Name:
Silver(I) Fluoride 99+%
Synonym:
None
CAS:
7775-41-9
Section 1 - Chemical Product
MSDS Name:Silver(I) Fluoride 99+%
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7775-41-9 | Silver(I) Fluoride | >99 | 231-895-8 |
| Hazard Symbols: C Risk Phrases: 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Hygroscopic (absorbs moisture from the air).Light sensitive.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
No information found.
Causes burns.Hygroscopic (absorbs moisture from the air).Light sensitive.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Do NOT get water inside containers.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Do NOT get water inside containers.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Provide ventilation. Do not get water inside containers.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Provide ventilation. Do not get water inside containers.
Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Store protected from light. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Corrosives area. Store protected from moisture. Store protected from light.
Minimize dust generation and accumulation. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Store protected from light. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Corrosives area. Store protected from moisture. Store protected from light.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7775-41-9: United Kingdom, WEL - TWA: (listed as silver soluble compounds): mg/m3 TWA (as Ag) United Kingdom, WEL - STEL: (listed as silver soluble compounds): 0.03 mg/m3 STEL (as Ag) United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).0.01 mg TWA (listed under Silver soluble compounds).
Belgium - TWA: (listed as silver soluble compounds): 0.01 mg/m3 V (as Ag) France - VME: (listed as silver soluble compounds): 0.01 mg/m3 VM (as Ag) Germany: (listed as silver soluble compounds): 0.01 mg/m3 VME (as Japan: (listed as silver compounds): 0.01 mg/m3 OEL (as Ag) Malaysia: (listed as silver soluble compounds): 0.01 mg/m3 TWA (a Ag) Netherlands: (listed as fluorides): 3.5 mg/m3 STEL (as F) Netherlands: (listed as silver soluble compounds): 0.01 mg/m3 MAC Ag) Spain: (listed as silver soluble compounds): 0.01 mg/m3 VLA-ED (a Ag) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7775-41-9: United Kingdom, WEL - TWA: (listed as silver soluble compounds): mg/m3 TWA (as Ag) United Kingdom, WEL - STEL: (listed as silver soluble compounds): 0.03 mg/m3 STEL (as Ag) United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).0.01 mg TWA (listed under Silver soluble compounds).
Belgium - TWA: (listed as silver soluble compounds): 0.01 mg/m3 V (as Ag) France - VME: (listed as silver soluble compounds): 0.01 mg/m3 VM (as Ag) Germany: (listed as silver soluble compounds): 0.01 mg/m3 VME (as Japan: (listed as silver compounds): 0.01 mg/m3 OEL (as Ag) Malaysia: (listed as silver soluble compounds): 0.01 mg/m3 TWA (a Ag) Netherlands: (listed as fluorides): 3.5 mg/m3 STEL (as F) Netherlands: (listed as silver soluble compounds): 0.01 mg/m3 MAC Ag) Spain: (listed as silver soluble compounds): 0.01 mg/m3 VLA-ED (a Ag) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Chunks
Color: rust
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 1150 deg C @ 760.00mm Hg
Freezing/Melting Point: 435 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: IN WATER: 182 G/100ML (15.5C)
Specific Gravity/Density: 5.8520g/cm3
Molecular Formula: AgF
Molecular Weight: 126.87
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light, dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, strong acids, strong bases, strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light, dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, strong acids, strong bases, strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7775-41-9: VW4250000 LD50/LC50:
Not available.
Carcinogenicity:
Silver(I) Fluoride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7775-41-9: VW4250000 LD50/LC50:
Not available.
Carcinogenicity:
Silver(I) Fluoride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7775-41-9: No information available.
Canada
CAS# 7775-41-9 is listed on Canadas NDSL List.
CAS# 7775-41-9 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7775-41-9 is listed on the TSCA inventory.
