Name:
Seven Alcohol Blend
Section 1 - Chemical Product
MSDS Name:Seven Alcohol Blend
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 67-63-0 | Isopropyl alcohol | 17.3 | 200-661-7 |
Hazard Symbols: XN Risk Phrases: 10 21/22 36 37 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin and if swallowed. Irritating to eyes. Irritating to respiratory system.Flammable liquid.
Potential Health Effects
Eye:
May result in corneal injury. Vapors may cause eye irritation.
May cause conjunctivitis. May cause eye irritation and possible burns.
Skin:
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. Causes symptoms similar to those of inhalation. May be harmful if absorbed through the skin. Excessive drying of the skin may result from repeated or prolonged contact. May cause skin irritation and possible burns.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause effects similar to those for inhalation exposure.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. Aspiration may cause respiratory swelling and pneumonitis. May cause kidney damage. May cause drowsiness, unconsciousness, and central nervous system depression.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. Prolonged or repeated skin contact may cause defatting and dermatitis. May cause allergic skin reaction in some individuals.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Urine acetone test may be helpful in diagnosis. Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Combustion generates toxic fumes. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May form explosive peroxides. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as saw dust. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Personal Protective Equipment Eyes: Wear safety glasses and chemical goggles if splashing is possible. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 84 deg F ( 28.89 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. This material may be sensitive to peroxide formation.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g.
dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g.
methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, sodium), nitrides (e.g. potassium nitride, sodium nitride), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents (strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide, potassium nitrate), reducing agents (strong, e.g. aluminum carbide, chlorosilane, hydrogen phosphide, lithium hydride), water reactive substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium carbide, ethyl dichlorosilane).
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Not available.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 67-63-0: NT8050000 CAS# 71-23-8: UH8225000 CAS# 71-41-0: SB9800000 CAS# 104-76-7: MP0350000 CAS# 108-11-2: SA7350000 CAS# 111-27-3: MQ4025000 CAS# 111-70-6: MK0350000 LD50/LC50:
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, rat: LC50 = 16000 ppm/8H; Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit: LD50 = 12800 mg/kg.
CAS# 71-23-8: Draize test, rabbit, eye: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 48 gm/m3; Oral, mouse: LD50 = 6800 mg/kg; Oral, rabbit: LD50 = 2825 mg/kg; Oral, rat: LD50 = 1870 mg/kg; Skin, rabbit: LD50 = 5040 mg/kg.
CAS# 71-41-0: Draize test, rabbit, eye: 81 mg Severe; Draize test, rabbit, eye: 5 uL/24H Severe; Draize test, rabbit, skin: 3200 mg/kg/24H Severe; Draize test, rabbit, skin: 20 mg/24H Moderate; Oral, mouse: LD50 = 200 mg/kg; Oral, rat: LD50 = 5660 uL/kg; Skin, rabbit: LD50 = 2830 uL/kg.
CAS# 104-76-7: Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, mouse: LD50 = 2500 mg/kg; Oral, rabbit: LD50 = 1180 mg/kg; Oral, rat: LD50 = 3730 mg/kg; Skin, rabbit: LD50 = 1970 mg/kg; Skin, rat: LD50 = >3 gm/kg.
CAS# 108-11-2: Oral, rat: LD50 = 2590 mg/kg; Skin, rabbit: LD50 = 3560 uL/kg.
CAS# 111-27-3: Oral, mouse: LD50 = 1950 mg/kg; Oral, rat: LD50 = 720 mg/kg; Skin, rabbit: LD50 = 3100 uL/kg.
CAS# 111-70-6: Inhalation, mouse: LC50 = 6600 mg/m3/2H; Oral, mouse: LD50 = 1500 mg/kg; Oral, rabbit: LD50 = 750 mg/kg; Oral, rat: LD50 = 500 mg/kg; Skin, rabbit: LD50 = 2 gm/kg.
Carcinogenicity:
Isopropyl alcohol - IARC: Group 3 carcinogen N-propyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Amyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
2-ethylhexanol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl isobutyl carbinol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
N-hexanol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
N-heptyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 21/22 Harmful in contact with skin and if
swallowed.
R 36 Irritating to eyes.
R 37 Irritating to respiratory system.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 71-23-8: 1
CAS# 71-41-0: 1
CAS# 104-76-7: 2
CAS# 108-11-2: 1
CAS# 111-27-3: 1
CAS# 111-70-6: 1
United Kingdom Occupational Exposure Limits
CAS# 67-63-0: OES-United Kingdom, TWA 400 ppm TWA; 999 mg/m3 TWA
CAS# 67-63-0: OES-United Kingdom, STEL 500 ppm STEL; 1250 mg/m3 STEL
CAS# 71-23-8: OES-United Kingdom, TWA 200 ppm TWA; 500 mg/m3 TWA
CAS# 71-23-8: OES-United Kingdom, STEL 250 ppm STEL; 625 mg/m3 STEL
CAS# 71-23-8: OES-United Kingdom, STEL 250 ppm STEL; 625 mg/m3 STEL
CAS# 108-11-2: OES-United Kingdom, TWA 25 ppm TWA; 106 mg/m3 TWA
CAS# 108-11-2: OES-United Kingdom, STEL 40 ppm STEL; 170 mg/m3 STEL
CAS# 108-11-2: OES-United Kingdom, STEL 40 ppm STEL; 170 mg/m3 STEL
Canada
CAS# 67-63-0 is listed on Canadas DSL List.
CAS# 71-23-8 is listed on Canadas DSL List.
CAS# 71-41-0 is listed on Canadas DSL List.
CAS# 104-76-7 is listed on Canadas DSL List.
CAS# 108-11-2 is listed on Canadas DSL List.
CAS# 111-27-3 is listed on Canadas DSL List.
CAS# 111-70-6 is listed on Canadas DSL List.
CAS# 67-63-0 is listed on Canadas Ingredient Disclosure List.
CAS# 71-23-8 is listed on Canadas Ingredient Disclosure List.
CAS# 71-41-0 is listed on Canadas Ingredient Disclosure List.
CAS# 104-76-7 is listed on Canadas Ingredient Disclosure List.
CAS# 108-11-2 is listed on Canadas Ingredient Disclosure List.
CAS# 111-27-3 is listed on Canadas Ingredient Disclosure List.
CAS# 111-70-6 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 67-63-0: OEL-AUSTRALIA:TWA 400 ppm (980 mg/m3);STEL 500 ppm (1225
mg/m3)
OEL-BELGIUM:TWA 400 ppm (985 mg/m3);STEL 500 ppm (1230 mg/m3)
OEL-DENMARK:TWA 200 ppm (490 mg/m3);Skin
OEL-FRANCE:STEL 400 ppm (980 mg/m3)
OEL-GERMANY:TWA 400 ppm (980 mg/m3)
OEL-JAPAN:STEL 400 ppm (980 mg/m3)
OEL-THE NETHERLANDS:TWA 400 ppm (980 mg/m3);Skin
OEL-THE PHILIPPINES:TWA 400 ppm (980 mg/m3)
OEL-RUSSIA:STEL 400 ppm (10 mg/m3)
OEL-SWEDEN:TWA 150 ppm (350 mg/m3);STEL 250 ppm (600 mg/m3)
OEL-SWITZERLAND:TWA 400 ppm (980 mg/m3);STEL 800 ppm
OEL-TURKEY:TWA 200 ppm (500 mg/m3)
OEL-UNITED KINGDOM:TWA 400 ppm (980 mg/m3);STEL 500 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 71-23-8: OEL-AUSTRALIA:TWA 200 ppm (500 mg/m3);STEL 250 ppm;Skin
CAS# 71-41-0: OEL-AUSTRALIA:TWA 100 ppm (530 mg/m3)
OEL-AUSTRIA:TWA 100 ppm (525 mg/m3) (all isomers)
OEL-BELGIUM:TWA 100 ppm (532 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 100 mg/m3;STEL 200 mg/m3
OEL-CZECHOSLOVAKIA:TWA 200 mg/m3;STEL 800 mg/m3
OEL-DENMARK:TWA 100 ppm (360 mg/m3)
OEL-DENMARK:TWA 100 ppm (525 mg/m3)
OEL-FINLAND:TWA 100 ppm (360 mg/m3);STEL 150 ppm (540 mg/m3)
OEL-FINLAND:TWA 100 ppm (525 mg/m3);STEL 150 ppm (790 mg/m3)
OEL-FRANCE:TWA 100 ppm (530 mg/m3);STEL 150 ppm (800 mg/m3)
OEL-GERMANY:TWA 100 ppm (525 mg/m3)
OEL-GERMANY:TWA 100 ppm (525 mg/m3) (all isomers)
OEL-HUNGARY:TWA 400 mg/m3;STEL 800 mg/m3
OEL-JAPAN:TWA 100 ppm (530 mg/m3)
OEL-THE NETHERLANDS:TWA 100 ppm (530 mg/m3)
OEL-THE PHILIPPINES:TWA 100 ppm (525 mg/m3)
OEL-POLAND:TWA 100 mg/m3
OEL-POLAND:TWA 100 mg/m3;STEL 450 mg/m3
OEL-RUSSIA:STEL 10 mg/m3
OEL-RUSSIA:TWA 100 ppm;STEL 100 mg/m3
OEL-SWEDEN:TWA 100 ppm (500 mg/m3);STEL 150 ppm (all isomers)
OEL-SWITZERLAND:TWA 100 ppm (540 mg/m3)
OEL-SWITZERLAND:TWA 100 ppm (540 mg/m3) (all isomers)
OEL-TURKEY:TWA 100 ppm (525 mg/m3)
OEL-UNITED KINGDOM:TWA 100 ppm (530 mg/m3);STEL 150 ppm
CAS# 108-11-2: OEL-AUSTRALIA:TWA 25 ppm (100 mg/m3);STEL 40 ppm;Skin
OEL-BELGIUM:TWA 25 ppm (104 mg/m3);STEL 40 ppm (166 mg/m3);Skin
OEL-DENMARK:TWA 25 ppm (100 mg/m3);Skin
OEL-FINLAND:TWA 25 ppm (100 mg/m3);STEL 40 ppm (170 mg/m3);Skin
OEL-FRANCE:TWA 25 ppm (100 mg/m3);Skin
OEL-GERMANY:TWA 25 ppm (100 mg/m3);Skin
OEL-RUSSIA:STEL 10 mg/m3;Skin
OEL-SWITZERLAND:TWA 25 ppm (100 mg/m3);STEL 125 ppm;Skin
OEL-UNITED KINGDOM:TWA 25 ppm (100 mg/m3);STEL 40 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 111-70-6: OEL-RUSSIA:STEL 10 mg/m3;Skin
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 71-23-8 is listed on the TSCA inventory.
CAS# 71-41-0 is listed on the TSCA inventory.
CAS# 104-76-7 is listed on the TSCA inventory.
CAS# 108-11-2 is listed on the TSCA inventory.
CAS# 111-27-3 is listed on the TSCA inventory.
CAS# 111-70-6 is listed on the TSCA inventory.