MSDS Name:Sparkleen 2
Synonym:FisherBrand Sparkleen 2 Detergent

EMERGENCY OVERVIEW
Contact with acids liberates toxic gas. Causes burns. Contact with combustible material may cause fire. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion:
May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea.
Inhalation:
May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation.
Chronic:
Prolonged or repeated contact with concentrated solutions causes tissue damage.

Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
Get medical aid immediately. In case of contact, immediately wipe away excess material with a dry cloth while removing contaminated clothing and shoes. Under safety shower, wash affected areas thoroughly with large amounts of water, and soap if available, for at least 15 minutes. Discard or decontaminate clothing and shoes.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Oxidizer. Greatly increases the burning rate of combustible materials. Aqueous solutions at 10% or greater of sodium metasilicate are corrosive to skin and to aluminum.
Extinguishing Media:
Water is a suitable extinguishing media. Do not use dry chemical extinguisher containing ammonia compounds.

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid ingestion and inhalation. Keep from contact with clothing and other combustible materials. Do not use Sparkleen 2 for cleaning of rubber, silverware, aluminum, tinned metal, galvanized metal, brass, or other materials harmed by alkaline chlorine solutions.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from flammable liquids.

Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 497-19-8: Russia: 5 mg/m3 TWA CAS# 2893-78-9: CAS# 6834-92-0: CAS# 7757-82-6: Russia: 10 mg/m3 TWA CAS# 7758-29-4: CAS# 51580-86-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Physical State: Granules
Color: white
Odor: chlorine-like
pH: 12.1 (0.5% soln)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Approx. 10% in water @ 25C
Specific Gravity/Density: Not available.
Molecular Formula: Mixture
Molecular Weight: 0

Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong reducing agents, acids, aluminum, organic matter.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide, toxic fumes of sodium oxide, nitrogen trichloride.
Hazardous Polymerization: Will not occur.

RTECS#:
CAS# 497-19-8: VZ4050000 CAS# 2893-78-9: XZ1900000 CAS# 6834-92-0: VV9275000 CAS# 7757-82-6: WE1650000 CAS# 7758-29-4: YK4570000 CAS# 51580-86-0: XZ1910000 LD50/LC50:
CAS# 497-19-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, eye: 50 mg Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 1200 mg/m3/2H; Inhalation, rat: LC50 = 2300 mg/m3/2H; Oral, mouse: LD50 = 6600 mg/kg; Oral, mouse: LD50 = 6600 mg/kg; Oral, rat: LD50 = 4090 mg/kg.
CAS# 2893-78-9: Draize test, rabbit, eye: 100 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg Severe; Oral, rat: LD50 = 1420 mg/kg.
CAS# 6834-92-0: Draize test, rabbit, skin: 250 mg/24H Severe; Oral, mouse: LD50 = 770 mg/kg; Oral, rat: LD50 = 1153 mg/kg.
CAS# 7757-82-6: Oral, mouse: LD50 = 5989 mg/kg.
CAS# 7758-29-4: Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, mouse: LD50 = 3100 mg/kg; Oral, rat: LD50 = 3120 mg/kg; Skin, rabbit: LD50 = >4640 mg/kg.
CAS# 51580-86-0.
Carcinogenicity:
Sodium carbonate anhydrous - Not listed by ACGIH, IARC, or NTP.
Dichloroisocyanuric acid, sodium salt, anhydrous - Not listed by ACGIH, IARC, or NTP.
Sodium metasilicate - Not listed by ACGIH, IARC, or NTP.
Sodium sulfate anhydrous - Not listed by ACGIH, IARC, or NTP.
Sodium tripolyphosphate - Not listed by ACGIH, IARC, or NTP.
Sodium dichloroisocyanurate, dihydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Ecotoxicity:
Aquatic toxicity data for Sodium dichloroisocyanurate dihydrate: 96 hr LC50 rainbow trout: 0.22 mg/l 96 hr LC50 bluegill sunfish: 0.28 mg/l 48 hr LC50 (Daphnia magna): 0.2 mg/l.
Other When too many nutrients such as phosphorus are in the water, algae grows maniacally. Algae blooms are followed by a die-off, and as material decays, it consumes oxygen like a forest fire. No fish, plants or insects can live in oxygen-free zones.

Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

IATA
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing Group: III
IMO
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing Group: III
RID/ADR
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing group: III
USA RQ: CAS# 7758-29-4: 5000 lb final RQ (Listed under Sodium phosphate, tribasi

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C N
Risk Phrases:
R 31 Contact with acids liberates toxic gas.
R 34 Causes burns.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 8 Keep container dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 41 In case of fire and/or explosion do not breathe
fumes.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 497-19-8: 1
CAS# 2893-78-9: 2
CAS# 6834-92-0: 1
CAS# 7757-82-6: 0
CAS# 7758-29-4: 1
CAS# 51580-86-0: No information available.
Canada
CAS# 497-19-8 is listed on Canadas DSL List.
CAS# 2893-78-9 is listed on Canadas DSL List.
CAS# 6834-92-0 is listed on Canadas DSL List.
CAS# 7757-82-6 is listed on Canadas DSL List.
CAS# 7758-29-4 is listed on Canadas DSL List.
CAS# 497-19-8 is listed on Canadas Ingredient Disclosure List.
CAS# 2893-78-9 is listed on Canadas Ingredient Disclosure List.
CAS# 6834-92-0 is listed on Canadas Ingredient Disclosure List.
CAS# 7757-82-6 is not listed on Canadas Ingredient Disclosure List.
CAS# 7758-29-4 is not listed on Canadas Ingredient Disclosure List.
CAS# 51580-86-0 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 497-19-8 is listed on the TSCA inventory.
CAS# 2893-78-9 is listed on the TSCA inventory.
CAS# 6834-92-0 is listed on the TSCA inventory.
CAS# 7757-82-6 is listed on the TSCA inventory.
CAS# 7758-29-4 is listed on the TSCA inventory.
CAS# 51580-86-0 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).