Name:
Polyurethane foam (polymer A)
Synonym:
Non
CAS:
0-00-0
Section 1 - Chemical Product
MSDS Name:Polyurethane foam (polymer A)
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 0-00-0 | 4,4-diphenylmethanediisocyanate | N/A | 202-966-0 |
| Hazard Symbols: XN Risk Phrases: 36/37/38 42/43 20 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. Harmful by inhalation.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause allergic respiratory reaction. May cause respiratory tract irritation. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Symptoms of exposure include: increased secretions, cough, pain or respiration, Symptoms of initial exposure may include nocturnal dyspnea (labored breathing) with nocturnal cough with progression to asthmatic bronchitis.
Chronic:
Repeated exposure may cause sensitization dermatitis. Repeated exposure may cause allergic respiratory reaction (asthma).
Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. Harmful by inhalation.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause allergic respiratory reaction. May cause respiratory tract irritation. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Symptoms of exposure include: increased secretions, cough, pain or respiration, Symptoms of initial exposure may include nocturnal dyspnea (labored breathing) with nocturnal cough with progression to asthmatic bronchitis.
Chronic:
Repeated exposure may cause sensitization dermatitis. Repeated exposure may cause allergic respiratory reaction (asthma).
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use dry chemical, carbon dioxide, or alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use dry chemical, carbon dioxide, or alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use only under a chemical fume hood.
Exposure Limits CAS# 0-00-0: CAS# 101-68-8: United States OSHA: ; 0.02 ppm Ceiling; 0.2 mg/m3 Ceiling Belgium - TWA: 0.005 ppm VLE; 0.052 mg/m3 VLE France - VME: 0.01 ppm VME; 0.1 mg/m3 VME France - VLE: 0.02 ppm VLE (5 min); 0.2 mg/m3 VLE (5 min) Germany: 0.05 mg/m3 TWA Japan: 0.05 mg/m3 OEL Malaysia: 0.005 ppm TWA; 0.051 mg/m3 TWA Netherlands: 0.02 ppm STEL; 0.21 mg/m3 STEL Netherlands: 0.005 ppm MAC; 0.05 mg/m3 MAC Russia: 0.5 mg/m3 TWA Spain: 0.005 ppm VLA-ED; 0.052 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use only under a chemical fume hood.
Exposure Limits CAS# 0-00-0: CAS# 101-68-8: United States OSHA: ; 0.02 ppm Ceiling; 0.2 mg/m3 Ceiling Belgium - TWA: 0.005 ppm VLE; 0.052 mg/m3 VLE France - VME: 0.01 ppm VME; 0.1 mg/m3 VME France - VLE: 0.02 ppm VLE (5 min); 0.2 mg/m3 VLE (5 min) Germany: 0.05 mg/m3 TWA Japan: 0.05 mg/m3 OEL Malaysia: 0.005 ppm TWA; 0.051 mg/m3 TWA Netherlands: 0.02 ppm STEL; 0.21 mg/m3 STEL Netherlands: 0.005 ppm MAC; 0.05 mg/m3 MAC Russia: 0.5 mg/m3 TWA Spain: 0.005 ppm VLA-ED; 0.052 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 0-00-0 unlisted.
CAS# 101-68-8: NQ9350000 LD50/LC50:
Not available.
CAS# 101-68-8: Draize test, rabbit, eye: 100 mg Moderate; Draize test, rabbit, skin: 500 mg/24H; Inhalation, rat: LC50 = 178 mg/m3; Oral, mouse: LD50 = 2200 mg/kg; Oral, rat: LD50 = 9200 mg/kg.
Carcinogenicity:
Polymeric components - Not listed by ACGIH, IARC, or NTP.
4,4-diphenylmethanediisocyanate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 0-00-0 unlisted.
CAS# 101-68-8: NQ9350000 LD50/LC50:
Not available.
CAS# 101-68-8: Draize test, rabbit, eye: 100 mg Moderate; Draize test, rabbit, skin: 500 mg/24H; Inhalation, rat: LC50 = 178 mg/m3; Oral, mouse: LD50 = 2200 mg/kg; Oral, rat: LD50 = 9200 mg/kg.
Carcinogenicity:
Polymeric components - Not listed by ACGIH, IARC, or NTP.
4,4-diphenylmethanediisocyanate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 101-68-8: 5000 lb final RQ; 2270 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20 Harmful by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 0-00-0: No information available.
CAS# 101-68-8: 1
Canada
CAS# 101-68-8 is listed on Canadas DSL List.
CAS# 0-00-0 is not listed on Canadas Ingredient Disclosure List.
CAS# 101-68-8 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 0-00-0 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 101-68-8 is listed on the TSCA inventory.
