Name:
Sodium Silicate Solution
Synonym:
Non
CAS:
1313-59-3
Section 1 - Chemical Product
MSDS Name:Sodium Silicate Solution
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1313-59-3 | Sodium oxide | 9.1 | 215-208-9 |
| Hazard Symbols: C Risk Phrases: 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Causes severe pain, nausea, vomiting, diarrhea, and shock.
May cause systemic effects.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes chemical burns to the respiratory tract. May cause systemic effects.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Causes severe pain, nausea, vomiting, diarrhea, and shock.
May cause systemic effects.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema.
Causes chemical burns to the respiratory tract. May cause systemic effects.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Wash thoroughly after handling. Use with adequate ventilation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 1313-59-3: CAS# 7631-86-9: United Kingdom, WEL - TWA: 6 mg/m3 TWA (inhalable dust); 2.4 mg/m TWA (respirable dust) United Kingdom, WEL - STEL: 18 mg/m3 STEL (inhalable dust); 7.2 m STEL (respirable dust) Germany: 4 mg/m3 TWA (inhalable fraction) Russia: 1 mg/m3 TWA CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 1313-59-3: CAS# 7631-86-9: United Kingdom, WEL - TWA: 6 mg/m3 TWA (inhalable dust); 2.4 mg/m TWA (respirable dust) United Kingdom, WEL - STEL: 18 mg/m3 STEL (inhalable dust); 7.2 m STEL (respirable dust) Germany: 4 mg/m3 TWA (inhalable fraction) Russia: 1 mg/m3 TWA CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: not available
Odor: none reported
pH: 11.2
Vapor Pressure: 14 mm Hg
Viscosity: Not available.
Boiling Point: 213 deg F
Freezing/Melting Point: 31 deg F
Autoignition Temperature: Not applicable.
Flash Point: Non-flammable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.4
Molecular Formula: Mixture
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. Sodium oxide reacts on contact with water forming Sodium Hydroxide.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Acids, Corrosive to metals such as aluminum, tin, and zinc. These reactions may cause the formation of hydrogen gas., Sodium oxide is reactive with water..
Hazardous Decomposition Products:
Sodium hydroxide..
Hazardous Polymerization: Has not been reported.
Stable at room temperature in closed containers under normal storage and handling conditions. Sodium oxide reacts on contact with water forming Sodium Hydroxide.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Acids, Corrosive to metals such as aluminum, tin, and zinc. These reactions may cause the formation of hydrogen gas., Sodium oxide is reactive with water..
Hazardous Decomposition Products:
Sodium hydroxide..
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1313-59-3 unlisted.
CAS# 7631-86-9: EU8655000 VV7565000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
Not available.
CAS# 7631-86-9: Draize test, rabbit, eye: 25 mg/24H Mild.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Sodium oxide - Not listed by ACGIH, IARC, or NTP.
Silica, amorphous - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 1313-59-3 unlisted.
CAS# 7631-86-9: EU8655000 VV7565000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
Not available.
CAS# 7631-86-9: Draize test, rabbit, eye: 25 mg/24H Mild.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Sodium oxide - Not listed by ACGIH, IARC, or NTP.
Silica, amorphous - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Pseudomonas putida:
Fish: Pseudomonas putida:
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE LIQUID, NOS(Sodium silicate solution)
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, NOS(Sodium silicate solution)
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, NOS(Sodium silicate solution)
Hazard Class: 8
UN Number: 1760
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1313-59-3: 1
CAS# 7631-86-9: 0
CAS# 7732-18-5: No information available.
Canada
CAS# 1313-59-3 is listed on Canadas DSL List.
CAS# 7631-86-9 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 1313-59-3 is not listed on Canadas Ingredient Disclosure List.
CAS# 7631-86-9 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1313-59-3 is listed on the TSCA inventory.
CAS# 7631-86-9 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
