Name:
Sulfuric Acid Volumetric Solutions 0.05 M
Synonym:
Non
CAS:
7664-93-9
Section 1 - Chemical Product
MSDS Name:Sulfuric Acid Volumetric Solutions 0.05 M
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7664-93-9 | Sulfuric acid | 0.49 | 231-639-5 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
No information found.
Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use dry chemical to fight fire.
Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use dry chemical to fight fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Keep container closed when not in use. Store in a dry area. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not store near alkaline substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Keep container closed when not in use. Store in a dry area. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not store near alkaline substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: colourless
Odor: Not available.
pH: <1.0
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: >1.0
Molecular Formula: Mixture
Molecular Weight: Not available
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, metals, excess heat, combustible materials, organic materials, oxidizers, amines, bases.
Incompatibilities with Other Materials:
Acetic Anhydride, Acetone Cyanhydrin, Acetone + Nitric Acid, Acetone + Potassium Dichromate, Acetonitrile, Acrolein, Acrylonitrile, Alcohols + Hydrogen Peroxide, Allyl Alcohol, Allyl Chloride, 2-Aminoethanol, Ammonium Hydroxide, Ammonium Triperchromate, Aniline, Bromates + Metals, Bromine Pentafluoride, n-Butyraldehyde, Carbides, Cesium Acetylene Carbide, Chlorates, Chlorine Trifluoride, Chlorosulfonic Acid, Cuprous Nitride, Diisobutylene, Epichlorohydrin, Ethylene Cyanohydrin, Ethylene Diamine, Ethylene Glycol, Ethylenimine, Fulminates, Other Acids, Iodine Heptafluoride, Metals, Isoprene, Lithium Silicide, Mercuric Nitride, Mesityl Oxide, P-Nitrotoluene, Pentasilver Trihydroxydiaminophosphate, Perchlorates, Permanganates + Benzene, Phosphorus, Phosphorus Isocyanate, Picrates, Potassium t-Butoxide, Potassium Chlorate, Permanganates, beta-Propiolactone, Propylene Oxide, Pyridine, Rubidium Acetylene Carbide and Sodium.
Hazardous Decomposition Products:
Oxides of sulfur.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, metals, excess heat, combustible materials, organic materials, oxidizers, amines, bases.
Incompatibilities with Other Materials:
Acetic Anhydride, Acetone Cyanhydrin, Acetone + Nitric Acid, Acetone + Potassium Dichromate, Acetonitrile, Acrolein, Acrylonitrile, Alcohols + Hydrogen Peroxide, Allyl Alcohol, Allyl Chloride, 2-Aminoethanol, Ammonium Hydroxide, Ammonium Triperchromate, Aniline, Bromates + Metals, Bromine Pentafluoride, n-Butyraldehyde, Carbides, Cesium Acetylene Carbide, Chlorates, Chlorine Trifluoride, Chlorosulfonic Acid, Cuprous Nitride, Diisobutylene, Epichlorohydrin, Ethylene Cyanohydrin, Ethylene Diamine, Ethylene Glycol, Ethylenimine, Fulminates, Other Acids, Iodine Heptafluoride, Metals, Isoprene, Lithium Silicide, Mercuric Nitride, Mesityl Oxide, P-Nitrotoluene, Pentasilver Trihydroxydiaminophosphate, Perchlorates, Permanganates + Benzene, Phosphorus, Phosphorus Isocyanate, Picrates, Potassium t-Butoxide, Potassium Chlorate, Permanganates, beta-Propiolactone, Propylene Oxide, Pyridine, Rubidium Acetylene Carbide and Sodium.
Hazardous Decomposition Products:
Oxides of sulfur.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7664-93-9: WS5600000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation, mouse: LC50 = 320 mg/m3/2H; Inhalation, rat: LC50 = 510 mg/m3/2H; Oral, rat: LD50 = 2140 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Sulfuric acid - ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorg OSHA: Select carcinogen IARC: Group 1 carcinogen Water - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
CAS# 7664-93-9: WS5600000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation, mouse: LC50 = 320 mg/m3/2H; Inhalation, rat: LC50 = 510 mg/m3/2H; Oral, rat: LD50 = 2140 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Sulfuric acid - ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorg OSHA: Select carcinogen IARC: Group 1 carcinogen Water - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Sulfuric acid is harmful to aquatic life in very low concentrations.
It may be dangerous if it enters water intakes. The aquatic toxicity for bluegill in fresh water was 24.5 ppm/24 hr, which was lethal.
Sulfuric acid is harmful to aquatic life in very low concentrations.
It may be dangerous if it enters water intakes. The aquatic toxicity for bluegill in fresh water was 24.5 ppm/24 hr, which was lethal.
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7664-93-9: 2
CAS# 7732-18-5: No information available.
United Kingdom Occupational Exposure Limits
CAS# 7664-93-9: OES-United Kingdom, TWA 1 mg/m3 TWA
Canada
CAS# 7664-93-9 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 7664-93-9 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 7664-93-9: OEL-ARAB Republic of Egypt:TWA 1 mg/m3
OEL-AUSTRALIA:TWA 1 mg/m3
OEL-BELGIUM:TWA 1 mg/m3;STEL 3 mg/m3
OEL-CZECHOSLOVAKIA:TWA 1 mg/m3;STEL 2 mg/m3
OEL-DENMARK:TWA 1 mg/m3
OEL-FINLAND:TWA 1 mg/m3;STEL 3 mg/m3;Skin
OEL-FRANCE:TWA 1 mg/m3;STEL 3 mg/m3
OEL-GERMANY:TWA 1 mg/m3
OEL-HUNGARY:STEL 1 mg/m3
OEL-JAPAN:TWA 1 mg/m3
OEL-THE NETHERLANDS:TWA 1 mg/m3
OEL-THE PHILIPPINES:TWA 1 mg/m3
OEL-POLAND:TWA 1 mg/m3
OEL-RUSSIA:STEL 1 mg/m3;Skin
OEL-SWEDEN:TWA 1 mg/m3;STEL 3 mg/m3
OEL-SWITZERLAND:TWA 1 mg/m3;STEL 2 mg/m3
OEL-THAILAND:TWA 1 mg/m3
OEL-TURKEY:TWA 1 mg/m3
OEL-UNITED KINGDOM:TWA 1 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
