Name:
Phosphorus White Sticks
Synonym:
Non
CAS:
7723-14-0
Section 1 - Chemical Product
MSDS Name:Phosphorus White Sticks
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7723-14-0 | Phosphorus | 100.0 | 231-768-7 |
| Hazard Symbols: T F Risk Phrases: 17 26/28 35 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Spontaneously flammable in air. Very toxic by inhalation and if swallowed. Causes severe burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Chronic exposure may lead to anemia, digestive tract effects, brittleness of bones, and necrosis of the jaw.
Ingestion:
May be fatal if swallowed. Causes gastrointestinal tract burns.
Inhalation:
May be fatal if inhaled. Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May cause visual abnormalities.
Chronic:
Chronic exposure may lead to anemia, digestive tract effects, brittleness of bones, and necrosis of the jaw.
Spontaneously flammable in air. Very toxic by inhalation and if swallowed. Causes severe burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Chronic exposure may lead to anemia, digestive tract effects, brittleness of bones, and necrosis of the jaw.
Ingestion:
May be fatal if swallowed. Causes gastrointestinal tract burns.
Inhalation:
May be fatal if inhaled. Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May cause visual abnormalities.
Chronic:
Chronic exposure may lead to anemia, digestive tract effects, brittleness of bones, and necrosis of the jaw.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
Material can spontaneously ignite (pyrophoric) when exposed to air at normal or slightly elevated temperatures. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. If combustion occurs in a confined space, it will cause asphyxiation.
Extinguishing Media:
Use water only!
Material can spontaneously ignite (pyrophoric) when exposed to air at normal or slightly elevated temperatures. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. If combustion occurs in a confined space, it will cause asphyxiation.
Extinguishing Media:
Use water only!
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Avoid generating dusty conditions. Flush down the spill with a large amount of water. Cover with sand and place into a closed container for disposal. Provide ventilation.
Spills/Leaks:
Avoid generating dusty conditions. Flush down the spill with a large amount of water. Cover with sand and place into a closed container for disposal. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 7723-14-0: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.1 mg/m3 TWA Belgium - TWA: 0.02 ppm VLE; 0.1 mg/m3 VLE Germany: 0.1 mg/m3 TWA (inhalable fraction) Japan: 0.1 mg/m3 OEL Malaysia: 0.02 ppm TWA; 0.1 mg/m3 TWA Netherlands: 0.1 mg/m3 MAC Russia: 0.03 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 7723-14-0: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.1 mg/m3 TWA Belgium - TWA: 0.02 ppm VLE; 0.1 mg/m3 VLE Germany: 0.1 mg/m3 TWA (inhalable fraction) Japan: 0.1 mg/m3 OEL Malaysia: 0.02 ppm TWA; 0.1 mg/m3 TWA Netherlands: 0.1 mg/m3 MAC Russia: 0.03 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white to yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 1 mm Hg @76.6C
Viscosity: Not available.
Boiling Point: 536 deg F
Freezing/Melting Point: 111 deg F
Autoignition Temperature: 86 deg F ( 30.00 deg C)
Flash Point: Not applicable.
Explosion Limits, lower: None available
Explosion Limits, upper: None available
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 1.82
Molecular Formula: P
Molecular Weight: 30.9738
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at normal temperatures in tightly closed containers under an inert atmosphere.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Reacts explosively with a large number of compounds and elements.
Please refer to NFPA s Fire Protection guide to Hazardous Materials for details. May explode on contact with oxidizing materials. Darkens on exposure to light. Produces acrid fumes in air.
Hazardous Decomposition Products:
Oxides of phosphorus.
Hazardous Polymerization: Has not been reported.
Stable at normal temperatures in tightly closed containers under an inert atmosphere.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Reacts explosively with a large number of compounds and elements.
Please refer to NFPA s Fire Protection guide to Hazardous Materials for details. May explode on contact with oxidizing materials. Darkens on exposure to light. Produces acrid fumes in air.
Hazardous Decomposition Products:
Oxides of phosphorus.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7723-14-0: TH3495000 TH3500000 LD50/LC50:
CAS# 7723-14-0: Oral, mouse: LD50 = 11.5 mg/kg; Oral, mouse: LD50 = 4820 ug/kg; Oral, rabbit: LD50 = 105 mg/kg; Oral, rat: LD50 = 11.5 mg/kg; Oral, rat: LD50 = 3030 ug/kg.
Carcinogenicity:
Phosphorus - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7723-14-0: TH3495000 TH3500000 LD50/LC50:
CAS# 7723-14-0: Oral, mouse: LD50 = 11.5 mg/kg; Oral, mouse: LD50 = 4820 ug/kg; Oral, rabbit: LD50 = 105 mg/kg; Oral, rat: LD50 = 11.5 mg/kg; Oral, rat: LD50 = 3030 ug/kg.
Carcinogenicity:
Phosphorus - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: PHOSPHORUS, AMORPHOUS
Hazard Class: 4.1
UN Number: 1338
Packing Group: III
IMO
Shipping Name: PHOSPHORUS, AMORPHOUS
Hazard Class: 4.1
UN Number: 1338
Packing Group: III
RID/ADR
Shipping Name: PHOSPHORUS, AMORPHOUS
Hazard Class: 4.1
UN Number: 1338
Packing group: III
USA RQ: CAS# 7723-14-0: 1 lb final RQ; 0.454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 17 Spontaneously flammable in air.
R 26/28 Very toxic by inhalation and if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 3 Keep in a cool place.
S 5 Keep emsdss under ... (appropriate liquid to
be specified by the manufacturer).
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7723-14-0: No information available.
Canada
CAS# 7723-14-0 is listed on Canadas DSL List.
CAS# 7723-14-0 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7723-14-0 is listed on the TSCA inventory.
