MSDS Name:Sodium hydrogen selenite p.a.
Synonym:Sodium hydroselenite: sodium biselenit

EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed. Danger of cumulative effects.The toxicological properties of this material have not been fully investigated.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Effects of inhalation may be delayed.
Chronic:
Chronic exposure to selenium may cause central nervous system effects, digestive tract disturbances, pallor, garlic breath,

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen.
Notes to Physician:

General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use water spray, fog or regular foam.

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.

Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Wash clothing before reuse. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7782-82-3: United Kingdom, WEL - TWA: (listed as selenium compounds): 0.1 mg TWA (except hydrogen selenide, as Se) United Kingdom, WEL - STEL: (listed as selenium compounds): 0.3 m STEL (except hydrogen selenide, as Se) United States OSHA: 0.2 mg/m3 TWA (as Se) (listed under Selenium compounds).
Belgium - TWA: (listed as selenium compounds): 0.2 mg/m3 VLE (as Japan: (listed as selenium compounds): 0.1 mg/m3 OEL (except SeH2 SeF6, as Se) Malaysia: (listed as selenium compounds): 0.2 mg/m3 TWA (as Se) Netherlands: (listed as selenium compounds): 0.1 mg/m3 MAC (as Se Spain: (listed as selenium compounds): 0.1 mg/m3 VLA-ED (except hydrogen selenide, as Se) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Physical State: Solid
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density:
Molecular Formula: HNaO3Se
Molecular Weight: 150.96

Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong acids.
Hazardous Decomposition Products:
Selenium/selenium oxides.
Hazardous Polymerization: Will not occur.

RTECS#:
CAS# 7782-82-3: VS7500000 LD50/LC50:
CAS# 7782-82-3: Oral, rabbit: LD50 = 8.6 mg/kg; Oral, rat: LD50 = 2.5 mg/kg.
Carcinogenicity:
SODIUM HYDROGEN SELENITE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Dispose of in a manner consistent with federal, state, and local regulations.

IATA
Shipping Name: SELENITES
Hazard Class: 6.1
UN Number: 2630
Packing Group: I
IMO
Shipping Name: SELENITES
Hazard Class: 6.1
UN Number: 2630
Packing Group: I
RID/ADR
Shipping Name: SELENITES
Hazard Class: 6.1
UN Number: 2630
Packing group: I
USA RQ: CAS# 7782-82-3: 100 lb final RQ; 45.4 kg final RQ

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7782-82-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7782-82-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7782-82-3 is not listed on the TSCA inventory.
It is for research and development use only.