Name:
Platinum on calcium carbonate (5% pt)
Synonym:
None
CAS:
471-34-1
Section 1 - Chemical Product
MSDS Name:Platinum on calcium carbonate (5% pt)
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 471-34-1 | Carbonic acid | ~95.0 | 207-439-9 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation. May cause dermatitis.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. Inhalation of the dust of soluble platinum salts is irritating and may cause runny nose, sneezing, tightness of chest, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), wheezing, cough.
Chronic:
No information found.
Not available.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation. May cause dermatitis.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. Inhalation of the dust of soluble platinum salts is irritating and may cause runny nose, sneezing, tightness of chest, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), wheezing, cough.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote: None reported.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote: None reported.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Provide ventilation.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 471-34-1: United Kingdom, WEL - TWA: (listed as calcium carbonate): 10 mg/m TWA (inhalable dust); 4 mg/m3 TWA (respirable dust) United Kingdom, WEL - STEL: (listed as calcium carbonate): 30 mg/ STEL (inhalable dust); 12 mg/m3 STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) (listed under Calcium carbonate).
Belgium - TWA: (listed as calcium carbonate): 10 mg/m3 VLE France - VME: (listed as calcium carbonate): 10 mg/m3 VME Germany: (listed as calcium carbonate): 10 mg/m3 VME Japan: (listed as calcium carbonate): 1 mg/m3 OEL (respirable dus 4 mg/m3 OEL (total dust) Malaysia: (listed as calcium carbonate): 10 mg/m3 TWA (particulat matter containing no asbestos and <1% crystalline sili Netherlands: 10 mg/m3 MAC Russia: 6 mg/m3 TWA Spain: 10 mg/m3 VLA-ED CAS# 7440-06-4: United Kingdom, WEL - TWA: 5 mg/m3 TWA United Kingdom, WEL - STEL: 15 mg/m3 STEL United States OSHA: 0.002 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE France - VME: 1 mg/m3 VME Germany: 1 mg/m3 TWA (inhalable fraction) Malaysia: 1 mg/m3 TWA Netherlands: 1 mg/m3 MAC Spain: 1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 471-34-1: United Kingdom, WEL - TWA: (listed as calcium carbonate): 10 mg/m TWA (inhalable dust); 4 mg/m3 TWA (respirable dust) United Kingdom, WEL - STEL: (listed as calcium carbonate): 30 mg/ STEL (inhalable dust); 12 mg/m3 STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) (listed under Calcium carbonate).
Belgium - TWA: (listed as calcium carbonate): 10 mg/m3 VLE France - VME: (listed as calcium carbonate): 10 mg/m3 VME Germany: (listed as calcium carbonate): 10 mg/m3 VME Japan: (listed as calcium carbonate): 1 mg/m3 OEL (respirable dus 4 mg/m3 OEL (total dust) Malaysia: (listed as calcium carbonate): 10 mg/m3 TWA (particulat matter containing no asbestos and <1% crystalline sili Netherlands: 10 mg/m3 MAC Russia: 6 mg/m3 TWA Spain: 10 mg/m3 VLA-ED CAS# 7440-06-4: United Kingdom, WEL - TWA: 5 mg/m3 TWA United Kingdom, WEL - STEL: 15 mg/m3 STEL United States OSHA: 0.002 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE France - VME: 1 mg/m3 VME Germany: 1 mg/m3 TWA (inhalable fraction) Malaysia: 1 mg/m3 TWA Netherlands: 1 mg/m3 MAC Spain: 1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Not applicable.
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Aluminum, hydrazine, phosphorus, hydrogen peroxides, lithium, acetone, arsenic, dioxygen difluoride, white phosphorus, carbon+methanol, nitrosyl chloride, ethanol, hydrogen+ air, methyl hydroperoxide, ozonides, peroxymonosulfuric acid, vanadium dichloride+water, selenium, tellurium.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Aluminum, hydrazine, phosphorus, hydrogen peroxides, lithium, acetone, arsenic, dioxygen difluoride, white phosphorus, carbon+methanol, nitrosyl chloride, ethanol, hydrogen+ air, methyl hydroperoxide, ozonides, peroxymonosulfuric acid, vanadium dichloride+water, selenium, tellurium.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 471-34-1: FF9335000 CAS# 7440-06-4: TP2160000 LD50/LC50:
CAS# 471-34-1: Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, rat: LD50 = 6450 mg/kg.
CAS# 7440-06-4.
Carcinogenicity:
Carbonic acid - Not listed by ACGIH, IARC, or NTP.
Platinum - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 471-34-1: FF9335000 CAS# 7440-06-4: TP2160000 LD50/LC50:
CAS# 471-34-1: Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, rat: LD50 = 6450 mg/kg.
CAS# 7440-06-4.
Carcinogenicity:
Carbonic acid - Not listed by ACGIH, IARC, or NTP.
Platinum - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 471-34-1: 0
CAS# 7440-06-4: 0
Canada
CAS# 471-34-1 is listed on Canadas DSL List.
CAS# 7440-06-4 is listed on Canadas DSL List.
CAS# 471-34-1 is not listed on Canadas Ingredient Disclosure List.
CAS# 7440-06-4 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 471-34-1 is listed on the TSCA inventory.
CAS# 7440-06-4 is listed on the TSCA inventory.
