Name:
Ethyl alcohol-d6 anhydrous 99 Atom % D
Synonym:
Ethanol-d6; Deuterated ethanol; Hexadeuteroethanol
CAS:
64-17-5
Section 1 - Chemical Product
MSDS Name:Ethyl alcohol-d6 anhydrous 99 Atom % D
Synonym:Ethanol-d6; Deuterated ethanol; Hexadeuteroethanol
Synonym:Ethanol-d6; Deuterated ethanol; Hexadeuteroethanol
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-17-5 | Ethyl alcohol-d6 | 99 | 216-162-2 |
| Hazard Symbols: F Risk Phrases: 11 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May be absorbed through the skin.
Ingestion:
Cannot be made non-poisonous. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause liver damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. Prolonged exposure may result in dizziness and general weakness.
Chronic:
Prolonged or repeated eye contact may cause conjunctivitis.
Prolonged or repeated exposure may cause adverse reproductive effects. May cause liver and kidney damage.
Highly flammable.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May be absorbed through the skin.
Ingestion:
Cannot be made non-poisonous. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause liver damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. Prolonged exposure may result in dizziness and general weakness.
Chronic:
Prolonged or repeated eye contact may cause conjunctivitis.
Prolonged or repeated exposure may cause adverse reproductive effects. May cause liver and kidney damage.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Remove contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Activated charcoal does not reduce ethanol absorption.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Remove contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Activated charcoal does not reduce ethanol absorption.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of water. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of water. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.
Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 64-17-5: United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE France - VME: 1000 ppm VME; 1900 mg/m3 VME France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 960 mg/m3 TWA Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA Netherlands: 500 ppm MAC; 1000 mg/m3 MAC Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED CAS# 1516-08-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 64-17-5: United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE France - VME: 1000 ppm VME; 1900 mg/m3 VME France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 960 mg/m3 TWA Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA Netherlands: 500 ppm MAC; 1000 mg/m3 MAC Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED CAS# 1516-08-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear, colorless
Odor: alcohol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 78 deg C @ 760 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: 363 deg C ( 685.40 deg F)
Flash Point: 12 deg C ( 53.60 deg F)
Explosion Limits, lower: 3.3
Explosion Limits, upper: 19
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: .8010g/cm3
Molecular Formula: C2D6O
Molecular Weight: 52.12
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, ignition sources, moist air.
Incompatibilities with Other Materials:
Oxidizing agents, peroxides, acids, acid chlorides, acid anhydrides, alkali metals, ammonia.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, ignition sources, moist air.
Incompatibilities with Other Materials:
Oxidizing agents, peroxides, acids, acid chlorides, acid anhydrides, alkali metals, ammonia.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-17-5: KQ6300000 CAS# 1516-08-1 unlisted.
LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg.
CAS# 1516-08-1.
Carcinogenicity:
Ethyl alcohol - Not listed by ACGIH, IARC, or NTP.
Ethyl alcohol-d6 - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 64-17-5: KQ6300000 CAS# 1516-08-1 unlisted.
LD50/LC50:
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg.
CAS# 1516-08-1.
Carcinogenicity:
Ethyl alcohol - Not listed by ACGIH, IARC, or NTP.
Ethyl alcohol-d6 - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 1516-08-1: No information available.
Canada
CAS# 64-17-5 is listed on Canadas DSL List.
CAS# 64-17-5 is listed on Canadas Ingredient Disclosure List.
CAS# 1516-08-1 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 1516-08-1 is not listed on the TSCA inventory.
It is for research and development use only.
