Name:
Sodium Phenate Solution
Synonym:
None Known
CAS:
108-95-2
Section 1 - Chemical Product
MSDS Name:Sodium Phenate Solution
Synonym:None Known
Synonym:None Known
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 108-95-2 | Phenol | 8.3 | 203-632-7 |
| Hazard Symbols: T Risk Phrases: 34 24/25 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns. Toxic in contact with skin and if swallowed.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. Toxic in contact with skin. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Poison by ingestion. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Causes severe pain, nausea, vomiting, diarrhea, and shock. May cause systemic effects.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause liver and kidney damage. May cause cancer according to animal studies. Effects may be delayed. Laboratory experiments have resulted in mutagenic effects.
Causes burns. Toxic in contact with skin and if swallowed.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. Toxic in contact with skin. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Poison by ingestion. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Causes severe pain, nausea, vomiting, diarrhea, and shock. May cause systemic effects.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause liver and kidney damage. May cause cancer according to animal studies. Effects may be delayed. Laboratory experiments have resulted in mutagenic effects.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use water with caution and in flooding amounts. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use water with caution and in flooding amounts. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Keep away from metals. Keep away from flammable liquids. Keep away from organic halogens.
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Keep away from metals. Keep away from flammable liquids. Keep away from organic halogens.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 108-95-2: United Kingdom, WEL - TWA: 2 ppm TWA United Kingdom, WEL - STEL: 6 ppm STEL United States OSHA: 5 ppm TWA; 19 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 7.8 mg/m3 VLE France - VME: 5 ppm VME; 19 mg/m3 VME Germany: 5 ppm TWA; 19 mg/m3 TWA Germany: Skin absorber Japan: 5 ppm OEL; 19 mg/m3 OEL Malaysia: 5 ppm TWA; 15 mg/m3 TWA Netherlands: 2 ppm MAC; 8 mg/m3 MAC Russia: 0.3 mg/m3 TWA Spain: 2 ppm VLA-ED; 8 mg/m3 VLA-ED CAS# 1310-73-2: United Kingdom, WEL - STEL: 2 mg/m3 STEL United States OSHA: 2 mg/m3 TWA Belgium - TWA: 2 mg/m3 VLE France - VME: 2 mg/m3 VME Germany: 2 mg/m3 TWA (inhalable fraction) Japan: 2 mg/m3 Ceiling Malaysia: 2 mg/m3 Ceiling Spain: 2 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 108-95-2: United Kingdom, WEL - TWA: 2 ppm TWA United Kingdom, WEL - STEL: 6 ppm STEL United States OSHA: 5 ppm TWA; 19 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 7.8 mg/m3 VLE France - VME: 5 ppm VME; 19 mg/m3 VME Germany: 5 ppm TWA; 19 mg/m3 TWA Germany: Skin absorber Japan: 5 ppm OEL; 19 mg/m3 OEL Malaysia: 5 ppm TWA; 15 mg/m3 TWA Netherlands: 2 ppm MAC; 8 mg/m3 MAC Russia: 0.3 mg/m3 TWA Spain: 2 ppm VLA-ED; 8 mg/m3 VLA-ED CAS# 1310-73-2: United Kingdom, WEL - STEL: 2 mg/m3 STEL United States OSHA: 2 mg/m3 TWA Belgium - TWA: 2 mg/m3 VLE France - VME: 2 mg/m3 VME Germany: 2 mg/m3 TWA (inhalable fraction) Japan: 2 mg/m3 Ceiling Malaysia: 2 mg/m3 Ceiling Spain: 2 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear, colorless
Odor: odorless
pH: Alkaline
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, acids, metals, Contact with metals such as aluminum, tin and zinc causes corrosion and the formation of flammable hydrogen gas., nitromethane, nitro compounds, Attacks some plastics, rubber and coatings., aliphatic amines, amides (e.g.
butyramide, diethyltoluamide, dimethyl formamide), butadiene, calcium hypochlorite, formaldehyde.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, toxic fumes of sodium oxide, sodium peroxide fumes.
Hazardous Polymerization: Has not been reported
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, acids, metals, Contact with metals such as aluminum, tin and zinc causes corrosion and the formation of flammable hydrogen gas., nitromethane, nitro compounds, Attacks some plastics, rubber and coatings., aliphatic amines, amides (e.g.
butyramide, diethyltoluamide, dimethyl formamide), butadiene, calcium hypochlorite, formaldehyde.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, toxic fumes of sodium oxide, sodium peroxide fumes.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 108-95-2: SJ3325000 CAS# 1310-73-2: WB4900000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 108-95-2: Draize test, rabbit, eye: 5 mg Severe; Draize test, rabbit, skin: 500 mg/24H Severe; Draize test, rabbit, skin: 100 mg Mild; Inhalation, mouse: LC50 = 177 mg/m3; Inhalation, mouse: LC50 = 177 mg/m3/4H; Inhalation, rat: LC50 = 316 mg/m3; Inhalation, rat: LC50 = 316 mg/m3/4H; Oral, mouse: LD50 = 270 mg/kg; Oral, rat: LD50 = 317 mg/kg; Oral, rat: LD50 = 512 mg/kg; Skin, rabbit: LD50 = 630 mg/kg; Skin, rat: LD50 = 669 mg/kg; Skin, rat: LD50 = 1500 mg/kg.
CAS# 1310-73-2: Draize test, rabbit, eye: 400 ug Mild; Draize test, rabbit, eye: 1% Severe; Draize test, rabbit, eye: 50 ug/24H Severe; Draize test, rabbit, eye: 1 mg/24H Severe; Draize test, rabbit, skin: 500 mg/24H Severe.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Phenol - Not listed by ACGIH, IARC, or NTP.
Sodium hydroxide - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 108-95-2: SJ3325000 CAS# 1310-73-2: WB4900000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 108-95-2: Draize test, rabbit, eye: 5 mg Severe; Draize test, rabbit, skin: 500 mg/24H Severe; Draize test, rabbit, skin: 100 mg Mild; Inhalation, mouse: LC50 = 177 mg/m3; Inhalation, mouse: LC50 = 177 mg/m3/4H; Inhalation, rat: LC50 = 316 mg/m3; Inhalation, rat: LC50 = 316 mg/m3/4H; Oral, mouse: LD50 = 270 mg/kg; Oral, rat: LD50 = 317 mg/kg; Oral, rat: LD50 = 512 mg/kg; Skin, rabbit: LD50 = 630 mg/kg; Skin, rat: LD50 = 669 mg/kg; Skin, rat: LD50 = 1500 mg/kg.
CAS# 1310-73-2: Draize test, rabbit, eye: 400 ug Mild; Draize test, rabbit, eye: 1% Severe; Draize test, rabbit, eye: 50 ug/24H Severe; Draize test, rabbit, eye: 1 mg/24H Severe; Draize test, rabbit, skin: 500 mg/24H Severe.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Phenol - Not listed by ACGIH, IARC, or NTP.
Sodium hydroxide - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Carp: 180ppm (LC100); 24HFish: Pseudomonas putida:
Fish: Carp: 180ppm (LC100); 24HFish: Pseudomonas putida:
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 108-95-2: 1000 lb final RQ; 454 kg final RQ
USA RQ: CAS# 1310-73-2: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 24/25 Toxic in contact with skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 108-95-2: 2
CAS# 1310-73-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 108-95-2 is listed on Canadas DSL List.
CAS# 1310-73-2 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 108-95-2 is listed on Canadas Ingredient Disclosure List.
CAS# 1310-73-2 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-95-2 is listed on the TSCA inventory.
CAS# 1310-73-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
