Name:
SafeFix II
Synonym:
Mixtur
CAS:
64-17-5
Section 1 - Chemical Product
MSDS Name:SafeFix II
Synonym:Mixtur
Synonym:Mixtur
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-17-5 | Ethanol | 17.0 | 200-578-6 |
| Hazard Symbols: XN Risk Phrases: 10 36/38 43 20 68 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Irritating to eyes and skin. May cause sensitization by skin contact. Harmful by inhalation.Possible risk of irreversible effects.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Vapors may cause eye irritation. May cause painful sensitization to light.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
May be absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause systemic toxicity with acidosis. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
May cause respiratory tract irritation. May cause liver and kidney damage. May cause effects similar to those described for ingestion.
May cause narcotic effects in high concentration. May cause drowsiness, unconsciousness, and central nervous system depression.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.
Flammable. Irritating to eyes and skin. May cause sensitization by skin contact. Harmful by inhalation.Possible risk of irreversible effects.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Vapors may cause eye irritation. May cause painful sensitization to light.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
May be absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May cause systemic toxicity with acidosis. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
May cause respiratory tract irritation. May cause liver and kidney damage. May cause effects similar to those described for ingestion.
May cause narcotic effects in high concentration. May cause drowsiness, unconsciousness, and central nervous system depression.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and water.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Flush skin with plenty of soap and water.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint.
Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be ineffective. Use water fog, dry chemical, carbon dioxide, or regular foam. Do NOT use straight streams of water.
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint.
Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be ineffective. Use water fog, dry chemical, carbon dioxide, or regular foam. Do NOT use straight streams of water.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 64-17-5: United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE France - VME: 1000 ppm VME; 1900 mg/m3 VME France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 960 mg/m3 TWA Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA Netherlands: 500 ppm MAC; 1000 mg/m3 MAC Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED CAS# 67-56-1: United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL United States OSHA: 200 ppm TWA; 260 mg/m3 TWA Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE France - VME: 200 ppm VME; 260 mg/m3 VME France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE Germany: 200 ppm TWA; 270 mg/m3 TWA Germany: Skin absorber Japan: 200 ppm OEL; 260 mg/m3 OEL Malaysia: 200 ppm TWA; 262 mg/m3 TWA Netherlands: 200 ppm MAC; 260 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC CAS# 107-22-2: CAS# 877-24-7: CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 64-17-5: United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE France - VME: 1000 ppm VME; 1900 mg/m3 VME France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 960 mg/m3 TWA Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA Netherlands: 500 ppm MAC; 1000 mg/m3 MAC Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED CAS# 67-56-1: United Kingdom, WEL - TWA: 200 ppm TWA; 266 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 333 mg/m3 STEL United States OSHA: 200 ppm TWA; 260 mg/m3 TWA Belgium - TWA: 200 ppm VLE; 266 mg/m3 VLE Belgium - STEL: 250 ppm VLE; 333 mg/m3 VLE France - VME: 200 ppm VME; 260 mg/m3 VME France - VLE: 1000 ppm VLE; 1300 mg/m3 VLE Germany: 200 ppm TWA; 270 mg/m3 TWA Germany: Skin absorber Japan: 200 ppm OEL; 260 mg/m3 OEL Malaysia: 200 ppm TWA; 262 mg/m3 TWA Netherlands: 200 ppm MAC; 260 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 200 ppm VLA-ED; 266 mg/m3 VLA-ED Spain: 250 ppm VLA-EC; 333 mg/m3 VLA-EC CAS# 107-22-2: CAS# 877-24-7: CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear, colorless
Odor: Alcoholic odor
pH: 4.0 - 4.3
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 99 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 113 deg F ( 45.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: <1
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of carbon.
Hazardous Polymerization: Has not been reported
Stable.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of carbon.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 107-22-2: MD2625000 MD2650000 MD2700000 CAS# 877-24-7: CZ4326000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 107-22-2: Dermal, guinea pig: LD50 = 6600 mg/kg; Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 100 uL/24H Moderate; Draize test, rabbit, eye: 100 uL Mild; Draize test, rabbit, skin: 500 uL/4H Mild; Draize test, rabbit, skin: 10 mg/24H; Inhalation, rat: LC50 = 2410 mg/m3/4H; Oral, mouse: LD50 = 400 mg/kg; Oral, mouse: LD50 = 1280 mg/kg; Oral, rabbit: LD50 = >3175 mg/kg; Oral, rat: LD50 = 200 mg/kg; Oral, rat: LD50 = 200 mg/kg; Oral, rat: LD50 = 4290 mg/kg; Oral, rat: LD50 = 2960 mg/kg; Skin, rabbit: LD50 = 10 mL/kg; Skin, rabbit: LD50 = 10 mL/kg; Skin, rabbit: LD50 = 10 mL/kg; Skin, rat: LD50 = >2 gm/kg.
CAS# 877-24-7: Dermal, guinea pig: LD50 = >1 gm/kg; Oral, rat: LD50 = >3200 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Ethanol - Not listed by ACGIH, IARC, or NTP.
Methanol - Not listed by ACGIH, IARC, or NTP.
Glyoxal - Not listed by ACGIH, IARC, or NTP.
Potassium hydrogen phthalate - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 107-22-2: MD2625000 MD2650000 MD2700000 CAS# 877-24-7: CZ4326000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg.
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, rabbit: LC50 = 81000 mg/m3/14H; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 107-22-2: Dermal, guinea pig: LD50 = 6600 mg/kg; Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 100 uL/24H Moderate; Draize test, rabbit, eye: 100 uL Mild; Draize test, rabbit, skin: 500 uL/4H Mild; Draize test, rabbit, skin: 10 mg/24H; Inhalation, rat: LC50 = 2410 mg/m3/4H; Oral, mouse: LD50 = 400 mg/kg; Oral, mouse: LD50 = 1280 mg/kg; Oral, rabbit: LD50 = >3175 mg/kg; Oral, rat: LD50 = 200 mg/kg; Oral, rat: LD50 = 200 mg/kg; Oral, rat: LD50 = 4290 mg/kg; Oral, rat: LD50 = 2960 mg/kg; Skin, rabbit: LD50 = 10 mL/kg; Skin, rabbit: LD50 = 10 mL/kg; Skin, rabbit: LD50 = 10 mL/kg; Skin, rat: LD50 = >2 gm/kg.
CAS# 877-24-7: Dermal, guinea pig: LD50 = >1 gm/kg; Oral, rat: LD50 = >3200 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Ethanol - Not listed by ACGIH, IARC, or NTP.
Methanol - Not listed by ACGIH, IARC, or NTP.
Glyoxal - Not listed by ACGIH, IARC, or NTP.
Potassium hydrogen phthalate - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 67-56-1: 5000 lb final RQ; 2270 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
R 68 Possible risk of irreversible effects.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 107-22-2: 1
CAS# 877-24-7: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 64-17-5 is listed on Canadas DSL List.
CAS# 67-56-1 is listed on Canadas DSL List.
CAS# 107-22-2 is listed on Canadas DSL List.
CAS# 877-24-7 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 64-17-5 is listed on Canadas Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canadas Ingredient Disclosure List.
CAS# 107-22-2 is listed on Canadas Ingredient Disclosure List.
CAS# 877-24-7 is not listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 107-22-2 is listed on the TSCA inventory.
CAS# 877-24-7 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
