digestive tract. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
May cause perforation of the digestive tract. Causes digestive tract burns with immediate pain, swelling of the throat, convulsions, and possible coma.
Inhalation:
Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May be fatal if exposed to high concentrations. Aspiration may lead to pulmonary edema. May also cause pallor, loss of appetite, nausea, vomiting, diarrhea, weakness, darkened urine, headache, sweating, convulsions, cyanosis, unconsciousness, fatigue, pulmonary edema and coma.
Inhalation at high concentrations may cause CNS depression and asphixiation.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. May cause liver and kidney damage. May cause reproductive and fetal effects. Effects may be delayed. Laboratory experiments have resulted in mutagenic effects.
Repeated skin contact may cause dermatitis with dark pigmentation of the skin. Animal studies have reported the development of tumors.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure. SPEEDY ACTION IS CRITICAL! Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Persons with liver or kidney disease should not be exposed to phenol for any length of time.
Antidote: Activated charcoal, followed by cathartic, may be preferred to ipecac induced emesis or lavage in decontamination of the GI tract and preventing systemic absorption of phenol.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure. SPEEDY ACTION IS CRITICAL! Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Persons with liver or kidney disease should not be exposed to phenol for any length of time.
Antidote: Activated charcoal, followed by cathartic, may be preferred to ipecac induced emesis or lavage in decontamination of the GI tract and preventing systemic absorption of phenol.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Store protected from light. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Store protected from moisture. Store protected from light.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Store protected from light. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Store protected from moisture. Store protected from light.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR ??1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirators use.
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR ??1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirators use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Appearance: white
Odor: sharp sweet, tangy odor detectable above
pH: Not available.
Vapor Pressure: 0.36 mm Hg
Viscosity: Not available.
Boiling Point: 182 deg C @ 760.00mm Hg
Freezing/Melting Point: 43 deg C
Autoignition Temperature: 605 deg C ( 1,121.00 deg F)
Flash Point: 79 deg C ( 174.20 deg F)
Explosion Limits, lower: 1.30 vol %
Explosion Limits, upper: 9.50 vol %
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.0710g/cm3
Molecular Formula: C6H6O
Molecular Weight: 94.11
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, isocyanates, acetaldehyde, nitrides (e.g. potassium nitride, sodium nitride), calcium hypochlorite, peroxomonosulfuric acid, nitrobenzene, sodium nitrite, aluminum chloride, peroxydisulfuric acid, 1,3-butadiene, boron trifluoride diethyl ether.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, isocyanates, acetaldehyde, nitrides (e.g. potassium nitride, sodium nitride), calcium hypochlorite, peroxomonosulfuric acid, nitrobenzene, sodium nitrite, aluminum chloride, peroxydisulfuric acid, 1,3-butadiene, boron trifluoride diethyl ether.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 108-95-2: SJ3325000 LD50/LC50:
CAS# 108-95-2: Draize test, rabbit, eye: 5 mg Severe; Draize test, rabbit, skin: 500 mg/24H Severe; Draize test, rabbit, skin: 100 mg Mild; Inhalation, mouse: LC50 = 177 mg/m3; Inhalation, rat: LC50 = 316 mg/m3; Oral, mouse: LD50 = 270 mg/kg; Oral, rat: LD50 = 317 mg/kg; Skin, rabbit: LD50 = 630 mg/kg; Skin, rat: LD50 = 669 mg/kg.
Carcinogenicity:
Phenol - ACGIH: A4 - Not Classifiable as a Human Carcinogen IARC: Group 3 carcinogen Other:
See actual entry in RTECS for complete information.
CAS# 108-95-2: SJ3325000 LD50/LC50:
CAS# 108-95-2: Draize test, rabbit, eye: 5 mg Severe; Draize test, rabbit, skin: 500 mg/24H Severe; Draize test, rabbit, skin: 100 mg Mild; Inhalation, mouse: LC50 = 177 mg/m3; Inhalation, rat: LC50 = 316 mg/m3; Oral, mouse: LD50 = 270 mg/kg; Oral, rat: LD50 = 317 mg/kg; Skin, rabbit: LD50 = 630 mg/kg; Skin, rat: LD50 = 669 mg/kg.
Carcinogenicity:
Phenol - ACGIH: A4 - Not Classifiable as a Human Carcinogen IARC: Group 3 carcinogen Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Water flea Daphnia: EC50=12 mg/l; 48-hour; CAS# 108-95-2: UnspecifiedWater flea Daphnia: EC50=4.0 mg/l; 96-hour; CAS# 108-95-2: UnspecifiedFish: Fathead Minnow: LC50 > 50 mg/l; 1 Hr; CAS# 108-95-2 Static @ 18-22CFish: Fathead Minnow: TLm = 41 mg/L; 48-hour; CAS# 108-95-2: Flow-through @ 15CFish: Bluegill/Sunfish: TLm = 19 / 5.7 mg/L; 96 Hr; CAS# 108-95-2: Flow-throughIf released to the environment, phenols primary removal mechanism is biodegradation which is generally rapid (days). If phenol is released to soil, it will readily leach and biodegrade. The biodegradation in soil is generally rapid with half-lives of under 5 days even in subsurface
Water flea Daphnia: EC50=12 mg/l; 48-hour; CAS# 108-95-2: UnspecifiedWater flea Daphnia: EC50=4.0 mg/l; 96-hour; CAS# 108-95-2: UnspecifiedFish: Fathead Minnow: LC50 > 50 mg/l; 1 Hr; CAS# 108-95-2 Static @ 18-22CFish: Fathead Minnow: TLm = 41 mg/L; 48-hour; CAS# 108-95-2: Flow-through @ 15CFish: Bluegill/Sunfish: TLm = 19 / 5.7 mg/L; 96 Hr; CAS# 108-95-2: Flow-throughIf released to the environment, phenols primary removal mechanism is biodegradation which is generally rapid (days). If phenol is released to soil, it will readily leach and biodegrade. The biodegradation in soil is generally rapid with half-lives of under 5 days even in subsurface
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: PHENOL, SOLID
Hazard Class: 6.1
UN Number: 1671
Packing Group: II
IMO
Shipping Name: PHENOL, SOLID
Hazard Class: 6.1
UN Number: 1671
Packing Group: II
RID/ADR
Shipping Name: PHENOL, SOLID
Dangerous Goods Code: 6.1(14B)
UN Number: 1671
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 34 Causes burns.
R 24/25 Toxic in contact with skin and if swallowed.
Safety Phrases:
S 1/2 Keep locked up and out of reach of children.
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 108-95-2: 2
United Kingdom Occupational Exposure Limits
CAS# 108-95-2: OES-United Kingdom, TWA 5 ppm TWA; 20 mg/m3 TWA
CAS# 108-95-2: OES-United Kingdom, STEL 10 ppm STEL; 39 mg/m3 STEL
Canada
CAS# 108-95-2 is listed on Canadas DSL List.
CAS# 108-95-2 is listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 108-95-2: OEL-ARAB Republic of Egypt:TWA 5 ppm (19 mg/m3);Skin
OEL-AUSTRALIA:TWA 5 ppm (19 mg/m3);Skin
OEL-BELGIUM:TWA 5 ppm (19 mg/m3);Skin
OEL-CZECHOSLOVAKIA:TWA 20 mg/m3;STEL 40 mg/m3
OEL-DENMARK:TWA 5 ppm (19 mg/m3);Skin
OEL-FINLAND:TWA 5 ppm (19 mg/m3);STEL 10 ppm (38 mg/m3);Skin
OEL-FRANCE:TWA 5 ppm (19 mg/m3);Skin
OEL-GERMANY:TWA 5 ppm (19 mg/m3);Skin
OEL-HUNGARY:TWA 4 mg/m3;STEL 8 mg/m3;Skin
OEL-JAPAN:TWA 5 ppm (19 mg/m3);Skin
OEL-THE NETHERLANDS:TWA 5 ppm (19 mg/m3);Skin
OEL-THE PHILIPPINES:TWA 5 ppm (10 mg/m3);Skin
OEL-POLAND:TWA 10 ppm
OEL-RUSSIA:TWA 5 ppm;STEL 0.3 mg/m3;Skin
OEL-SWEDEN:TWA 1 ppm (4 mg/m3);STEL 2 ppm (8 mg/m3);Skin
OEL-SWITZERLAND:TWA 5 ppm (19 mg/m3);STEL 10 ppm (38 mg/m3);Skin
OEL-THAILAND:TWA 5 ppm (19 mg/m3)
OEL-TURKEY:TWA 5 ppm (19 mg/m3);Skin
OEL-UNITED KINGDOM:TWA 5 ppm (19 mg/m3);STEL 10 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 108-95-2 is listed on the TSCA inventory.
