Name:
Poly(propylene Glycol) Average M.W. 425
Synonym:
Poly(Oxy(Methyl-1,2-Ethanediyl)), Alpha-Hydro-Omega-Hydroxy-
CAS:
25322-69-4
Section 1 - Chemical Product
MSDS Name:Poly(propylene Glycol) Average M.W. 425
Synonym:Poly(Oxy(Methyl-1,2-Ethanediyl)), Alpha-Hydro-Omega-Hydroxy-
Synonym:Poly(Oxy(Methyl-1,2-Ethanediyl)), Alpha-Hydro-Omega-Hydroxy-
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 25322-69-4 | Poly(propylene glycol) | 100 | 233-239-6 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Low hazard for usual industrial handling.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual industrial handling.
Chronic:
No information found.
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. Low hazard for usual industrial handling.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual industrial handling.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Material will burn in a fire. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Material will burn in a fire. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. No special precautions indicated.
Wash thoroughly after handling. Wash hands before eating. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. No special precautions indicated.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 25322-69-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 25322-69-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Viscous liquid
Color: almost colorless
Odor: sweetish odor
pH: Not available.
Vapor Pressure: < .01 mm Hg @ 20C
Viscosity: 300 cSt 25 deg C
Boiling Point: Not available.
Freezing/Melting Point: -31 deg C
Autoignition Temperature: Not available.
Flash Point: 230 deg C ( 446.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: practically insoluble in water
Specific Gravity/Density: 1.0050g/cm3
Molecular Formula: Polymer Chain
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 25322-69-4: OE5784360 TR5250000 TR5300000 TR5425000 TR5600000 TR5775000 TR5785000 TR5800000 TR5950000 TR6125000 TR6129000 TR6130000 TR6200000 TR6210000 TR6215000 TR6220000 LD50/LC50:
CAS# 25322-69-4: Draize test, rabbit, eye: 500 mg Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 3750 mg/kg; Oral, rat: LD50 = >2 gm/kg; Oral, rat: LD50 = 14800 mg/kg; Oral, rat: LD50 = 5840 mg/kg; Oral, rat: LD50 = 2410 mg/kg; Oral, rat: LD50 = 5840 mg/kg; Oral, rat: LD50 = 4190 mg/kg; Oral, rat: LD50 = 2150 mg/kg; Oral, rat: LD50 = 7250 mg/kg; Oral, rat: LD50 = 10334 mg/kg; Oral, rat: LD50 = 9760 mg/kg; Oral, rat: LD50 = 35600 uL/kg; Oral, rat: LD50 = >15 gm/kg; Oral, rat: LD50 = 56600 uL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rabbit: LD50 = >10 gm/kg; Skin, rabbit: LD50 = >30 gm/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rabbit: LD50 = 20 mL/kg; Skin, rabbit: LD50 = 20 mL/kg.
Carcinogenicity:
Poly(propylene glycol) - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 25322-69-4: OE5784360 TR5250000 TR5300000 TR5425000 TR5600000 TR5775000 TR5785000 TR5800000 TR5950000 TR6125000 TR6129000 TR6130000 TR6200000 TR6210000 TR6215000 TR6220000 LD50/LC50:
CAS# 25322-69-4: Draize test, rabbit, eye: 500 mg Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 3750 mg/kg; Oral, rat: LD50 = >2 gm/kg; Oral, rat: LD50 = 14800 mg/kg; Oral, rat: LD50 = 5840 mg/kg; Oral, rat: LD50 = 2410 mg/kg; Oral, rat: LD50 = 5840 mg/kg; Oral, rat: LD50 = 4190 mg/kg; Oral, rat: LD50 = 2150 mg/kg; Oral, rat: LD50 = 7250 mg/kg; Oral, rat: LD50 = 10334 mg/kg; Oral, rat: LD50 = 9760 mg/kg; Oral, rat: LD50 = 35600 uL/kg; Oral, rat: LD50 = >15 gm/kg; Oral, rat: LD50 = 56600 uL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rabbit: LD50 = >10 gm/kg; Skin, rabbit: LD50 = >30 gm/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rabbit: LD50 = 20 mL/kg; Skin, rabbit: LD50 = 20 mL/kg.
Carcinogenicity:
Poly(propylene glycol) - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 25322-69-4: 0
Canada
CAS# 25322-69-4 is listed on Canadas DSL List.
CAS# 25322-69-4 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 25322-69-4 is listed on the TSCA inventory.
