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Name:
Sodium iodate
Synonym:
Iodic acid, sodium salt
CAS:
7681-55-2
Section 1 - Chemical Product
MSDS Name:Sodium iodate
Synonym:Iodic acid, sodium salt
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
7681-55-2 Sodium iodate >99 231-672-5
Hazard Symbols: O
Risk Phrases: 42/43 8

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
May cause sensitization by inhalation and skin contact. Contact with combustible material may cause fire.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns. May cause eye injury.
Skin:
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Exposure may cause irritation and possible burns.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause allergic respiratory reaction. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in sensitive individuals.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. Strong oxidizer.
Contact with other material may cause fire. Use water with caution and in flooding amounts. Oxidizer. Greatly increases the burning rate of combustible materials. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water only! Contact professional fire-fighters immediately.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Do not use combustible materials such as paper towels to clean up spill.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7681-55-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: white
Odor: odorless
pH: Neutral in sol.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point: Decomposes
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 4.28
Molecular Formula: INaO3
Molecular Weight: 197.89

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable. However, may decompose if heated.
Conditions to Avoid:
High temperatures, dust generation.
Incompatibilities with Other Materials:
Strong reducing agents, combustible materials, flammable liquids.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen iodide, sodium oxide, iodine.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7681-55-2: NN1400000 LD50/LC50:
CAS# 7681-55-2: Oral, mouse: LD50 = 505 mg/kg.
Carcinogenicity:
Sodium iodate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: OXIDIZING SOLID, N.O.S.*
Hazard Class: 5.1
UN Number: 1479
Packing Group: II
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: II
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing group: II

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 42/43 May cause sensitization by inhalation and
skin contact.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7681-55-2: 1
Canada
CAS# 7681-55-2 is listed on Canadas DSL List.
CAS# 7681-55-2 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7681-55-2 is listed on the TSCA inventory.