Name:
Rhodamine B ozone friendly ready to use spray for TLC
Synonym:
CAS:
67-63-0
Section 1 - Chemical Product
MSDS Name:Rhodamine B ozone friendly ready to use spray for TLC
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 67-63-0 | Isopropanol | 98% | 200-661-7 |
| Hazard Symbols: XN F+ Risk Phrases: 12 40 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Extremely flammable. Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation.
Chronic:
Not available.
Extremely flammable. Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Extremely flammable liquid and vapor. Containers may explode in the heat of a fire.
Extinguishing Media:
Water may be ineffective. Use water spray, dry chemical, carbon dioxide, or chemical foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Extremely flammable liquid and vapor. Containers may explode in the heat of a fire.
Extinguishing Media:
Water may be ineffective. Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 67-63-0: United Kingdom, WEL - TWA: 400 ppm TWA; 999 mg/m3 TWA United Kingdom, WEL - STEL: 500 ppm STEL; 1250 mg/m3 STEL United States OSHA: 400 ppm TWA; 980 mg/m3 TWA Belgium - TWA: 400 ppm VLE; 997 mg/m3 VLE Belgium - STEL: 500 ppm VLE; 1248 mg/m3 VLE France - VLE: 400 ppm VLE; 980 mg/m3 VLE Germany: 200 ppm TWA; 500 mg/m3 TWA Japan: 400 ppm Ceiling; 980 mg/m3 Ceiling Malaysia: 400 ppm TWA; 983 mg/m3 TWA Netherlands: 250 ppm MAC; 650 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 400 ppm VLA-ED; 998 mg/m3 VLA-ED Spain: 500 ppm VLA-EC; 1250 mg/m3 VLA-EC CAS# 74-98-6: United States OSHA: 1000 ppm TWA; 1800 mg/m3 TWA Germany: 1000 ppm TWA; 1800 mg/m3 TWA Malaysia: 2500 ppm TWA Spain: 1000 ppm VLA-ED (listed under Aliphatic hydrocarbon gases mixtures alkanes C CAS# 81-88-9: CAS# 106-97-8: United Kingdom, WEL - TWA: 600 ppm TWA; 1450 mg/m3 TWA United Kingdom, WEL - STEL: 750 ppm STEL; 1810 mg/m3 STEL Belgium - TWA: 800 ppm VLE; 1928 mg/m3 VLE France - VME: 800 ppm VME; 1900 mg/m3 VME Germany: 1000 ppm TWA; 2400 mg/m3 TWA Japan: 500 ppm OEL; 1200 mg/m3 OEL Malaysia: 800 ppm TWA; 1900 mg/m3 TWA Netherlands: 600 ppm MAC; 1430 mg/m3 MAC Russia: 300 mg/m3 TWA Spain: 1000 ppm VLA-ED (listed under Aliphatic hydrocarbon gases mixtures alkanes C Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 67-63-0: United Kingdom, WEL - TWA: 400 ppm TWA; 999 mg/m3 TWA United Kingdom, WEL - STEL: 500 ppm STEL; 1250 mg/m3 STEL United States OSHA: 400 ppm TWA; 980 mg/m3 TWA Belgium - TWA: 400 ppm VLE; 997 mg/m3 VLE Belgium - STEL: 500 ppm VLE; 1248 mg/m3 VLE France - VLE: 400 ppm VLE; 980 mg/m3 VLE Germany: 200 ppm TWA; 500 mg/m3 TWA Japan: 400 ppm Ceiling; 980 mg/m3 Ceiling Malaysia: 400 ppm TWA; 983 mg/m3 TWA Netherlands: 250 ppm MAC; 650 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 400 ppm VLA-ED; 998 mg/m3 VLA-ED Spain: 500 ppm VLA-EC; 1250 mg/m3 VLA-EC CAS# 74-98-6: United States OSHA: 1000 ppm TWA; 1800 mg/m3 TWA Germany: 1000 ppm TWA; 1800 mg/m3 TWA Malaysia: 2500 ppm TWA Spain: 1000 ppm VLA-ED (listed under Aliphatic hydrocarbon gases mixtures alkanes C CAS# 81-88-9: CAS# 106-97-8: United Kingdom, WEL - TWA: 600 ppm TWA; 1450 mg/m3 TWA United Kingdom, WEL - STEL: 750 ppm STEL; 1810 mg/m3 STEL Belgium - TWA: 800 ppm VLE; 1928 mg/m3 VLE France - VME: 800 ppm VME; 1900 mg/m3 VME Germany: 1000 ppm TWA; 2400 mg/m3 TWA Japan: 500 ppm OEL; 1200 mg/m3 OEL Malaysia: 800 ppm TWA; 1900 mg/m3 TWA Netherlands: 600 ppm MAC; 1430 mg/m3 MAC Russia: 300 mg/m3 TWA Spain: 1000 ppm VLA-ED (listed under Aliphatic hydrocarbon gases mixtures alkanes C Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Aerosol
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 67-63-0: NT8050000 CAS# 74-98-6: TX2275000 CAS# 81-88-9: BP3675000 CAS# 106-97-8: EJ4200000 LD50/LC50:
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, mouse: LC50 = 53000 mg/m3; Inhalation, rat: LC50 = 16000 ppm/8H; Inhalation, rat: LC50 = 72600 mg/m3; Oral, mouse: LD50 = 3600 mg/kg; Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Oral, rat: LD50 = 5000 mg/kg; Skin, rabbit: LD50 = 12800 mg/kg.
CAS# 74-98-6.
CAS# 81-88-9: Oral, mouse: LD50 = 887 mg/kg.
CAS# 106-97-8: Inhalation, mouse: LC50 = 680000 mg/m3/2H; Inhalation, rat: LC50 = 658000 mg/m3/4H.
Carcinogenicity:
Isopropanol - Not listed by ACGIH, IARC, or NTP.
Propane - Not listed by ACGIH, IARC, or NTP.
Rhodamine B - California: carcinogen, initial date 7/1/90 Butane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 67-63-0: NT8050000 CAS# 74-98-6: TX2275000 CAS# 81-88-9: BP3675000 CAS# 106-97-8: EJ4200000 LD50/LC50:
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, mouse: LC50 = 53000 mg/m3; Inhalation, rat: LC50 = 16000 ppm/8H; Inhalation, rat: LC50 = 72600 mg/m3; Oral, mouse: LD50 = 3600 mg/kg; Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Oral, rat: LD50 = 5000 mg/kg; Skin, rabbit: LD50 = 12800 mg/kg.
CAS# 74-98-6.
CAS# 81-88-9: Oral, mouse: LD50 = 887 mg/kg.
CAS# 106-97-8: Inhalation, mouse: LC50 = 680000 mg/m3/2H; Inhalation, rat: LC50 = 658000 mg/m3/4H.
Carcinogenicity:
Isopropanol - Not listed by ACGIH, IARC, or NTP.
Propane - Not listed by ACGIH, IARC, or NTP.
Rhodamine B - California: carcinogen, initial date 7/1/90 Butane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: AEROSOLS, 30
Hazard Class: 2.1
UN Number: 1950
Packing Group:
IMO
Shipping Name: AEROSOLS, FLAMMABLE, N.O.S.
Hazard Class: 2.1
UN Number: 1950
Packing Group:
RID/ADR
Shipping Name: AEROSOLS
Hazard Class: 2
UN Number: 1950
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F+
Risk Phrases:
R 12 Extremely flammable.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 74-98-6: 0
CAS# 81-88-9: 2
CAS# 106-97-8: 0
Canada
CAS# 67-63-0 is listed on Canadas DSL List.
CAS# 74-98-6 is listed on Canadas DSL List.
CAS# 81-88-9 is listed on Canadas DSL List.
CAS# 106-97-8 is listed on Canadas DSL List.
CAS# 67-63-0 is listed on Canadas Ingredient Disclosure List.
CAS# 74-98-6 is not listed on Canadas Ingredient Disclosure List.
CAS# 81-88-9 is listed on Canadas Ingredient Disclosure List.
CAS# 106-97-8 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 74-98-6 is listed on the TSCA inventory.
CAS# 81-88-9 is listed on the TSCA inventory.
CAS# 106-97-8 is listed on the TSCA inventory.
