Name:
Vanadium(iii) oxide 99%
Synonym:
Vanadium sesquioxide; vanadium trioxide; Vanadic oxid
CAS:
1314-34-7
Section 1 - Chemical Product
MSDS Name:Vanadium(iii) oxide 99%
Synonym:Vanadium sesquioxide; vanadium trioxide; Vanadic oxid
Synonym:Vanadium sesquioxide; vanadium trioxide; Vanadic oxid
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1314-34-7 | VANADIUM(III) OXIDE | 215-230-9 |
| Hazard Symbols: T Risk Phrases: 25 36/37/38 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic if swallowed. Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.
Toxic if swallowed. Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1314-34-7: Russia: 0.5 mg/m3 TWA (dust) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1314-34-7: Russia: 0.5 mg/m3 TWA (dust) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: black
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 1940 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 4.8700g/cm3
Molecular Formula: O3V2
Molecular Weight: 149.88
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
May decompose on exposure to air.
Hazardous Decomposition Products:
Vanadium oxide (VOx) gases.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
May decompose on exposure to air.
Hazardous Decomposition Products:
Vanadium oxide (VOx) gases.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1314-34-7: YW3050000 YW3650000 LD50/LC50:
CAS# 1314-34-7: Draize test, rabbit, eye: 5 uL/24H Moderate; Oral, mouse: LD50 = 130 mg/kg; Oral, mouse: LD50 = 130 mg/kg; Oral, rat: LD50 = 566 mg/kg; Skin, rabbit: LD50 = 200 mg/kg.
Carcinogenicity:
VANADIUM(III) OXIDE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 1314-34-7: YW3050000 YW3650000 LD50/LC50:
CAS# 1314-34-7: Draize test, rabbit, eye: 5 uL/24H Moderate; Oral, mouse: LD50 = 130 mg/kg; Oral, mouse: LD50 = 130 mg/kg; Oral, rat: LD50 = 566 mg/kg; Skin, rabbit: LD50 = 200 mg/kg.
Carcinogenicity:
VANADIUM(III) OXIDE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing Group: III
IMO
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing Group: III
RID/ADR
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing group: III
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1314-34-7: No information available.
Canada
CAS# 1314-34-7 is listed on Canadas NDSL List.
CAS# 1314-34-7 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1314-34-7 is listed on the TSCA inventory.
